calcium fluoride


Liquid Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1691. - 4000.
A 23.88010
B -1.624841×10-9
C 5.607651×10-10
D -6.423311×10-11
E -5.230020×10-10
F -293.9309
G 44.73169
H -283.4771
ReferenceChase, 1998
Comment Data last reviewed in December, 1968
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
1691.23.8857.2839.5829.93
1700.23.8857.4039.6730.14
1800.23.8858.7740.7032.53
1900.23.8860.0641.6834.92
2000.23.8861.2842.6337.31
2100.23.8862.4543.5539.69
2200.23.8863.5644.4342.08
2300.23.8864.6245.2944.47
2400.23.8865.6446.1146.86
2500.23.8866.6146.9149.25
2600.23.8867.5547.6951.63
2700.23.8868.4548.4454.02
2800.23.8869.3249.1756.41
2900.23.8870.1649.8858.80
3000.23.8870.9750.5761.19
3100.23.8871.7551.2463.57
3200.23.8872.5151.8965.96
3300.23.8873.2452.5368.35
3400.23.8873.9653.1570.74
3500.23.8874.6553.7573.13
3600.23.8875.3254.3475.51
3700.23.8875.9754.9277.90
3800.23.8876.6155.4880.29
3900.23.8877.2356.0382.68
4000.23.8877.8456.5785.07

References

Go To: Top, Liquid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Liquid Phase Heat Capacity (Shomate Equation), References