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Water

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1251 to 1300

CAS Reg. No. 18610-42-9 + Water = C4H5O5-

By formula: CAS Reg. No. 18610-42-9 + H2O = C4H5O5-

Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C5H7O4-2 + Water = C5H9O5-

By formula: C5H7O4-2 + H2O = C5H9O5-

Quantity Value Units Method Reference Comment
Deltar23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C6H9O4-2 + Water = C6H11O5-

By formula: C6H9O4-2 + H2O = C6H11O5-

Quantity Value Units Method Reference Comment
Deltar23.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 22713-47-9 + Water = C10H8O7S2-2

By formula: CAS Reg. No. 22713-47-9 + H2O = C10H8O7S2-2

Quantity Value Units Method Reference Comment
Deltar32.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C7H11O4-2 + Water = C7H13O5-

By formula: C7H11O4-2 + H2O = C7H13O5-

Quantity Value Units Method Reference Comment
Deltar23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H13O4-2 + Water = C8H15O5-

By formula: C8H13O4-2 + H2O = C8H15O5-

Quantity Value Units Method Reference Comment
Deltar22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 3198-30-9 + 3Water = C8H10O7-2

By formula: CAS Reg. No. 3198-30-9 + 3H2O = C8H10O7-2

Quantity Value Units Method Reference Comment
Deltar35.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 48063-93-0 + Water = C9H17O5-

By formula: CAS Reg. No. 48063-93-0 + H2O = C9H17O5-

Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 48065-91-4 + Water = C10H19O5-

By formula: CAS Reg. No. 48065-91-4 + H2O = C10H19O5-

Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 93278-49-0 + Water = C5H9O5-

By formula: CAS Reg. No. 93278-49-0 + H2O = C5H9O5-

Quantity Value Units Method Reference Comment
Deltar35.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

Pentaerythritol + Nitric acid = C5H11NO6 + Water

By formula: C5H12O4 + HNO3 = C5H11NO6 + H2O

Quantity Value Units Method Reference Comment
Deltar-15.5kJ/molCmTsvetkov, Sopin, et al., 1986liquid phase; ALS

1,2-Ethanediol + Acetone = 1,3-Dioxolane, 2,2-dimethyl- + Water

By formula: C2H6O2 + C3H6O = C5H10O2 + H2O

Quantity Value Units Method Reference Comment
Deltar-10.kJ/molEqkAnteunis and Rommelaere, 1970liquid phase; ALS

1,2-Ethanediol + Nitric acid = 2-hydroxyethyl nitrate + Water

By formula: C2H6O2 + HNO3 = C2H5NO4 + H2O

Quantity Value Units Method Reference Comment
Deltar-7.9kJ/molCmTsvetkov, Sopin, et al., 1986liquid phase; ALS

Ethanol, 2,2'-oxybis- + Nitric acid = Ethanol, 2-(2-hydroxyethoxy)-, 1-nitrate + Water

By formula: C4H10O3 + HNO3 = C4H9NO5 + H2O

Quantity Value Units Method Reference Comment
Deltar-8.8kJ/molCmTsvetkov, Sopin, et al., 1986liquid phase; ALS

8-Hydroxyoctanoic acid = 2-Oxonanone + Water

By formula: C8H16O3 = C8H14O2 + H2O

Quantity Value Units Method Reference Comment
Deltar30.8 ± 0.54kJ/molCmWiberg and Waldron, 1991solid phase; ALS

10-Hydroxydecanoic acid = 2(3H)-Furanone, 5-hexyldihydro- + Water

By formula: C10H20O3 = C10H18O2 + H2O

Quantity Value Units Method Reference Comment
Deltar12.1 ± 0.67kJ/molCmWiberg and Waldron, 1991solid phase; ALS

Hexanoic acid, 6-hydroxy- = 2-Oxepanone + Water

By formula: C6H12O3 = C6H10O2 + H2O

Quantity Value Units Method Reference Comment
Deltar15.5 ± 0.3kJ/molCmWiberg and Waldron, 1991solid phase; ALS

7-Hydroxyheptanoic acid = Heptanolactone + Water

By formula: C7H14O3 = C7H12O2 + H2O

Quantity Value Units Method Reference Comment
Deltar30.2 ± 0.2kJ/molCmWiberg and Waldron, 1991solid phase; ALS

2-Pentanone, 5-(acetyloxy)- + Water = 2-Pentanone, 4-hydroxy- + Acetic acid

By formula: C7H12O3 + H2O = C5H10O2 + C2H4O2

Quantity Value Units Method Reference Comment
Deltar12.kJ/molEqkGrigor'ev, Katsman, et al., 1981liquid phase; ALS

