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iron trifluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
3.62 ± 0.13R-ABorshchevskii, Boltalina, et al., 1988Fluoride Affinity: FeF2 < FeF3 by 22.6±2.6 kcal/mol.; value altered from reference due to conversion from electron convention to ion convention; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.5 ± 0.3EIZmbov and Margrave, 1967RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FeF+16.0 ± 0.3?EIZmbov and Margrave, 1967RDSH
FeF2+13.7 ± 0.3FEIZmbov and Margrave, 1967RDSH
Fe+20.5 ± 0.3?EIZmbov and Margrave, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N., Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions., J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8 . [all data]

Zmbov and Margrave, 1967
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies at high temperatures. XV.Sublimation pressures of chromium, manganese and iron trifluoridcs and the heat of dissociation of Fe,F,(g), J. Inorg. Nucl. Chem., 1967, 29, 673. [all data]


Notes

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