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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 601 to 650

C3H9O+ + Water = (C3H9O+ bullet Water)

By formula: C3H9O+ + H2O = (C3H9O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

C4H10N+ + Water = (C4H10N+ bullet Water)

By formula: C4H10N+ + H2O = (C4H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar57.3kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H11O2+ + Water = (C4H11O2+ bullet Water)

By formula: C4H11O2+ + H2O = (C4H11O2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.6kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C4H8N+ + Water = (C4H8N+ bullet Water)

By formula: C4H8N+ + H2O = (C4H8N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar80.3kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C4H8N+ + Water = (C4H8N+ bullet Water)

By formula: C4H8N+ + H2O = (C4H8N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C4H9O+ + Water = (C4H9O+ bullet Water)

By formula: C4H9O+ + H2O = (C4H9O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C6H15O+ + Water = (C6H15O+ bullet Water)

By formula: C6H15O+ + H2O = (C6H15O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar78.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar119.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C6H15O3+ + Water = (C6H15O3+ bullet Water)

By formula: C6H15O3+ + H2O = (C6H15O3+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar73.6kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar146.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C6H16N+ + Water = (C6H16N+ bullet Water)

By formula: C6H16N+ + H2O = (C6H16N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C6H5N2+ + Water = (C6H5N2+ bullet Water)

By formula: C6H5N2+ + H2O = (C6H5N2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

C6H8N+ + Water = (C6H8N+ bullet Water)

By formula: C6H8N+ + H2O = (C6H8N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.5kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

C7H10N+ + Water = (C7H10N+ bullet Water)

By formula: C7H10N+ + H2O = (C7H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C7H11N2+ + Water = (C7H11N2+ bullet Water)

By formula: C7H11N2+ + H2O = (C7H11N2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar50.2kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

C7H6N+ + Water = (C7H6N+ bullet Water)

By formula: C7H6N+ + H2O = (C7H6N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar79.1kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C8H12N+ + Water = (C8H12N+ bullet Water)

By formula: C8H12N+ + H2O = (C8H12N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar59.4kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C9H14N+ + Water = (C9H14N+ bullet Water)

By formula: C9H14N+ + H2O = (C9H14N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar59.4kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar129.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

phenoxide anion + Water = (phenoxide anion bullet Water)

By formula: C6H5O- + H2O = (C6H5O- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.4kJ/molPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M

(Magnesium ion (1+) bullet 2Water) + Water = (Magnesium ion (1+) bullet 3Water)

By formula: (Mg+ bullet 2H2O) + H2O = (Mg+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar72.4 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
72.4 (+8.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet 3Water) + Water = (Magnesium ion (1+) bullet 4Water)

By formula: (Mg+ bullet 3H2O) + H2O = (Mg+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
48.1 (+8.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) bullet Water) + Water = (Magnesium ion (1+) bullet 2Water)

By formula: (Mg+ bullet H2O) + H2O = (Mg+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar93.3 ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
93.7 (+6.7,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

C2H5F3N+ + Water = (C2H5F3N+ bullet Water)

By formula: C2H5F3N+ + H2O = (C2H5F3N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar88.3kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

C2H8N+ + Water = (C2H8N+ bullet Water)

By formula: C2H8N+ + H2O = (C2H8N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar73.2kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

2,5,8,11-Tetraoxadodecane + Water = (2,5,8,11-Tetraoxadodecane bullet Water)

By formula: C8H18O4 + H2O = (C8H18O4 bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar85.4kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar168.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

Diacetamide + Water = Acetamide + Acetic acid

By formula: C4H7NO2 + H2O = C2H5NO + C2H4O2

Quantity Value Units Method Reference Comment
Deltar-18.1 ± 0.2kJ/molCmHill and Wadso, 1968solid phase; Heat of hydrolysis; ALS
Deltar-18.1 ± 0.2kJ/molCmWadso, 1965solid phase; Heat of hydrolysis; ALS

(O2S- bullet 2Sulfur dioxide) + Water = (O2S- bullet Water bullet 2Sulfur dioxide)

By formula: (O2S- bullet 2O2S) + H2O = (O2S- bullet H2O bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar31.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.1 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 3Sulfur dioxide) + Water = (O2S- bullet Water bullet 3Sulfur dioxide)

By formula: (O2S- bullet 3O2S) + H2O = (O2S- bullet H2O bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar31.8 ± 1.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar14.2 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 4Sulfur dioxide) + Water = (O2S- bullet Water bullet 4Sulfur dioxide)

By formula: (O2S- bullet 4O2S) + H2O = (O2S- bullet H2O bullet 4O2S)

Quantity Value Units Method Reference Comment
Deltar31.4 ± 1.7kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.8 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 5Sulfur dioxide) + Water = (O2S- bullet Water bullet 5Sulfur dioxide)

