- Formula: Cl2
- Molecular weight: 70.906
- IUPAC Standard InChI:
- Download the identifier in a file.
- IUPAC Standard InChIKey: KZBUYRJDOAKODT-UHFFFAOYSA-N
- CAS Registry Number: 7782-50-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
- Other names: Cl2; Bertholite; Chloor; Chlor; Chlore; Chlorine mol.; Cloro; Molecular chlorine; UN 1017; Diatomic chlorine
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Ion clustering data
Go To: Top, References, Notes
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
+ = ( )
By formula: Cl- + Cl2 = (Cl- Cl2)
|rH°||71.1||kJ/mol||SAMS||Robbiani and Franklin, 1979||gas phase; based on Cl- + SO2Cl2 <--> Cl3- + SO2; National Bureau of Standards, 1968; M|
+ = Cl3-
By formula: Cl- + Cl2 = Cl3-
|rH°||99.2 ± 5.0||kJ/mol||CIDT||Nizzi, Pommerening, et al., 1998||gas phase; B|
|rH°||69.87||kJ/mol||Ther||Robbiani and Franklin, 1979, 2||gas phase; «DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2; B|
|rH°||<182.4||kJ/mol||PDis||Lee, Smith, et al., 1979||gas phase; B|
Go To: Top, Ion clustering data, Notes
Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L., Negative ion-molecule reaction in sulfuryl halides, J. Am. Chem. Soc., 1979, 101, 3709. [all data]
National Bureau of Standards, 1968
National Bureau of Standards, US, Technical Note 270 - 3 in The NBS Tables of Chemical Thermodynamic Properties, 1968. [all data]
Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S., Gas-phase thermochemistry of polyhalide anions, J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508 . [all data]
Robbiani and Franklin, 1979, 2
Robbiani, R.; Franklin, J.L., Formation of the trihalide ion Cl3- in the gas phase, J. Am. Chem. Soc., 1979, 101, 764. [all data]
Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-, J. Chem. Phys., 1979, 70, 3237. [all data]
Go To: Top, Ion clustering data, References
- Symbols used in this document:
rH° Enthalpy of reaction at standard conditions
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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