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bromine pentafluoride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil313.4KN/APCR Inc., 1990BS
Tboil314.45KN/AStein, Vogel, et al., 1954Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus211.85KN/AStein, Vogel, et al., 1954Uncertainty assigned by TRC = 0.6 K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
30.6304.Rogers and Speirs, 1956Based on data from 297. - 314. K.; AC
31.2255.Ruff and Menzel, 1931Based on data from 213. - 297. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
203.8 - 313.64.797771411.692-19.763Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Stein, Vogel, et al., 1954
Stein, L.; Vogel, R.C.; Ludewig, W.H., Partial Molal Volumes and Molar Refractions of the System Bromine Trifluoride-Bromine Pentafluoride, J. Am. Chem. Soc., 1954, 76, 4287-9. [all data]

Rogers and Speirs, 1956
Rogers, Max T.; Speirs, John L., Bromine Pentafluoride. Freezing and Boiling Points, Heat of Vaporization and Vapor Pressure- Temperature Relations, J. Phys. Chem., 1956, 60, 10, 1462-1463, https://doi.org/10.1021/j150544a038 . [all data]

Ruff and Menzel, 1931
Ruff, Otto; Menzel, Walter, Das Brom-5-fluorid, Z. Anorg. Allg. Chem., 1931, 202, 1, 49-61, https://doi.org/10.1002/zaac.19312020106 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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