By formula: (O2S- bullet 5O2S) + H2O = (O2S- bullet H2O bullet 5O2S)

Quantity Value Units Method Reference Comment
Deltar27.2 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet Sulfur dioxide) + Water = (O2S- bullet Water bullet Sulfur dioxide)

By formula: (O2S- bullet O2S) + H2O = (O2S- bullet H2O bullet O2S)

Quantity Value Units Method Reference Comment
Deltar37.2 ± 3.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

C2H5O+ + Water = (C2H5O+ bullet Water)

By formula: C2H5O+ + H2O = (C2H5O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar105.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H5O2+ + Water = (C2H5O2+ bullet Water)

By formula: C2H5O2+ + H2O = (C2H5O2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar90.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C3H4N2+ + Water = (C3H4N2+ bullet Water)

By formula: C3H4N2+ + H2O = (C3H4N2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.9kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H7O+ + Water = (C3H7O+ bullet Water)

By formula: C3H7O+ + H2O = (C3H7O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar85.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C5H9O+ + Water = (C5H9O+ bullet Water)

By formula: C5H9O+ + H2O = (C5H9O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar76.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C7H11O+ + Water = (C7H11O+ bullet Water)

By formula: C7H11O+ + H2O = (C7H11O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar69.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C8H9O + Water = (C8H9O bullet Water)

By formula: C8H9O + H2O = (C8H9O bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar81.6kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar122.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(Vanadium ion (1+) bullet 2Water) + Water = (Vanadium ion (1+) bullet 3Water)

By formula: (V+ bullet 2H2O) + H2O = (V+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar51.0kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
68.2 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Bromine anion bullet 14Water) + Water = (Bromine anion bullet 15Water)

By formula: (Br- bullet 14H2O) + H2O = (Br- bullet 15H2O)

Quantity Value Units Method Reference Comment
Deltar-2. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

Acetyl iodide + Water = Hydrogen iodide + Acetic acid

By formula: C2H3IO + H2O = HI + C2H4O2

Quantity Value Units Method Reference Comment
Deltar-93.97kJ/molCmDevore and O'Neal, 1969liquid phase; Heat of hydrolysis; ALS
Deltar-90.33kJ/molCmCarson and Skinner, 1949liquid phase; Heat of hydrolysis; ALS

(Iron ion (1+) bullet Water) + Water = (Iron ion (1+) bullet 2Water)

By formula: (Fe+ bullet H2O) + H2O = (Fe+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar171.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
164. (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) bullet Water) + Water = (Chromium ion (1+) bullet 2Water)

By formula: (Cr+ bullet H2O) + H2O = (Cr+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar123.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
142. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) bullet Water) + Water = (Manganese ion (1+) bullet 2Water)

By formula: (Mn+ bullet H2O) + H2O = (Mn+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar74.5kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
90.0 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) bullet Water) + Water = (Vanadium ion (1+) bullet 2Water)

By formula: (V+ bullet H2O) + H2O = (V+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar149.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
151. (+10.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) bullet Water) + Water = (Nickel ion (1+) bullet 2Water)

By formula: (Ni+ bullet H2O) + H2O = (Ni+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar170.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
168. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Water = (Cobalt ion (1+) bullet 2Water)

By formula: (Co+ bullet H2O) + H2O = (Co+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar175.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
162. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Bromine anion bullet 10Water) + Water = (Bromine anion bullet 11Water)

By formula: (Br- bullet 10H2O) + H2O = (Br- bullet 11H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 11Water) + Water = (Bromine anion bullet 12Water)

By formula: (Br- bullet 11H2O) + H2O = (Br- bullet 12H2O)

Quantity Value Units Method Reference Comment
Deltar10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 12Water) + Water = (Bromine anion bullet 13Water)

By formula: (Br- bullet 12H2O) + H2O = (Br- bullet 13H2O)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 13Water) + Water = (Bromine anion bullet 14Water)

By formula: (Br- bullet 13H2O) + H2O = (Br- bullet 14H2O)

Quantity Value Units Method Reference Comment
Deltar13. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 15Water) + Water = (Bromine anion bullet 16Water)

By formula: (Br- bullet 15H2O) + H2O = (Br- bullet 16H2O)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takimoto, et al., 1986
Hiraoka, K.; Takimoto, H.; Morise, K., Gas-Phase Hydration Reactions of Protonated Alcohols. Energetics and Bulk Hydration of Cluster Ions, J. Am. Chem. Soc., 1986, 108, 19, 5683, https://doi.org/10.1021/ja00279a004 . [all data]

Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S., Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms, J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]

Speller and Meot-Ner (Mautner), 1985
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Notes

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