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H2S+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 34710 ± 12 gas Potts and Price, 1972
Hochlaf, Weitzel, et al., 2004


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 2259 T gas PE Karlsson, Mattsson, et al., 1976
2 Bend 800 T gas TPE Hochlaf, Weitzel, et al., 2004

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 18518 gas A-X 400 500 Dixon, Duxbury, et al., 1971
Potts and Price, 1972
Duxbury, Horani, et al., 1972
Karlsson, Mattsson, et al., 1976
Baltzer, Karlsson, et al., 1995
Hochlaf, Weitzel, et al., 2004
Han, Kang, et al., 2010


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 2600 T gas PE Baltzer, Karlsson, et al., 1995
2 Bend 950 ± 5 gas PE Potts and Price, 1972
Karlsson, Mattsson, et al., 1976
Baltzer, Karlsson, et al., 1995

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 2496 gas PE TPE Baltzer, Karlsson, et al., 1995
Hochlaf, Weitzel, et al., 2004
2 Bend 1159.0 gas EF TPE Duxbury, Horani, et al., 1972
Baltzer, Karlsson, et al., 1995
Hochlaf, Weitzel, et al., 2004

Additional references: Jacox, 1994, page 24; Jacox, 1998, page 135; Moehlmann and de Heer, 1975

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Potts and Price, 1972
Potts, A.W.; Price, W.C., Photoelectron spectra and valence shell orbital structures of groups V VI hydrides, Proc. R. Soc. London A:, 1972, 326, 181. [all data]

Hochlaf, Weitzel, et al., 2004
Hochlaf, M.; Weitzel, K.-M.; Ng, C.Y., Vacuum ultraviolet pulsed-field ionization-photoelectron study of H[sub 2]S in the energy range of 10--17 eV, J. Chem. Phys., 2004, 120, 15, 6944, https://doi.org/10.1063/1.1669386 . [all data]

Karlsson, Mattsson, et al., 1976
Karlsson, L.; Mattsson, L.; Jadrny, R.; Bergmark, T.; Siegbahn, K., Vibrational ans vibronic structure in the valence electron spectrum of H2S, Phys. Scr., 1976, 13, 229. [all data]

Dixon, Duxbury, et al., 1971
Dixon, R.N.; Duxbury, G.; Horani, M.; Rostas, J., The H, Mol. Phys., 1971, 22, 6, 977, https://doi.org/10.1080/00268977100103311 . [all data]

Duxbury, Horani, et al., 1972
Duxbury, G.; Horani, M.; Rostas, J., Rotational Analysis of the Electronic Emission Spectrum of the HFormulaSFormula Ion Radical, Proc. Roy. Soc. (London) A331, 1972, 331, 1584, 109, https://doi.org/10.1098/rspa.1972.0167 . [all data]

Baltzer, Karlsson, et al., 1995
Baltzer, P.; Karlsson, L.; Lundqvist, M.; Wannberg, B.; Holland, D.M.P.; MacDonald, M.A., An experimental study of the valence shell photoelectron spectrum of hydrogen sulphide, Chem. Phys., 1995, 195, 1-3, 403, https://doi.org/10.1016/0301-0104(95)00053-Q . [all data]

Han, Kang, et al., 2010
Han, S.; Kang, T.Y.; Kim, S.K., Rotationally resolved spectroscopy of the A [sup 2]A[sub 1]<--X [sup 2]B[sub 1] transition of H[sub 2]S[sup +] above the barrier to linearity using the mass-analyzed threshold ionization photofragment excitation technique, J. Chem. Phys., 2010, 132, 12, 124304, https://doi.org/10.1063/1.3358252 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Moehlmann and de Heer, 1975
Moehlmann, G.R.; de Heer, F.J., Lifetimes of the vibronic Ã2A1 states of H2S+, Chem. Phys. Lett., 1975, 36, 3, 353, https://doi.org/10.1016/0009-2614(75)80254-5 . [all data]


Notes

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