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Oxygen

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 70

(Oxygen anion bullet Oxygen) + Oxygen = (Oxygen anion bullet 2Oxygen)

By formula: (O2- bullet O2) + O2 = (O2- bullet 2O2)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 2Oxygen) + Oxygen = (O3- bullet 3Oxygen)

By formula: (O3- bullet 2O2) + O2 = (O3- bullet 3O2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSHiraoka, 1988, 2gas phase; M

(O3- bullet 3Oxygen) + Oxygen = (O3- bullet 4Oxygen)

By formula: (O3- bullet 3O2) + O2 = (O3- bullet 4O2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar64.4J/mol*KPHPMSHiraoka, 1988, 2gas phase; M

(O3- bullet Oxygen) + Oxygen = (O3- bullet 2Oxygen)

By formula: (O3- bullet O2) + O2 = (O3- bullet 2O2)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 0.8kJ/molPHPMSHiraoka, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar81.2J/mol*KPHPMSHiraoka, 1988, 2gas phase; M

O4- + Nitrogen + Oxygen = N2O4-

By formula: O4- + N2 + O2 = N2O4-

Quantity Value Units Method Reference Comment
Deltar12.1 ± 0.84kJ/molTDAsHiraoka, 1988, 2gas phase; B
Quantity Value Units Method Reference Comment
Deltar-8.8 ± 2.1kJ/molTDAsHiraoka, 1988, 2gas phase; B

Methane, bromotrinitro- + 218.5Water + 11.25Oxygen + Diethyl Phthalate = Hydrogen bromide + 13Carbon dioxide + 1.5Nitrogen

By formula: CBrN3O6 + 218.5H2O + 11.25O2 + C12H14O4 = HBr + 13CO2 + 1.5N2

Quantity Value Units Method Reference Comment
Deltar-6350.2 ± 1.0kJ/molCcrCarpenter, Zimmer, et al., 1970liquid phase; The HBr is in 225H2O; ALS

HO2+ + Oxygen = (HO2+ bullet Oxygen)

By formula: HO2+ + O2 = (HO2+ bullet O2)

Quantity Value Units Method Reference Comment
Deltar83.7kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

2-Fluoro-N-(2-fluoro-2,2-dinitroethyl)-N,2,2-trinitroethylamine + 6Oxygen + Ethanedioic acid, diethyl ester = 10Carbon dioxide + 2hydrogen fluoride + 3Nitrogen + 6Water

By formula: C4H4F2N6O10 + 6O2 + C6H10O4 = 10CO2 + 2HF + 3N2 + 6H2O

Quantity Value Units Method Reference Comment
Deltar-4976.2 ± 2.3kJ/molCcrBaroody and Carpenter, 1973solid phase; Corrected for CODATA value of «DELTA»fH; HF.100H2O; ALS

(Oxygen cation bullet Nitrogen bullet Oxygen) + Nitrogen = (Oxygen cation bullet 2Nitrogen bullet Oxygen)

By formula: (O2+ bullet N2 bullet O2) + N2 = (O2+ bullet 2N2 bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
2.230.HPMSSpeller and Fitaire, 1983gas phase; M

Benzene, 1,1',1'',1''',1'''',1'''''-(1,2-ethanediylidyne)hexakis- + Oxygen = Bis(triphenylmethyl)peroxide

By formula: C38H30 + O2 = C38H30O2

Quantity Value Units Method Reference Comment
Deltar-190.4 ± 2.1kJ/molCmBent, Cuthbertson, et al., 1936solid phase; Heat of oxidation; ALS

C13H14O + Oxygen = Naphth[2,3-b]oxiren-2(1aH)-one, 7,7a-dihydro-7-hydroxy-1a,7,7a-trimethyl-

By formula: C13H14O + O2 = C13H14O3

Quantity Value Units Method Reference Comment
Deltar-222.3kJ/molCmArnett, Dowd, et al., 1992liquid phase; solvent: THF; ALS

2,4-Dimethyl-1-naphthol + Oxygen = Naphth[2,3-b]oxiren-2(1aH)-one, 7,7a-dihydro-7-hydroxy-1a,7-dimethyl-

By formula: C12H12O + O2 = C12H12O3

Quantity Value Units Method Reference Comment
Deltar-250.8kJ/molCmArnett, Dowd, et al., 1992liquid phase; solvent: THF; ALS

Lithium ion (1+) + Oxygen = (Lithium ion (1+) bullet Oxygen)

By formula: Li+ + O2 = (Li+ bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.319.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Sodium ion (1+) + Oxygen = (Sodium ion (1+) bullet Oxygen)

By formula: Na+ + O2 = (Na+ bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
0.8310.DTKeller and Beyer, 1971gas phase; low E/N; M

Oxygen + Benzene, 1,1'-(diazomethylene)bis- = Nitrogen + Oxonium, (diphenylmethylene)hydroxy-, hydroxide, inner salt

