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Deuterium

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Cobalt ion (1+) + Deuterium = (Cobalt ion (1+) bullet Deuterium)

By formula: Co+ + D2 = (Co+ bullet D2)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.1 (+1.6,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID

D3+ + Deuterium = (D3+ bullet Deuterium)

By formula: D3+ + D2 = (D3+ bullet D2)

Quantity Value Units Method Reference Comment
Deltar7.1 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar18.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet Deuterium) + Deuterium = (D3+ bullet 2Deuterium)

By formula: (D3+ bullet D2) + D2 = (D3+ bullet 2D2)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 0.2kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 2Deuterium) + Deuterium = (D3+ bullet 3Deuterium)

By formula: (D3+ bullet 2D2) + D2 = (D3+ bullet 3D2)

Quantity Value Units Method Reference Comment
Deltar3.4 ± 0.2kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 3Deuterium) + Deuterium = (D3+ bullet 4Deuterium)

By formula: (D3+ bullet 3D2) + D2 = (D3+ bullet 4D2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 4Deuterium) + Deuterium = (D3+ bullet 5Deuterium)

By formula: (D3+ bullet 4D2) + D2 = (D3+ bullet 5D2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar19.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 5Deuterium) + Deuterium = (D3+ bullet 6Deuterium)

By formula: (D3+ bullet 5D2) + D2 = (D3+ bullet 6D2)

Quantity Value Units Method Reference Comment
Deltar1.7 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 6Deuterium) + Deuterium = (D3+ bullet 7Deuterium)

By formula: (D3+ bullet 6D2) + D2 = (D3+ bullet 7D2)

Quantity Value Units Method Reference Comment
Deltar0.9 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar12.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 7Deuterium) + Deuterium = (D3+ bullet 8Deuterium)

By formula: (D3+ bullet 7D2) + D2 = (D3+ bullet 8D2)

Quantity Value Units Method Reference Comment
Deltar0.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar15.3cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 8Deuterium) + Deuterium = (D3+ bullet 9Deuterium)

By formula: (D3+ bullet 8D2) + D2 = (D3+ bullet 9D2)

Quantity Value Units Method Reference Comment
Deltar0.7 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 9Deuterium) + Deuterium = (D3+ bullet 10Deuterium)

By formula: (D3+ bullet 9D2) + D2 = (D3+ bullet 10D2)

Quantity Value Units Method Reference Comment
Deltar0.6kcal/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Thermochemical Stabilities of D3+(D2)n with n = 1 - 10, Chem. Phys. Lett., 1989, 157, 5, 467, https://doi.org/10.1016/0009-2614(89)87282-3 . [all data]


Notes

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