Water

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1301 to 1350

C9H24O9-2 + 6Water = C9H26O10-2

By formula: C9H24O9-2 + 6H2O = C9H26O10-2

Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H22O7-2 + 4Water = C10H24O8-2

By formula: C10H22O7-2 + 4H2O = C10H24O8-2

Quantity Value Units Method Reference Comment
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H24O8-2 + 5Water = C10H26O9-2

By formula: C10H24O8-2 + 5H2O = C10H26O9-2

Quantity Value Units Method Reference Comment
Δr24.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H26O9-2 + 6Water = C10H28O10-2

By formula: C10H26O9-2 + 6H2O = C10H28O10-2

Quantity Value Units Method Reference Comment
Δr21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H10O7-2 + 4Water = C8H12O8-2

By formula: C8H10O7-2 + 4H2O = C8H12O8-2

Quantity Value Units Method Reference Comment
Δr30.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H12O8-2 + 5Water = C8H14O9-2

By formula: C8H12O8-2 + 5H2O = C8H14O9-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H14O9-2 + 6Water = C8H16O10-2

By formula: C8H14O9-2 + 6H2O = C8H16O10-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12O10Se-2 + 7Water = H14O11Se-2

By formula: H12O10Se-2 + 7H2O = H14O11Se-2

Quantity Value Units Method Reference Comment
Δr29.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14O11Se-2 + 8Water = H16O12Se-2

By formula: H14O11Se-2 + 8H2O = H16O12Se-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H16O12Se-2 + 9Water = H18O13Se-2

By formula: H16O12Se-2 + 9H2O = H18O13Se-2

Quantity Value Units Method Reference Comment
Δr23.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H10O8S2-2 + 6Water = H12O9S2-2

By formula: H10O8S2-2 + 6H2O = H12O9S2-2

Quantity Value Units Method Reference Comment
Δr30.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12O9S2-2 + 7Water = H14O10S2-2

By formula: H12O9S2-2 + 7H2O = H14O10S2-2

Quantity Value Units Method Reference Comment
Δr27.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14O10S2-2 + 8Water = H16O11S2-2

By formula: H14O10S2-2 + 8H2O = H16O11S2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H16O11S2-2 + 9Water = H18O12S2-2

By formula: H16O11S2-2 + 9H2O = H18O12S2-2

Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H6O9S2-2 + 4Water = H8O10S2-2

By formula: H6O9S2-2 + 4H2O = H8O10S2-2

Quantity Value Units Method Reference Comment
Δr33.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H8O10S2-2 + 5Water = H10O11S2-2

By formula: H8O10S2-2 + 5H2O = H10O11S2-2

Quantity Value Units Method Reference Comment
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H10O11S2-2 + 6Water = H12O12S2-2

By formula: H10O11S2-2 + 6H2O = H12O12S2-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12O12S2-2 + 7Water = H14O13S2-2

By formula: H12O12S2-2 + 7H2O = H14O13S2-2

Quantity Value Units Method Reference Comment
Δr23.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14O13S2-2 + 8Water = H16O14S2-2

By formula: H14O13S2-2 + 8H2O = H16O14S2-2

Quantity Value Units Method Reference Comment
Δr21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H8O8S2-2 + 3Water = C2H10O9S2-2

By formula: C2H8O8S2-2 + 3H2O = C2H10O9S2-2

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H10O9S2-2 + 4Water = C2H12O10S2-2

By formula: C2H10O9S2-2 + 4H2O = C2H12O10S2-2

Quantity Value Units Method Reference Comment
Δr27.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H12O10S2-2 + 5Water = C2H14O11S2-2

By formula: C2H12O10S2-2 + 5H2O = C2H14O11S2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H14O11S2-2 + 6Water = C2H16O12S2-2

By formula: C2H14O11S2-2 + 6H2O = C2H16O12S2-2

Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H4O10S2-2 + 3Water = H6O11S2-2

By formula: H4O10S2-2 + 3H2O = H6O11S2-2

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H6O11S2-2 + 4Water = H8O12S2-2

By formula: H6O11S2-2 + 4H2O = H8O12S2-2

Quantity Value Units Method Reference Comment
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H8O12S2-2 + 5Water = H10O13S2-2

By formula: H8O12S2-2 + 5H2O = H10O13S2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H10O13S2-2 + 6Water = H12O14S2-2

By formula: H10O13S2-2 + 6H2O = H12O14S2-2

Quantity Value Units Method Reference Comment
Δr22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H2O7S4-2 + 2Water = H4O8S4-2

By formula: H2O7S4-2 + 2H2O = H4O8S4-2

Quantity Value Units Method Reference Comment
Δr32.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H4O8S4-2 + 3Water = H6O9S4-2

