gallium trifluoride

• Formula: F₃Ga
• Molecular weight: 126.718
• CAS Registry Number: 7783-51-9
• Information on this page:
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 + F₃Ga = ( • F₃Ga)

By formula: F^- + F₃Ga = (F^- • F₃Ga)

AlF₄^- + F₃Ga = (AlF₄^- • F₃Ga)

By formula: AlF₄^- + F₃Ga = (AlF₄^- • F₃Ga)

F₄Ga^- + F₃Ga = F₇Ga₂^-

By formula: F₄Ga^- + F₃Ga = F₇Ga₂^-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

AlF₄^- + F₃Ga = (AlF₄^- • F₃Ga)

By formula: AlF₄^- + F₃Ga = (AlF₄^- • F₃Ga)

 + F₃Ga = ( • F₃Ga)

By formula: F^- + F₃Ga = (F^- • F₃Ga)

F₄Ga^- + F₃Ga = F₇Ga₂^-

By formula: F₄Ga^- + F₃Ga = F₇Ga₂^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brunetti, Piacente, et al., 2010
Brunetti, Bruno; Piacente, Vincenzo; Scardala, Paolo, Vapor Pressures of Gallium Trifluoride, Trichloride, and Triiodide and Their Standard Sublimation Enthalpies, J. Chem. Eng. Data, 2010, 55, 1, 98-102, https://doi.org/10.1021/je900276q . [all data]

Zhuravleva, Nikitin, et al., 1985
Zhuravleva, L.V.; Nikitin, M.I.; Sorokin, I.D.; Sidorov, L.N., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VIII. MF^-..GaF₃ Systems (M=Li, Na, K, Rb, Cs), Int. J. Mass Spectrom. Ion Proc., 1985, 65, 3, 253, https://doi.org/10.1016/0168-1176(85)87002-6 . [all data]

Feather, Buchler, et al., 1972
Feather, D.H.; Buchler, A.; Searcy, A.W., The vapor pressures of gallium trifluoride monomer and dimer, High Temp. Sci., 1972, 4, 290. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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