Lead dichloride
- Formula: Cl2Pb
- Molecular weight: 278.1
- IUPAC Standard InChI: InChI=1S/2ClH.Pb/h2*1H;/q;;+2/p-2
- IUPAC Standard InChIKey: HWSZZLVAJGOAAY-UHFFFAOYSA-L
- CAS Registry Number: 7758-95-4
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.2 | PE | Novak and Potts, 1984 | LBLHLM |
| 10.3 ± 0.1 | EI | Hastie, Bloom, et al., 1967 | RDSH |
| 11.2 ± 0.2 | EI | Bloom and Hastie, 1966 | RDSH |
| 10.34 | PE | Novak and Potts, 1984 | Vertical value; LBLHLM |
| 10.11 | PE | Berkowitz, 1972 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| PbCl+ | 10.7 ± 0.1 | Cl | EI | Hastie, Bloom, et al., 1967 | RDSH |
| PbCl+ | ~7.1 | Cl- | EI | Hastie, Bloom, et al., 1967 | RDSH |
| PbCl+ | 11.7 ± 0.2 | Cl | EI | Bloom and Hastie, 1966 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Novak and Potts, 1984
Novak, I.; Potts, A.W.,
Ultraviolet photoelectron spectra of gas phase and condensed tin and lead dihalides (MX2, M = Sn, Pb X = Cl, Br, I),
J. Electron Spectrosc. Relat. Phenom., 1984, 33, 1. [all data]
Hastie, Bloom, et al., 1967
Hastie, J.W.; Bloom, H.; Morrison, J.D.,
Electronimpact studies of PbCl2, PbBr2, and PbClBr,
J. Chem. Phys., 1967, 47, 1580. [all data]
Bloom and Hastie, 1966
Bloom, H.; Hastie, J.W.,
Vapour phase composition above molten salt mixtures: a mass spectrometric study,
Australian J. Chem., 1966, 19, 1003. [all data]
Berkowitz, 1972
Berkowitz, J.,
Photoelectron spectroscopic studies with a cylindrical-mirror analyzer
in Electron Spectroscopy, ed. D.A. Shirley (North-Holland Pub. Co., Amsterdam), 1972. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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