thallium fluoride
- Formula: FTl
- Molecular weight: 223.3817
- IUPAC Standard InChI: InChI=1S/FH.Tl/h1H;/q;+1/p-1
- IUPAC Standard InChIKey: CULOEOTWMUCRSJ-UHFFFAOYSA-M
- CAS Registry Number: 7789-27-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Thallium monofluoride
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 142.7 | kJ/mol | N/A | Keneshea and Cubicciotti, 1967 |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.52 | PE | Dehmer, Berkowitz, et al., 1973 | LLK |
| 11.2 ± 0.5 | EI | Murad, Hildenbrand, et al., 1966 | RDSH |
| 10.80 ± 0.02 | PE | Streets and Berkowitz, 1976 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tl+ | 10.68 | F | PI | Berkowitz and Walter, 1968 | RDSH |
| Tl+ | 7.59 | F- | PI | Berkowitz and Walter, 1968 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Keneshea and Cubicciotti, 1967
Keneshea, Francis J.; Cubicciotti, Daniel,
The thermodynamics of vaporization of thallous fluoride,
J. Phys. Chem., 1967, 71, 6, 1958-1960, https://doi.org/10.1021/j100865a076
. [all data]
Dehmer, Berkowitz, et al., 1973
Dehmer, J.L.; Berkowitz, J.; Cusachs, L.C.,
Photoelectron spectroscopy of high-temperature vapors. III. Monomer and dimer spectra of thallous fluoride,
J. Chem. Phys., 1973, 58, 5681. [all data]
Murad, Hildenbrand, et al., 1966
Murad, E.; Hildenbrand, D.L.; Main, R.P.,
Dissociation energies of group IIIA monofluorides-the possibility of potential maxima in their excited H states,,
J. Chem. Phys., 1966, 45, 263. [all data]
Streets and Berkowitz, 1976
Streets, D.G.; Berkowitz, J.,
The structure of Tl2F2 from photoelectron spectroscopy,
Chem. Phys. Lett., 1976, 38, 475. [all data]
Berkowitz and Walter, 1968
Berkowitz, J.; Walter, T.A.,
Photoionization of high-temperature vapors. IV.TIF, TICI, and TIBr,
J. Chem. Phys., 1968, 49, 1184. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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