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Water

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 501 to 550

(Lithium ion (1+) bullet Water) + Water = (Lithium ion (1+) bullet 2Water)

By formula: (Li+ bullet H2O) + H2O = (Li+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

C5H12NO2+ + Water = (C5H12NO2+ bullet Water)

By formula: C5H12NO2+ + H2O = (C5H12NO2+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar80.8kJ/molPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar152.J/mol*KPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M

(C3H9O+ bullet 2Water) + Water = (C3H9O+ bullet 3Water)

By formula: (C3H9O+ bullet 2H2O) + H2O = (C3H9O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 3Water) + Water = (C3H9O+ bullet 4Water)

By formula: (C3H9O+ bullet 3H2O) + H2O = (C3H9O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 2Water) + Water = (C3H9O+ bullet 3Water)

By formula: (C3H9O+ bullet 2H2O) + H2O = (C3H9O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 3Water) + Water = (C3H9O+ bullet 4Water)

By formula: (C3H9O+ bullet 3H2O) + H2O = (C3H9O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C4H11O2+ bullet 2Water) + Water = (C4H11O2+ bullet 3Water)

By formula: (C4H11O2+ bullet 2H2O) + H2O = (C4H11O2+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.3kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 3Water) + Water = (C4H11O2+ bullet 4Water)

By formula: (C4H11O2+ bullet 3H2O) + H2O = (C4H11O2+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 4Water) + Water = (C4H11O2+ bullet 5Water)

By formula: (C4H11O2+ bullet 4H2O) + H2O = (C4H11O2+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ bullet 2Water) + Water = (C6H15O+ bullet 3Water)

By formula: (C6H15O+ bullet 2H2O) + H2O = (C6H15O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ bullet 3Water) + Water = (C6H15O+ bullet 4Water)

By formula: (C6H15O+ bullet 3H2O) + H2O = (C6H15O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar99.2J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ bullet 4Water) + Water = (C6H15O+ bullet 5Water)

By formula: (C6H15O+ bullet 4H2O) + H2O = (C6H15O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(HO- bullet 7Water) + Water = (HO- bullet 8Water)

By formula: (HO- bullet 7H2O) + H2O = (HO- bullet 8H2O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Deltar11. ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; Entropy estimated; B

(CH3O- bullet 3Water) + Water = (CH3O- bullet 4Water)

By formula: (CH3O- bullet 3H2O) + H2O = (CH3O- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

C13H22N+ + Water = (C13H22N+ bullet Water)

By formula: C13H22N+ + H2O = (C13H22N+ bullet H2O)

Bond type: Hydrogen bonds with steric hindrance in positive ions

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar170.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

(C2H7O+ bullet 4Water) + Water = (C2H7O+ bullet 5Water)

By formula: (C2H7O+ bullet 4H2O) + H2O = (C2H7O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 4Water) + Water = (C3H9O+ bullet 5Water)

By formula: (C3H9O+ bullet 4H2O) + H2O = (C3H9O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 5Water) + Water = (C3H9O+ bullet 6Water)

By formula: (C3H9O+ bullet 5H2O) + H2O = (C3H9O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet Water) + Water = (C3H9O+ bullet 2Water)

By formula: (C3H9O+ bullet H2O) + H2O = (C3H9O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar74.9kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 4Water) + Water = (C3H9O+ bullet 5Water)

By formula: (C3H9O+ bullet 4H2O) + H2O = (C3H9O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 5Water) + Water = (C3H9O+ bullet 6Water)

By formula: (C3H9O+ bullet 5H2O) + H2O = (C3H9O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C4H10N+ bullet Water) + Water = (C4H10N+ bullet 2Water)

By formula: (C4H10N+ bullet H2O) + H2O = (C4H10N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C4H11O2+ bullet Water) + Water = (C4H11O2+ bullet 2Water)

By formula: (C4H11O2+ bullet H2O) + H2O = (C4H11O2+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar65.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H9O+ bullet Water) + Water = (C4H9O+ bullet 2Water)

By formula: (C4H9O+ bullet H2O) + H2O = (C4H9O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C5H11O+ bullet Water) + Water = (C5H11O+ bullet 2Water)

By formula: (C5H11O+ bullet H2O) + H2O = (C5H11O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C5H6N+ bullet 2Water) + Water = (C5H6N+ bullet 3Water)

By formula: (C5H6N+ bullet 2H2O) + H2O = (C5H6N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C6H15O+ bullet Water) + Water = (C6H15O+ bullet 2Water)

By formula: (C6H15O+ bullet H2O) + H2O = (C6H15O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O3+ bullet Water) + Water = (C6H15O3+ bullet 2Water)

By formula: (C6H15O3+ bullet H2O) + H2O = (C6H15O3+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H5N2+ bullet 2Water) + Water = (C6H5N2+ bullet 3Water)

