zinc fluoride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
60.331015.MEBiefeld and Eick, 1973Based on data from 901. - 1125. K.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + F2Zn = (Fluorine anion • F2Zn)

By formula: F- + F2Zn = (F- • F2Zn)

Quantity Value Units Method Reference Comment
Δr80.5 ± 4.5kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
13.91 ± 0.03PELee, Law, et al., 1980 
13.5PEDyke, Fayad, et al., 1980 
13.91PEDyke, Fayad, et al., 1980Vertical value

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + F2Zn = (Fluorine anion • F2Zn)

By formula: F- + F2Zn = (F- • F2Zn)

Quantity Value Units Method Reference Comment
Δr80.5 ± 4.5kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Biefeld and Eick, 1973
Biefeld, Robert M.; Eick, Harry A., The sublimation thermodynamics of zinc(II) fluoride, The Journal of Chemical Thermodynamics, 1973, 5, 3, 353-360, https://doi.org/10.1016/S0021-9614(73)80024-2 . [all data]

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Lee, Law, et al., 1980
Lee, E.P.F.; Law, D.; Potts, A.W., Photoelectron spectra and valence shell electronic structure of zinc and cadmium difluoride, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1314. [all data]

Dyke, Fayad, et al., 1980
Dyke, J.M.; Fayad, N.K.; Josland, G.D.; Morris, A., Study by high-temperature photoelectron spectroscopy of the electronic structure of the transition metal difluorides, CuF2 and ZnF2, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1672. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References