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Arsenic trichloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director

Quantity Value Units Method Reference Comment
Tc653.KN/ASladkov and Shimeleva, 1974Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Vc0.247l/molN/ASladkov and Shimeleva, 1974Uncertainty assigned by TRC = 0.005 l/mol; Abstract, no details; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
261.8 - 403.64.475471620.019-41.362Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Deltar115. ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.2 ± 0.1EIOzgen, 1983LBLHLM
11.6 ± 0.05EIPabst, Sharpe, et al., 1980LLK
10.57 ± 0.03EIJohnstone and Mellon, 1972LLK
10.55 ± 0.025PEJohnstone and Mellon, 1972LLK
10.72 ± 0.07PELloyd, 1970RDSH
11.7 ± 0.1EICullen and Frost, 1962RDSH
10.90PELee and Rabalais, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
As+17.4 ± 0.1?EIOzgen, 1983LBLHLM
As+20.4 ± 0.43ClEIPabst, Sharpe, et al., 1980LLK
AsCl+16.6 ± 0.1Cl2/2ClEIOzgen, 1983LBLHLM
ClAs+17.7 ± 0.2?EIPabst, Sharpe, et al., 1980LLK
AsCl2+12.1 ± 0.1ClEIOzgen, 1983LBLHLM
Cl2As+12.4 ± 0.2Cl-EIPabst, Sharpe, et al., 1980LLK
Cl+22.0 ± 0.1?EIOzgen, 1983LBLHLM

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Deltar115. ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Eric Wils, TNO Prins Maurits Laboratory, The Netherlands.
NIST MS number 273374

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References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sladkov and Shimeleva, 1974
Sladkov, I.B.; Shimeleva, V.I., Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 154. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]

Ozgen, 1983
Ozgen, T., Mass spectrometric determination of the appearance potentials of PCl3, AsCl3, SbCl3, BiCl3 and their fragments, Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]

Pabst, Sharpe, et al., 1980
Pabst, R.E.; Sharpe, M.C.; Margrave, J.L.; Franklin, J.L., An electron impact study of the appearance energies of positive ions from AsF3, AsCl3, AsBr3 and AsF5, Int. J. Mass Spectrom. Ion Phys., 1980, 33, 187. [all data]

Johnstone and Mellon, 1972
Johnstone, R.A.W.; Mellon, F.A., Electron-impact ionization and appearance potentials, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1209. [all data]

Lloyd, 1970
Lloyd, D.R., The failure of electron impact measurements to detect first ionization potentials in some molecules, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 500. [all data]

Cullen and Frost, 1962
Cullen, W.R.; Frost, D.C., Ionization potentials of some perfluoroalkyl arsines, Can. J. Chem., 1962, 40, 390. [all data]

Lee and Rabalais, 1974
Lee, T.H.; Rabalais, J.W., Model for spin- orbit interactions with inclusion of d electrons: Applications to photoelectron spectroscopy, J. Chem. Phys., 1974, 60, 1172. [all data]


Notes

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