By formula: (C6H5N2+ bullet 2H2O) + H2O = (C6H5N2+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C6H5N2+ bullet 3Water) + Water = (C6H5N2+ bullet 4Water)

By formula: (C6H5N2+ bullet 3H2O) + H2O = (C6H5N2+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar34.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C6H5N2+ bullet Water) + Water = (C6H5N2+ bullet 2Water)

By formula: (C6H5N2+ bullet H2O) + H2O = (C6H5N2+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.5kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(Chlorine anion bullet Water) + Hydrogen chloride = (Chlorine anion bullet Hydrogen chloride bullet Water)

By formula: (Cl- bullet H2O) + HCl = (Cl- bullet HCl bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; M

Trimethyl orthobutyrate + Water = Butanoic acid, methyl ester + 2Methyl Alcohol

By formula: C7H16O3 + H2O = C5H10O2 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar-26.24 ± 0.059kJ/molCmWiberg, Martin, et al., 1985liquid phase; solvent: Aqueous dioxane; ALS
Deltar-26.42 ± 0.059kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis; ALS

Pentane, 1,1,1-trimethoxy- + Water = Methyl valerate + 2Methyl Alcohol

By formula: C8H18O3 + H2O = C6H12O2 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar-25.53 ± 0.050kJ/molCmWiberg, Martin, et al., 1985liquid phase; solvent: Aqueous dioxane; ALS
Deltar-25.72 ± 0.03kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis; ALS

1,1,1-Trimethoxy-3-methylbutane + Water = Methyl isovalerate + 2Methyl Alcohol

By formula: C8H18O3 + H2O = C6H12O2 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar-30.52 ± 0.067kJ/molCmWiberg, Martin, et al., 1985liquid phase; solvent: Aqueous dioxane; ALS
Deltar-30.82 ± 0.063kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis; ALS

(C2H5F3N+ bullet 2Water) + Water = (C2H5F3N+ bullet 3Water)

By formula: (C2H5F3N+ bullet 2H2O) + H2O = (C2H5F3N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar59.4kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar122.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H8N+ bullet 2Water) + Water = (C2H8N+ bullet 3Water)

By formula: (C2H8N+ bullet 2H2O) + H2O = (C2H8N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar129.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C5H6N+ bullet Water) + Water = (C5H6N+ bullet 2Water)

By formula: (C5H6N+ bullet H2O) + H2O = (C5H6N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(2,5,8,11-Tetraoxadodecane bullet 2Water) + Water = (2,5,8,11-Tetraoxadodecane bullet 3Water)

By formula: (C8H18O4 bullet 2H2O) + H2O = (C8H18O4 bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C2H5F3N+ bullet Water) + Water = (C2H5F3N+ bullet 2Water)

By formula: (C2H5F3N+ bullet H2O) + H2O = (C2H5F3N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar72.4kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H8N+ bullet Water) + Water = (C2H8N+ bullet 2Water)

By formula: (C2H8N+ bullet H2O) + H2O = (C2H8N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.5kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(2,5,8,11-Tetraoxadodecane bullet 3Water) + Water = (2,5,8,11-Tetraoxadodecane bullet 4Water)

By formula: (C8H18O4 bullet 3H2O) + H2O = (C8H18O4 bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(2,5,8,11-Tetraoxadodecane bullet Water) + Water = (2,5,8,11-Tetraoxadodecane bullet 2Water)

By formula: (C8H18O4 bullet H2O) + H2O = (C8H18O4 bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.5kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar133.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(MeCO2 anion bullet CH3CONHCH(CH3)COOCH3) + Water = (MeCO2 anion bullet Water bullet CH3CONHCH(CH3)COOCH3)

By formula: (C2H3O2- bullet C6H11NO3) + H2O = (C2H3O2- bullet H2O bullet C6H11NO3)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H5O+ bullet 2Water) + Water = (C3H5O+ bullet 3Water)

By formula: (C3H5O+ bullet 2H2O) + H2O = (C3H5O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.6kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

(C3H5O+ bullet 3Water) + Water = (C3H5O+ bullet 4Water)

By formula: (C3H5O+ bullet 3H2O) + H2O = (C3H5O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar53.1kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

C6H12NO3+ + Water = (C6H12NO3+ bullet Water)

By formula: C6H12NO3+ + H2O = (C6H12NO3+ bullet H2O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(O2S- bullet 2Water bullet 3Sulfur dioxide) + Water = (O2S- bullet 3Water bullet 3Sulfur dioxide)

By formula: (O2S- bullet 2H2O bullet 3O2S) + H2O = (O2S- bullet 3H2O bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar27.6 ± 1.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.6 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 2Water bullet 4Sulfur dioxide) + Water = (O2S- bullet 3Water bullet 4Sulfur dioxide)

