cerium trifluoride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + CeF3 = (Fluorine anion • CeF3)

By formula: F- + CeF3 = (F- • CeF3)

Quantity Value Units Method Reference Comment
Δr109.7 ± 7.0kcal/molTherSidorov, Sorokin, et al., 1981gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.4EIRoberts and Searcy, 1972LLK
28.0 ± 0.7EIZmbov and Margrave, 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Ce+25.2?EIRoberts and Searcy, 1972LLK
FCe+17.2?EIRoberts and Searcy, 1972LLK
CeF+20.5 ± 0.7?EIZmbov and Margrave, 1968RDSH
CeF+13.0 ± 0.7FEIZmbov and Margrave, 1968RDSH
F2Ce+13.5?EIRoberts and Searcy, 1972LLK

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + CeF3 = (Fluorine anion • CeF3)

By formula: F- + CeF3 = (F- • CeF3)

Quantity Value Units Method Reference Comment
Δr109.7 ± 7.0kcal/molTherSidorov, Sorokin, et al., 1981gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sidorov, Sorokin, et al., 1981
Sidorov, L.N.; Sorokin, I.D.; Nitikin, N.I.; Skokan, E.V., Effusion method for determining the electron affinity and heat of formation of negative ions, Int. J. Mass Spectrom. Ion Phys., 1981, 39, 311. [all data]

Roberts and Searcy, 1972
Roberts, J.A., Jr.; Searcy, A.W., The stabilities of Ce2F6(g) and La2F6(g), High Temp. Sci., 1972, 4, 411. [all data]

Zmbov and Margrave, 1968
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies of scandium, yttrium, lanthanum, and rare-earth fluorides, Advan. Chem. Ser., 1968, 72, 267. [all data]


Notes

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