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silicon tetrabromide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.62 ± 0.04PICreasey, Lambert, et al., 1991LL
14. ± 1.EIFarber and Srivastava, 1980LLK
10.8PEGreen, Green, et al., 1970RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Br+25.0 ± 0.5?PICreasey, Lambert, et al., 1991LL
BrSi+17.1 ± 0.3?PICreasey, Lambert, et al., 1991LL
Br2Si+16.1 ± 0.3?PICreasey, Lambert, et al., 1991LL
Br3Si+11.31 ± 0.03BrPICreasey, Lambert, et al., 1991LL
Si+23.4 ± 0.4?PICreasey, Lambert, et al., 1991LL

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Creasey, Lambert, et al., 1991
Creasey, J.C.; Lambert, I.R.; Tuckett, R.P.; Codling, K.; Leszek, J.F.; Hatherly, P.A.; Stankiewicz, M., Photoionization mass-spectrometric study of fragmentation of SiBr4 and GeBr4 in the range 400-1220 A, J. Chem. Soc. Faraday Trans., 1991, 87, 3717. [all data]

Farber and Srivastava, 1980
Farber, M.; Srivastava, R.D., Mass spectrometric determination of the heats of formation of the silicon bromides SiBr(g), SiBr2(g), and SiBr3(g)., High Temp. Sci., 1980, 12, 21. [all data]

Green, Green, et al., 1970
Green, J.C.; Green, M.L.H.; Joachim, P.J.; Orchard, A.F.; Turner, D.W., A study of the bonding in the group IV tetrahalides by photoelectron spectroscopy, Phil. Trans. Roy. Soc. (London), 1970, A268, III. [all data]


Notes

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