Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Ethanone, 1-phenyl-2,2-bis(2,4,6-trimethylphenyl)-


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.7 ± 0.1PELecoultre, Heilbronner, et al., 1986LBLHLM
7.6 ± 0.1EIBiali, Lifshitz, et al., 1981LLK
8.3 ± 0.05PELecoultre, Heilbronner, et al., 1986Vertical value; LBLHLM

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lecoultre, Heilbronner, et al., 1986
Lecoultre, J.; Heilbronner, E.; Biali, S.E.; Rappoport, Z., 223. Ionization energies of 1-R-2,2-dimesitylethenols, 1,2-dimesityl-2-phenylethenol, and some of their keto tautomers, Helv. Chim. Acta, 1986, 69, 2108. [all data]

Biali, Lifshitz, et al., 1981
Biali, S.E.; Lifshitz, C.; Rappoport, Z., Thermochemistry and unimolecular reactions of ionized 1,2-dimesityl-2-phenylethanone and 2,2-dimesityl-1-phenylethanone and their enols and enol acetates in the gas phase, J. Am. Chem. Soc., 1981, 103, 2896. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References