By formula: (O2S- bullet 2H2O bullet 4O2S) + H2O = (O2S- bullet 3H2O bullet 4O2S)

Quantity Value Units Method Reference Comment
Deltar29.7 ± 2.9kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.9 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 5Sulfur dioxide bullet 2Water) + Sulfur dioxide = (O2S- bullet 6Sulfur dioxide bullet 2Water)

By formula: (O2S- bullet 5O2S bullet 2H2O) + O2S = (O2S- bullet 6O2S bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar15.9 ± 3.8kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Meot-Ner and Field, 1974
Meot-Ner, (Mautner); Field, F.H., Solvation and Association of Protonated Gaseous Amino Acids, J. Am. Chem. Soc., 1974, 96, 10, 3168, https://doi.org/10.1021/ja00817a024 . [all data]

Hiraoka, Takimoto, et al., 1986
Hiraoka, K.; Takimoto, H.; Morise, K., Gas-Phase Hydration Reactions of Protonated Alcohols. Energetics and Bulk Hydration of Cluster Ions, J. Am. Chem. Soc., 1986, 108, 19, 5683, https://doi.org/10.1021/ja00279a004 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]

Meot-Ner (Mautner) and Speller, 1986
Meot-Ner (Mautner), M.; Speller, C.V., The Filling of Solvent Shells in Cluster Ions: Thermochemical Criteria nd the Effects of Isomeric Clusters, J. Phys. Chem., 1986, 90, 25, 6616, https://doi.org/10.1021/j100283a006 . [all data]

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]

Meot-Ner M. and Sieck, 1983
Meot-Ner M.; Sieck, L.W., The Ionic Hydrogen Bond. 1. Sterically Hindered Bonds. Solvation and Clustering of Sterically Hindered Amines and Pyridines, J. Am. Chem. Soc., 1983, 105, 10, 2956, https://doi.org/10.1021/ja00348a005 . [all data]

Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S., Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms, J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018 . [all data]

Davidson, Sunner J., et al., 1979
Davidson, W.R.; Sunner J.; Kebarle, P., Hydrogen Bonding of Water to Onium Ions. Hydration of Substituted Pyridinium Ions and Related Systems, J. Am. Chem. Soc., 1979, 101, 7, 1675, https://doi.org/10.1021/ja00501a005 . [all data]

Upschulte, Evans, et al., 1986
Upschulte, B.L.; Evans, D.H.; Keesee, R.G.; Castleman, A.W., Unpublished results, referred to in Keesee and Castleman, 1986, 1986. [all data]

Wiberg, Martin, et al., 1985
Wiberg, K.B.; Martin, E.J.; Squires, R.R., Thermochemical studies of carbonyl compounds. 3. Enthalpies of hydrolysis of ortho esters, J. Org. Chem., 1985, 50, 4717-4720. [all data]

Wiberg, 1980
Wiberg, K.B., Energies of organic compounds, Rept. DOE-E(11-1)4060 Prepared for US Dept. of Energy by Yale Univ., New Haven, CT. Avail. NTIS, 1980, 1-24. [all data]

Lau and Kebarle, 1981
Lau, Y.K.; Kebarle, P., Hydrogen Bonding Solvent Effect on the Basicity of Primary Amines CH3NH2, C2H5NH2, AND CF3CH2NH2, Can. J. Chem., 1981, 59, 1, 151, https://doi.org/10.1139/v81-024 . [all data]

Meot-Ner (Mautner), 1988
Meot-Ner (Mautner), M., Models for Strong Interactions in Proteins and Enzymes. 2. Interactions of Ions with the Peptide Link and Imidazole, J. Am. Chem. Soc., 1988, 110, 10, 3075, https://doi.org/10.1021/ja00218a014 . [all data]

Hiraoka and Kebarle, 1977
Hiraoka, K.; Kebarle, P., Condensation reactions involving carbonium ions in the gas phase synthesis of protonated acids in gaseous methane containing carbon monoxide and water vapor, J. Am. Chem. Soc., 1977, 99, 366. [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner), The Ionic Hydrogen Bond. 4. Intramolecular and Multiple Bonds. Proton Affinities, Hydration and Complexes of Amides and Amino Acid Derivatives, J. Am. Chem. Soc., 1984, 106, 2, 278, https://doi.org/10.1021/ja00314a003 . [all data]

Vacher, Leduc, et al., 1994
Vacher, J.R.; Leduc, E.; Fitaire, M., Stabilities of Anionic Mixed Clusters of Sulfur Dioxide and Water, Int. J. Mass Spectrom. Ion Proc., 1994, 135, 2-3, 139, https://doi.org/10.1016/0168-1176(94)03985-2 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]


Notes

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