CAS Reg. No. 1000-88-0 + Water = C3H5O5-

By formula: CAS Reg. No. 1000-88-0 + H2O = C3H5O5-

Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 15251-42-0 + 3Water = H8O10P2-2

By formula: CAS Reg. No. 15251-42-0 + 3H2O = H8O10P2-2

Quantity Value Units Method Reference Comment
Deltar37.2 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 15251-42-0 + 4Water = H10O11P2-2

By formula: CAS Reg. No. 15251-42-0 + 4H2O = H10O11P2-2

Quantity Value Units Method Reference Comment
Deltar33.1 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 15251-42-0 + 5Water = H12O12P2-2

By formula: CAS Reg. No. 15251-42-0 + 5H2O = H12O12P2-2

Quantity Value Units Method Reference Comment
Deltar28.0 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 207592-41-4 + Water = C5H10O9P-

By formula: CAS Reg. No. 207592-41-4 + H2O = C5H10O9P-

Quantity Value Units Method Reference Comment
Deltar24.3 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 73679-94-4 + 2Water = C10H17N5O12P2-2

By formula: CAS Reg. No. 73679-94-4 + 2H2O = C10H17N5O12P2-2

Quantity Value Units Method Reference Comment
Deltar33.1 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 73679-94-4 + 3Water = C10H19N5O13P2-2

By formula: CAS Reg. No. 73679-94-4 + 3H2O = C10H19N5O13P2-2

Quantity Value Units Method Reference Comment
Deltar28.5 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 73679-94-4 + 5Water = C10H23N5O15P2-2

By formula: CAS Reg. No. 73679-94-4 + 5H2O = C10H23N5O15P2-2

Quantity Value Units Method Reference Comment
Deltar23.4 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 73679-94-4 + 6Water = C10H25N5O16P2-2

By formula: CAS Reg. No. 73679-94-4 + 6H2O = C10H25N5O16P2-2

Quantity Value Units Method Reference Comment
Deltar21.3 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 73679-94-4 + 7Water = C10H27N5O17P2-2

By formula: CAS Reg. No. 73679-94-4 + 7H2O = C10H27N5O17P2-2

Quantity Value Units Method Reference Comment
Deltar19.2 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

Butanoic acid, 4-hydroxy- = Water + Butyrolactone

By formula: C4H8O3 = H2O + C4H6O2

Quantity Value Units Method Reference Comment
Deltar4.5 ± 0.2kJ/molCmWiberg and Waldron, 1991liquid phase; ALS

Neopentyl glycol + Acetone = 1,3 Dioxane, 2,2,5,5-tetramethyl- + Water

By formula: C5H12O2 + C3H6O = C8H16O2 + H2O

Quantity Value Units Method Reference Comment
Deltar-11.kJ/molEqkAnteunis and Rommelaere, 1970liquid phase; ALS

Propylene Glycol + Acetone = 1,3-Dioxolane, 2,2,4-trimethyl- + Water

By formula: C3H8O2 + C3H6O = C6H12O2 + H2O

Quantity Value Units Method Reference Comment
Deltar-3.kJ/molEqkAnteunis and Rommelaere, 1970liquid phase; ALS

Acetone + 1,2-Propanediol, 3-chloro- = 1,3-Dioxolane, 4-(chloromethyl)-2,2-dimethyl- + Water

By formula: C3H6O + C3H7ClO2 = C6H11ClO2 + H2O

Quantity Value Units Method Reference Comment
Deltar-12.kJ/molEqkAnteunis and Rommelaere, 1970liquid phase; ALS

1,3-Propanediol + Acetone = 1,3-Dioxane, 2,2-dimethyl- + Water

By formula: C3H8O2 + C3H6O = C6H12O2 + H2O

Quantity Value Units Method Reference Comment
Deltar-23.kJ/molEqkAnteunis and Rommelaere, 1970liquid phase; ALS

H18O12S2-2 + 10Water = H20O13S2-2

By formula: H18O12S2-2 + 10H2O = H20O13S2-2

Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

CAS Reg. No. 47287-36-5 + Water = C10H16N5O8P-

By formula: CAS Reg. No. 47287-36-5 + H2O = C10H16N5O8P-

Quantity Value Units Method Reference Comment
Deltar22.6 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 73679-94-4 + Water = C10H15N5O11P2-2

By formula: CAS Reg. No. 73679-94-4 + H2O = C10H15N5O11P2-2

Quantity Value Units Method Reference Comment
Deltar38.9 ± 0.84kJ/molIMREBlades, Ho, et al., 1996gas phase; B

CAS Reg. No. 920-52-5 + Water = C2H3O5-

By formula: CAS Reg. No. 920-52-5 + H2O = C2H3O5-

Quantity Value Units Method Reference Comment
Deltar26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

