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Oxygen difluoride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)13.11 ± 0.01eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
13.11 ± 0.01PIBerkowitz, Dehmer, et al., 1973LLK
13.11PEBrundle, Robin, et al., 1972LLK
13.13PECornford, Frost, et al., 1971LLK
13.26PEChadwick, Cornford, et al., 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
OF+<=14.438FPIBerkowitz, Dehmer, et al., 1973LLK
OF+15.8 ± 0.2FEIMalone and McGee, 1965RDSH
OF+15.8 ± 0.2FEIDibeler, Reese, et al., 1957RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, P.M.; Chupka, W.A., Photoionization mass spectrometry of F2O, J. Chem. Phys., 1973, 59, 925. [all data]

Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A.; Basch, H., Perfluoro effect in photoelectron spectroscopy. I. Nonaromatic molecules, J. Am. Chem. Soc., 1972, 94, 1451. [all data]

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Photoelectron spectra of F2O and Cl2O, J. Chem. Phys., 1971, 55, 2820. [all data]

Chadwick, Cornford, et al., 1972
Chadwick, D.; Cornford, A.B.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of some dihalocompounds in Electron spectroscopy, ed. D.A. Shirley (North-Holland Publixhing Co, Amsterdam), 1972, 453. [all data]

Malone and McGee, 1965
Malone, T.J.; McGee, H.A., Jr., Mass spectrometric investigations of the synthesis, stability, and energetics of the low-temperature oxygen fluorides. I. Dioxygen difluoride, J. Phys. Chem., 1965, 69, 4338. [all data]

Dibeler, Reese, et al., 1957
Dibeler, V.H.; Reese, R.M.; Franklin, J.L., Ionization and dissociation of oxygen difluoride by electron impact, J. Chem. Phys., 1957, 27, 1296. [all data]


Go To: Top, Gas phase ion energetics data, References