Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

iron trifluoride


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + F3Fe = (Fluorine anion bullet F3Fe)

By formula: F- + F3Fe = (F- bullet F3Fe)

Quantity Value Units Method Reference Comment
Deltar453. ± 15.kJ/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention
Deltar439. ± 14.kJ/molTDEqSorokin, Sidorov, et al., 1981gas phase; Fluoride Affinity: 14.9 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention
Deltar456. ± 14.kJ/molTDEqChilingarov, Korobov, et al., 1984gas phase; Fluoride Affinity: 8.8 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

F4Fe- + F3Fe = F7Fe2-

By formula: F4Fe- + F3Fe = F7Fe2-

Quantity Value Units Method Reference Comment
Deltar189. ± 24.kJ/molTDAsSidirov, Borshchevsky, et al., 1986gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar204. ± 4.2kJ/molTDAsSorokin, Sidorov, et al., 1981gas phase; «DELTA»Hf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Sorokin, Sidorov, et al., 1981
Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V., Mass-spectrometric determination of the enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. V. Heats of formation of FeF3- and FeF4-, Int. J. Mass Spectrom. Ion Phys., 1981, 41, 45. [all data]

Chilingarov, Korobov, et al., 1984
Chilingarov, N.S.; Korobov, M.V.; Sidirov, L.N.; Mitkin, V.N.; Shipachev, V.A.; Zemskov, S.V., Electron affinity of rhodium tetrafluoride, J. Chem. Thermodyn., 1984, 16, 965. [all data]

Sidirov, Borshchevsky, et al., 1986
Sidirov, L.N.; Borshchevsky, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Skokan, E.V., Electron affinities of gaseous iron fluorides and dimers, Int. J. Mass Spectrom. Ion Processes, 1986, 73, 1. [all data]


Notes

Go To: Top, Ion clustering data, References