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bismuth trichloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
503.7 - 710.65.669684143.04619.221Yanai, Watanabe, et al., 1973Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
124.7371. - 468.MECubicciotti, 1966See also Darnell and Yosim, 1959.; AC
118.8 ± 0.4420.MEDarnell and Yosim, 1959Based on data from 371. - 468. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Deltar153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
11.2 ± 0.1EIOzgen, 1983 
10.4PENovak and Potts, 1983 
10.98PENovak and Potts, 1983Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
BiCl+12.2 ± 0.12Cl/Cl2EIOzgen, 1983 
BiCl2+11.6 ± 0.1ClEIOzgen, 1983 

Ion clustering data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Deltar153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yanai, Watanabe, et al., 1973
Yanai, M.; Watanabe, F.; Saeki, Y., The Vapor Pressure of Bismuth Trichloride, J. Less-Common Met., 1973, 33, 3, 387-389, https://doi.org/10.1016/0022-5088(73)90192-6 . [all data]

Cubicciotti, 1966
Cubicciotti, Daniel, A New «SIGMA»-Plot Treatment of Equilibrium Data and Its Application to the Vaporization of Bismuth Chloride 1, J. Phys. Chem., 1966, 70, 7, 2410-2413, https://doi.org/10.1021/j100879a504 . [all data]

Darnell and Yosim, 1959
Darnell, A.J.; Yosim, S.J., Some Thermodynamic Properties of Solid Bismuth Chloride, J. Phys. Chem., 1959, 63, 11, 1813-1815, https://doi.org/10.1021/j150581a005 . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]

Ozgen, 1983
Ozgen, T., Mass spectrometric determination of the appearance potentials of PCl3, AsCl3, SbCl3, BiCl3 and their fragments, Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]

Novak and Potts, 1983
Novak, I.; Potts, A.W., The ultraviolet photoelectron spectra of gas phase and condensed bismuth halides and antimony trifluoride, J. Chem. Soc. Dalton Trans., 1983, 635. [all data]


Notes

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