Arsenic trichloride
- Formula: AsCl3
- Molecular weight: 181.281
- IUPAC Standard InChIKey: OEYOHULQRFXULB-UHFFFAOYSA-N
- CAS Registry Number: 7784-34-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Arsenic(III) chloride; AsCl3; Arsenous chloride; Arsenous trichloride; Arsenic chloride; Arsenic butter; Arsenious chloride; Butter of arsenic; Chlorure arsenieux; Chlorure d'arsenic; Fuming liquid arsenic; Trichloroarsine; Trichlorure d'arsenic; UN 1560; Arsenic chloride (AsCl3); Arsenic(3+) chloride
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.2 ± 0.1 | EI | Ozgen, 1983 | LBLHLM |
11.6 ± 0.05 | EI | Pabst, Sharpe, et al., 1980 | LLK |
10.57 ± 0.03 | EI | Johnstone and Mellon, 1972 | LLK |
10.55 ± 0.025 | PE | Johnstone and Mellon, 1972 | LLK |
10.72 ± 0.07 | PE | Lloyd, 1970 | RDSH |
11.7 ± 0.1 | EI | Cullen and Frost, 1962 | RDSH |
10.90 | PE | Lee and Rabalais, 1974 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
As+ | 17.4 ± 0.1 | ? | EI | Ozgen, 1983 | LBLHLM |
As+ | 20.4 ± 0.4 | 3Cl | EI | Pabst, Sharpe, et al., 1980 | LLK |
AsCl+ | 16.6 ± 0.1 | Cl2/2Cl | EI | Ozgen, 1983 | LBLHLM |
ClAs+ | 17.7 ± 0.2 | ? | EI | Pabst, Sharpe, et al., 1980 | LLK |
AsCl2+ | 12.1 ± 0.1 | Cl | EI | Ozgen, 1983 | LBLHLM |
Cl2As+ | 12.4 ± 0.2 | Cl- | EI | Pabst, Sharpe, et al., 1980 | LLK |
Cl+ | 22.0 ± 0.1 | ? | EI | Ozgen, 1983 | LBLHLM |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ozgen, 1983
Ozgen, T.,
Mass spectrometric determination of the appearance potentials of PCl3, AsCl3, SbCl3, BiCl3 and their fragments,
Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]
Pabst, Sharpe, et al., 1980
Pabst, R.E.; Sharpe, M.C.; Margrave, J.L.; Franklin, J.L.,
An electron impact study of the appearance energies of positive ions from AsF3, AsCl3, AsBr3 and AsF5,
Int. J. Mass Spectrom. Ion Phys., 1980, 33, 187. [all data]
Johnstone and Mellon, 1972
Johnstone, R.A.W.; Mellon, F.A.,
Electron-impact ionization and appearance potentials,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1209. [all data]
Lloyd, 1970
Lloyd, D.R.,
The failure of electron impact measurements to detect first ionization potentials in some molecules,
Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 500. [all data]
Cullen and Frost, 1962
Cullen, W.R.; Frost, D.C.,
Ionization potentials of some perfluoroalkyl arsines,
Can. J. Chem., 1962, 40, 390. [all data]
Lee and Rabalais, 1974
Lee, T.H.; Rabalais, J.W.,
Model for spin- orbit interactions with inclusion of d electrons: Applications to photoelectron spectroscopy,
J. Chem. Phys., 1974, 60, 1172. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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