By formula: O2 + C13H10N2 = N2 + C13H10O2

Quantity Value Units Method Reference Comment
Deltar-201. ± 3.kJ/molCphaHartstock, Kanabus-Kaminska, et al., 1989liquid phase; ALS

(Oxygen cation bullet 2Oxygen) + Oxygen = (Oxygen cation bullet 3Oxygen)

By formula: (O+ bullet 2O2) + O2 = (O+ bullet 3O2)

Quantity Value Units Method Reference Comment
Deltar4.kJ/molPILinn, Ono, et al., 1981gas phase; M

(Oxygen cation bullet Oxygen) + Oxygen = (Oxygen cation bullet 2Oxygen)

By formula: (O+ bullet O2) + O2 = (O+ bullet 2O2)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molPILinn, Ono, et al., 1981gas phase; M

1,3-Cyclohexadiene + Oxygen = Bicyclo[2.2.2]oct-5-ene-2,3-dione

By formula: C6H8 + O2 = C8H8O2

Quantity Value Units Method Reference Comment
Deltar-175. ± 20.kJ/molCphaOlmsted, 1980liquid phase; solvent: CCl4; ALS

Calcium ion (1+) + Oxygen = (Calcium ion (1+) bullet Oxygen)

By formula: Ca+ + O2 = (Ca+ bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.296.FASpears and Fehsenfeld, 1972gas phase; M

perbenzoic acid = Benzaldehyde + Oxygen

By formula: C7H6O3 = C7H6O + O2

Quantity Value Units Method Reference Comment
Deltar253.kJ/molCmBriner and Chastonay, 1954solid phase; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, 1988
Hiraoka, K., A Determination of the Stabilities of O2+(O2)n and O2-(O2)n with n = 1 - 8 from Measurements of the Gas-Phase Ion Equilibria, J. Chem. Phys., 1988, 89, 5, 3190, https://doi.org/10.1063/1.454976 . [all data]

Hiraoka, 1988, 2
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Carpenter, Zimmer, et al., 1970
Carpenter, G.A.; Zimmer, M.F.; Baroody, E.E.; Robb, R.A., Enthalpy of formation of bromotrinitromethane, J. Chem. Eng. Data, 1970, 15, 553-556. [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Baroody and Carpenter, 1973
Baroody, E.E.; Carpenter, G.A., Enthalpies of formation of some fluorodinitroethyl derivatives and 2,2',4,4',6,6'-hexanitroazobenzene, J. Chem. Eng. Data, 1973, 18, 28-36. [all data]

Speller and Fitaire, 1983
Speller, C.V.; Fitaire, M., Proceedings of the 16th International Conference on Phenomena of Ionized Gases, H. Boetticher, H. Wenk and E. Shulz - Gulde, ed(s)., ICPIG, Dusseldorf, 1983, 568. [all data]

Bent, Cuthbertson, et al., 1936
Bent, H.E.; Cuthbertson, G.R.; Dorfman, M.; Leary, R.E., Single bond energies. I. The C-C bond in hexaphenylethane, J. Am. Chem. Soc., 1936, 58, 165-170. [all data]

Arnett, Dowd, et al., 1992
Arnett, E.M.; Dowd, P.; Flowers, R.A., II; Ham, S.W.; Naganathan, S., Thermochemical confirmation of the mechanism of action of vitamin K, J. Am. Chem. Soc., 1992, 114, 9209-9210. [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A., CO2 and O2 Clustering to Sodium Ions, J. Geophys. Res., 1971, 74, 1, 289, https://doi.org/10.1029/JA076i001p00289 . [all data]

Hartstock, Kanabus-Kaminska, et al., 1989
Hartstock, F.W.; Kanabus-Kaminska, J.M.; Griller, D., Heat of formation of benzophenone oxide [1], Int. J. Chem. Kinet., 1989, 21, 157-163. [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., A Study of the Ion - Molecule Half Reactions O2+(a4piu, v)...(O2)m ---> O2m+1 + O, m=1, 2, 3, Using the Molecular Beam Photoionization Method, J. Chem. Phys., 1981, 74, 6, 3348, https://doi.org/10.1063/1.441487 . [all data]

Olmsted, 1980
Olmsted, J., III, Photocalorimetric studies of singlet oxygen reactions, J. Am. Chem. Soc., 1980, 102, 66-71. [all data]

Spears and Fehsenfeld, 1972
Spears, K.G.; Fehsenfeld, F.C., Termolecular Association Reactions of Mg, Ca, and Ba Ions, J. Chem. Phys., 1972, 56, 11, 5698, https://doi.org/10.1063/1.1677091 . [all data]

Briner and Chastonay, 1954
Briner, E.; Chastonay, P., Etude thermochemique de l'autoxydation de Valdehyde benzoique, Helv. Chim. Acta, 1954, 238, 539-541. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References