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zirconium tetrafluoride


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + zirconium tetrafluoride = (Fluorine anion bullet zirconium tetrafluoride)

By formula: F- + F4Zr = (F- bullet F4Zr)

Quantity Value Units Method Reference Comment
Deltar99.3 ± 2.0kcal/molTDEqSkokan, Sorokin, et al., 1982gas phase; Fluoride Affinity: 22±1 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention
Deltar96.3 ± 1.0kcal/molTDEqSkokan, Nikitin, et al., 1981gas phase; Fluoride Affinity: 23.12 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

F5Zr- + zirconium tetrafluoride = F9Zr2-

By formula: F5Zr- + F4Zr = F9Zr2-

Quantity Value Units Method Reference Comment
Deltar51.2 ± 1.0kcal/molTDAsSkokan, Sorokin, et al., 1982gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Skokan, Sorokin, et al., 1982
Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VI. Enthalpy of Formation of ZrF5-, Int. J. Mass Spectrom. Ion Phys., 1982, 43, 4, 209, https://doi.org/10.1016/0020-7381(82)80017-X . [all data]

Skokan, Nikitin, et al., 1981
Skokan, E.V.; Nikitin, M.I.; Sorokin, I.D.; Gusarov, A.V.; Sidirov, L.N., Determination of the heat of formation of the tetrafluoroscandate and pentfluorozirconate ions by the effusion nethod, Russ. J. Phys. Chem., 1981, 55, 1062. [all data]


Notes

Go To: Top, Ion clustering data, References