12-Hydroxydodecanoic acid = Water + Oxacyclotridecan-2-one

By formula: C12H24O3 = H2O + C12H22O2

Quantity Value Units Method Reference Comment
Deltar9. ± 4.kJ/molCmWiberg and Waldron, 1991solid phase; ALS

CH3LiO (cr) + Water (l) = HLiO (cr) + Methyl Alcohol (l)

By formula: CH3LiO (cr) + H2O (l) = HLiO (cr) + CH4O (l)

Quantity Value Units Method Reference Comment
Deltar-5.2 ± 2.3kJ/molRSCLeal and Martinho Simões, 1993MS

C2H5LiO (cr) + Water (l) = HLiO (cr) + Ethanol (l)

By formula: C2H5LiO (cr) + H2O (l) = HLiO (cr) + C2H6O (l)

Quantity Value Units Method Reference Comment
Deltar-3.6 ± 2.5kJ/molRSCLeal and Martinho Simões, 1993MS

C6H5NaO (cr) + Water (l) = Phenol (cr) + Sodium hydroxide (cr)

By formula: C6H5NaO (cr) + H2O (l) = C6H6O (cr) + HNaO (cr)

Quantity Value Units Method Reference Comment
Deltar21.4 ± 3.6kJ/molRSCLeal, Pires de Matos, et al., 1991MS

C3H5O5- + 2Water = C3H7O6-

By formula: C3H5O5- + 2H2O = C3H7O6-

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C4H7O5- + 2Water = C4H9O6-

By formula: C4H7O5- + 2H2O = C4H9O6-

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C5H9O5- + 2Water = C5H11O6-

By formula: C5H9O5- + 2H2O = C5H11O6-

Quantity Value Units Method Reference Comment
Deltar25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C5H9O5- + 2Water = C5H11O6-

By formula: C5H9O5- + 2H2O = C5H11O6-

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C6H11O5- + 2Water = C6H13O6-

By formula: C6H11O5- + 2H2O = C6H13O6-

Quantity Value Units Method Reference Comment
Deltar18.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C4H5O5- + 2Water = C4H7O6-

By formula: C4H5O5- + 2H2O = C4H7O6-

Quantity Value Units Method Reference Comment
Deltar21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C9H20O7-2 + 4Water = C9H22O8-2

By formula: C9H20O7-2 + 4H2O = C9H22O8-2

Quantity Value Units Method Reference Comment
Deltar28.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C9H22O8-2 + 5Water = C9H24O9-2

By formula: C9H22O8-2 + 5H2O = C9H24O9-2

Quantity Value Units Method Reference Comment
Deltar24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Tsvetkov, Sopin, et al., 1986
Tsvetkov, V.G.; Sopin, V.P.; Tsvetkova, L.Ya.; Marchenko, G.N., Enthalpy of reaction of nitric acid with some organic compounds, J. Gen. Chem. USSR, 1986, 56, 471-474. [all data]

Anteunis and Rommelaere, 1970
Anteunis, M.; Rommelaere, Y., NMR experiments on acetals. XXIX. The ease of acetonide formation of some glycols, Bull. Soc. Chim. Belg., 1970, 79, 523-530. [all data]

Wiberg and Waldron, 1991
Wiberg, K.B.; Waldron, R.F., Lactones. 2. Enthalpies of hydrolysis, reduction, and formation of the C4-C13 monocyclic lactones. strain energies and conformations, J. Am. Chem. Soc., 1991, 113, 7697-7705. [all data]

Grigor'ev, Katsman, et al., 1981
Grigor'ev, A.A.; Katsman, E.A.; Bobrov, A.F.; Dan'ko, T.N.; Pinkhasik, E.V., Preparation of «gamma»-acetopropyl alcohol, Sov. Chem. Ind. (Engl. Transl.), 1981, 967-972. [all data]

Blades, Ho, et al., 1996
Blades, A.T.; Ho, Y.; Kebarle, P., Free Energies of Hydration in the Gas Phase of Some Phosphate Singly and Doubly Charged Anions: orthophosphate, diphosphate, Ribose-5-phosphate, Adenosine-5'-phosphate and Adenosine-5'-Dipho, J. Phys. Chem., 1996, 100, 6, 2443, https://doi.org/10.1021/jp952032s . [all data]

Leal and Martinho Simões, 1993
Leal, J.P.; Martinho Simões, J.A., J. Organometal. Chem., 1993, 460, 131. [all data]

Leal, Pires de Matos, et al., 1991
Leal, J.P.; Pires de Matos, A.; Martinho Simões, J.A., J. Organometal. Chem., 1991, 403, 1. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References