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tetrafluorogermane


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

Fluorine anion + tetrafluorogermane = (Fluorine anion bullet tetrafluorogermane)

By formula: F- + F4Ge = (F- bullet F4Ge)

Quantity Value Units Method Reference Comment
Deltar418. ± 29.kJ/molTherMallouk, Rosenthal, et al., 1984gas phase; Fluoride affinities from this method appear to be consistently about 10 kcal/mol too bound
Deltar>404.6kJ/molIMRBHarland, Cradock, et al., 1972gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mallouk, Rosenthal, et al., 1984
Mallouk, T.E.; Rosenthal, G.L.; Muller, G.; Brusasco, R.; Bartlett, N., Fluoride ion affinities of GeF4 and BF4 from thermodynamic and structural data for (SF2)2GeF6, ClO2GeF5, and ClO2BF4, Inorg. Chem., 1984, 23, 3167. [all data]

Harland, Cradock, et al., 1972
Harland, P.W.; Cradock, S.; Thynne, J.C.J., Positive- and negative-ion formation due to the electron bombardment of germanium tetrafluoride, Int. J. Mass Spectrom. Ion Phys., 1972, 10, 169. [all data]


Notes

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