Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Phosphorus trifluoride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to F3P+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)11.38 ± 0.10eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)695.3kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity662.8kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
11.38 ± 0.01PIPECORuede, Troxler, et al., 1993LL
<=11.44PIBerkowitz, Greene, et al., 1984LBLHLM
11.51EINeskovic, Miletic, et al., 1983LBLHLM
11.65EIBaldwin, Loudon, et al., 1977LLK
11.65 ± 0.07EITorgerson and Westmore, 1975LLK
11.4 ± 0.2EIHarland, Rankin, et al., 1974LLK
11.5 ± 0.1PIHarland, Rankin, et al., 1974LLK
11.6 ± 0.1EIDean, Finch, et al., 1974LLK
11.57 ± 0.01PEMaier and Turner, 1972LLK
11.66 ± 0.01PEBasset and Lloyd, 1972LLK
11.56PEMuller, Fenderl, et al., 1971LLK
11.7 ± 0.1EIMuller and Fenderl, 1971LLK
9.71PIPrice and Passmore, 1963RDSH
12.20PEYarbrough and Hall, 1978Vertical value; LLK
12.28PEDaamen, Boxhoorn, et al., 1978Vertical value; LLK
12.23 ± 0.02PECradock and Rankin, 1972Vertical value; LLK
12.28PEPotts, Lempka, et al., 1970Vertical value; RDSH
12.3PEHillier, Marriott, et al., 1970Vertical value; RDSH
12.31PEGreen, King, et al., 1970Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FP+20.5 ± 0.2F2EITorgerson and Westmore, 1975LLK
FP+21.0 ± 0.32FEIHarland, Rankin, et al., 1974LLK
F2P+14.27 ± 0.02FPIPECORuede, Troxler, et al., 1993LL
F2P+14.55 ± 0.01FPIBerkowitz, Greene, et al., 1984LBLHLM
F2P+15.42FEINeskovic, Miletic, et al., 1983LBLHLM
F2P+15.5 ± 0.2FEITorgerson and Westmore, 1975LLK
F2P+13.5 ± 0.1FEIDean, Finch, et al., 1974LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Ruede, Troxler, et al., 1993
Ruede, R.; Troxler, H.; Beglinger, C.; Jungen, M., The dissociation energies of the positive ions NH3+, NF3+, PH3+, PF3+ and PCl3+, Chem. Phys. Lett., 1993, 203, 477. [all data]

Berkowitz, Greene, et al., 1984
Berkowitz, J.; Greene, J.P.; Foropoulos, J., Jr.; Neskovic, O.M., Bonding and ionization energies of N-F and P-F compounds, J. Chem. Phys., 1984, 81, 6166. [all data]

Neskovic, Miletic, et al., 1983
Neskovic, O.; Miletic, M.; Veljkovic, M.; Golobocantin, D.; Zmbov, K.F., Ionization and fragmentation of phosphorous oxyfluoride by electron impact, Int. J. Mass Spectrom. Ion Processes, 1983, 47, 141. [all data]

Baldwin, Loudon, et al., 1977
Baldwin, M.A.; Loudon, A.G.; Dunmur, R.E.; Schmutzler, R.; Gregor, I.K., Charge location and fragmentation under electron impact. IV-The behaviour under electron impact of some N-methyl, N'-R-1,2,4-phosphadiazetidine-3-ones and related compounds, Org. Mass Spectrom., 1977, 12, 275. [all data]

Torgerson and Westmore, 1975
Torgerson, D.F.; Westmore, J.B., Energetics of the ionization and fragmentation of phosphorus trifluoride by electron impact, Can. J. Chem., 1975, 53, 933. [all data]

Harland, Rankin, et al., 1974
Harland, P.W.; Rankin, D.W.H.; Thynne, J.C.J., Ionisation by electron impact of phosphorus trifluoride and difluorocyanophosphine, Int. J. Mass Spectrom. Ion Phys., 1974, 13, 395. [all data]

Dean, Finch, et al., 1974
Dean, C.R.S.; Finch, A.; Gardner, P.J.; Payling, D.W., Appearance and ionization potentials of ions produced by electron-impact on some phosphorus-fluorine compounds: the phosphorusphorus bond dissociation energy in diphosphorus tetrafluoride, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1921. [all data]

Maier and Turner, 1972
Maier, J.P.; Turner, D.W., Photoelectron spectroscopy and the geometry of the phosphine and phosphorous trifluoride molecular ions, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 711. [all data]

Basset and Lloyd, 1972
Basset, P.J.; Lloyd, D.R., Photoelectron spectra of halides. Part III. Trifluorides and oxide trifluorides of nitrogen and phosphorus, and phosphorus oxide trichloride, J. Chem. Soc. Dalton Trans., 1972, 248. [all data]

Muller, Fenderl, et al., 1971
Muller, J.; Fenderl, K.; Mertschenk, B., Die Donor-Akzeptor-Eigenschaften des Liganden Trifluorphosphin in Ubergangsmetallkomplexen, Chem. Ber., 1971, 104, 700. [all data]

Muller and Fenderl, 1971
Muller, J.; Fenderl, K., Reaktionen des «pi»-Cyclopentadienyl-Mangantricarbonyl-Kations mit einfachen Fluorverbindungen in der gasphase, Chem. Ber., 1971, 104, 2207. [all data]

Price and Passmore, 1963
Price, W.C.; Passmore, T.R., [Title unavailable], Faraday Discuss. Chem. Soc., 1963, 35, 232. [all data]

Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B., Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative «pi»-acceptor and «sigma»-donor properties of various phosphorus ligands, Inorg. Chem., 1978, 17, 2269. [all data]

Daamen, Boxhoorn, et al., 1978
Daamen, H.; Boxhoorn, G.; Oskam, A., U. V. photoelectron (He I and He II) studies of M(CO)5PX3 (M=Cr, Mo, W and X=F, Cl, Br), Inorg. Chim. Acta, 1978, 28, 263. [all data]

Cradock and Rankin, 1972
Cradock, S.; Rankin, D.W.H., Photoelectron spectra of PF2H some substituted difluorophosphines, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 940. [all data]

Potts, Lempka, et al., 1970
Potts, A.W.; Lempka, H.J.; Streets, D.G.; Price, W.C., Photoelectron spectra of the halides of elements in groups III, IV, V and VI, Phil. Trans. Roy. Soc. (London), 1970, A268, 59. [all data]

Hillier, Marriott, et al., 1970
Hillier, I.H.; Marriott, J.C.; Saunders, V.R.; Ware, M.J.; Lloyd, D.R.; Lynaugh, N., A theoretical and experimental study of the bonding in PF3.BH3, Chem. Commun., 1970, 1586. [all data]

Green, King, et al., 1970
Green, J.C.; King, D.I.; Eland, J.H.D., Photoelectron spectra of trifluorophosphine and its complexes Ni(PF3), and Pt(PF3)4, Chem. Commun., 1970, 1121. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References