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Aluminum fluoride

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

AlF4- + Aluminum fluoride = (AlF4- bullet Aluminum fluoride)

By formula: AlF4- + AlF3 = (AlF4- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar204. ± 4.2kJ/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Quantity Value Units Method Reference Comment
Deltar175. ± 8.4kJ/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum fluoride = (Chlorine anion bullet Aluminum fluoride)

By formula: Cl- + AlF3 = (Cl- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiment at 800-1100 K. See also AlClF2..F-; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Aluminum fluoride = (Fluorine anion bullet Aluminum fluoride)

By formula: F- + AlF3 = (F- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar510. ± 90.kJ/molAVGN/AAverage of 7 values; Individual data points

(Fluorine anion bullet Aluminum fluoride) + Aluminum fluoride = (Fluorine anion bullet 2Aluminum fluoride)

By formula: (F- bullet AlF3) + AlF3 = (F- bullet 2AlF3)

Quantity Value Units Method Reference Comment
Deltar230.kJ/molMSPyatenko, Gusarov, et al., 1981gas phase; Knudsen cell; M
Deltar204.kJ/molMSNikitin, Skokan, et al., 1979gas phase; Knudsen cell; M

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D., Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]

Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N., Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions, Russ. J. Phys. Chem., 1992, 66, 635. [all data]

Pyatenko, Gusarov, et al., 1981
Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Negative Ions in the Vapor Over Lanthanum Trifluoride, High Temp., 1981, 19, 241. [all data]

Nikitin, Skokan, et al., 1979
Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N., Sov. Phys. Dokl., 1979, 247, 594. [all data]


Notes

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