Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Oxygen difluoride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)13.11 ± 0.01eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
13.11 ± 0.01PIBerkowitz, Dehmer, et al., 1973LLK
13.11PEBrundle, Robin, et al., 1972LLK
13.13PECornford, Frost, et al., 1971LLK
13.26PEChadwick, Cornford, et al., 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
OF+<=14.438FPIBerkowitz, Dehmer, et al., 1973LLK
OF+15.8 ± 0.2FEIMalone and McGee, 1965RDSH
OF+15.8 ± 0.2FEIDibeler, Reese, et al., 1957RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, P.M.; Chupka, W.A., Photoionization mass spectrometry of F2O, J. Chem. Phys., 1973, 59, 925. [all data]

Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A.; Basch, H., Perfluoro effect in photoelectron spectroscopy. I. Nonaromatic molecules, J. Am. Chem. Soc., 1972, 94, 1451. [all data]

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Photoelectron spectra of F2O and Cl2O, J. Chem. Phys., 1971, 55, 2820. [all data]

Chadwick, Cornford, et al., 1972
Chadwick, D.; Cornford, A.B.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of some dihalocompounds in Electron spectroscopy, ed. D.A. Shirley (North-Holland Publixhing Co, Amsterdam), 1972, 453. [all data]

Malone and McGee, 1965
Malone, T.J.; McGee, H.A., Jr., Mass spectrometric investigations of the synthesis, stability, and energetics of the low-temperature oxygen fluorides. I. Dioxygen difluoride, J. Phys. Chem., 1965, 69, 4338. [all data]

Dibeler, Reese, et al., 1957
Dibeler, V.H.; Reese, R.M.; Franklin, J.L., Ionization and dissociation of oxygen difluoride by electron impact, J. Chem. Phys., 1957, 27, 1296. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References