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Potassium fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
0.23NBAEDe Vreugd, Wijnaendts van Resandt, et al., 1979B
<1.5004IMRESidorov, Skokan, et al., 1980B
1.04 ± 0.21EIAEShevchenko, Iljin, et al., 1976From K2BO2F; value altered from reference due to conversion from electron convention to ion convention; B
>1.25999EIAEEbinghaus, 1964From (KF)2; B

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
K+9.8FEISchafer and Rabeneck, 1987LBLHLM
K+9.54 ± 0.20FEIShevchenko, Iljin, et al., 1976LLK
K+9.5 ± 0.3FEIHastie, Zmbov, et al., 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

De Vreugd, Wijnaendts van Resandt, et al., 1979
De Vreugd, C.; Wijnaendts van Resandt, R.W.; Los, J.; Smith, B., Differential Cross Sections for Collisions of Negative Halogen Ions and Alkali Atoms, Chem. Phys., 1979, 42, 3, 305, https://doi.org/10.1016/0301-0104(79)80078-6 . [all data]

Sidorov, Skokan, et al., 1980
Sidorov, L.N.; Skokan, E.V.; Nitikin, M.I.; Sorokin, I.D., Mass spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. III. Heat of formation of UF5- and electron affinity of UF5, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 215. [all data]

Shevchenko, Iljin, et al., 1976
Shevchenko, V.E.; Iljin, M.K.; Nikitin, O.T.; Sidorov, L.N., Mass-spectrometric study of mixed dimers M2BO2F, Int. J. Mass Spectrom. Ion Phys., 1976, 21, 279. [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Schafer and Rabeneck, 1987
Schafer, H.; Rabeneck, H., Massenspektroskopische untersuchung der borfluorid-komplexe ABF4, Z. Anorg. Allg. Chem., 1987, 545, 224. [all data]

Hastie, Zmbov, et al., 1968
Hastie, J.W.; Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXIII. Vapor equilibria over molten NaSnF3 and KSnF3, J. Inorg. Nucl. Chem., 1968, 30, 729. [all data]


Notes

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