By formula: H4O8S4-2 + 3H2O = H6O9S4-2

Quantity Value Units Method Reference Comment
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H6O9S4-2 + 4Water = H8O10S4-2

By formula: H6O9S4-2 + 4H2O = H8O10S4-2

Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H8O10S4-2 + 5Water = H10O11S4-2

By formula: H8O10S4-2 + 5H2O = H10O11S4-2

Quantity Value Units Method Reference Comment
Δr22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H8O7S2-2 + 2Water = C10H10O8S2-2

By formula: C10H8O7S2-2 + 2H2O = C10H10O8S2-2

Quantity Value Units Method Reference Comment
Δr29.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H10O8S2-2 + 3Water = C10H12O9S2-2

By formula: C10H10O8S2-2 + 3H2O = C10H12O9S2-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H12O9S2-2 + 4Water = C10H14O10S2-2

By formula: C10H12O9S2-2 + 4H2O = C10H14O10S2-2

Quantity Value Units Method Reference Comment
Δr23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C4H9O3- + 3Water = C4H11O4-

By formula: C4H9O3- + 3H2O = C4H11O4-

Quantity Value Units Method Reference Comment
Δr27.6 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C4H11O4- + 3Water = C4H13O5-

By formula: C4H11O4- + 3H2O = C4H13O5-

Quantity Value Units Method Reference Comment
Δr21.3 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

CAS Reg. No. 12509-93-2 + Water = H2O6S-

By formula: CAS Reg. No. 12509-93-2 + H2O = H2O6S-

Quantity Value Units Method Reference Comment
Δr17.2 ± 0.84kJ/molIMREMöhler, Reiner, et al., 1992gas phase; B

Calcium ion (1+) + Water = (Calcium ion (1+) • Water)

By formula: Ca+ + H2O = (Ca+ • H2O)

Quantity Value Units Method Reference Comment
Δr120.kJ/molHPMSKochanski and Constantin, 1987gas phase; M

Benzenamine, N-ethyl- + Nitrous acid = Benzenamine, N-ethyl-N-nitroso- + Water

By formula: C8H11N + HNO2 = C8H10N2O + H2O

Quantity Value Units Method Reference Comment
Δr-78.83kJ/molCmSwientoslawski, 1910liquid phase; ALS

C2H5NaO (cr) + Water (l) = Sodium hydroxide (cr) + Ethanol (l)

By formula: C2H5NaO (cr) + H2O (l) = HNaO (cr) + C2H6O (l)

Quantity Value Units Method Reference Comment
Δr-5.7 ± 1.9kJ/molRSCLeal, Pires de Matos, et al., 1991MS

C13H9N- + Water = C13H11NO-

By formula: C13H9N- + H2O = C13H11NO-

Quantity Value Units Method Reference Comment
Δr27. ± 6.3kJ/molN/AKokubo, Ando, et al., 2004gas phase; B

C4H7O2- + Water = C4H9O3-

By formula: C4H7O2- + H2O = C4H9O3-

Quantity Value Units Method Reference Comment
Δr36.0 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

CF3O- + Water = CH2F3O2-

By formula: CF3O- + H2O = CH2F3O2-

Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molN/AAmelynck, Van Bavel, et al., 2000gas phase; B

Benzaldehyde, phenylhydrazone + Water = Benzaldehyde + Hydrazine, phenyl-

By formula: C13H12N2 + H2O = C7H6O + C6H8N2

Quantity Value Units Method Reference Comment
Δr-61.1kJ/molCmLandrieu, 1905solid phase; ALS

Furaldehyde phenylhydrazone + Water = Hydrazine, phenyl- + Furfural

By formula: C11H10N2O + H2O = C6H8N2 + C5H4O2

Quantity Value Units Method Reference Comment
Δr-61.9kJ/molCmLandrieu, 1905solid phase; ALS

p-Anisaldehyde phenylhydrazone + Water = Hydrazine, phenyl- + Benzaldehyde, 4-methoxy-

By formula: C14H14N2O + H2O = C6H8N2 + C8H8O2

Quantity Value Units Method Reference Comment
Δr-61.9kJ/molCmLandrieu, 1905solid phase; ALS

sodium methanolate (cr) + Water (l) = Sodium hydroxide (cr) + Methyl Alcohol (l)

By formula: CH3NaO (cr) + H2O (l) = HNaO (cr) + CH4O (l)

Quantity Value Units Method Reference Comment
Δr-6.5 ± 2.4kJ/molRSCLeal, Pires de Matos, et al., 1991MS

Isopropyl Alcohol + Nitric acid = Nitric acid, 1-methylethyl ester + Water

By formula: C3H8O + HNO3 = C3H7NO3 + H2O

Quantity Value Units Method Reference Comment
Δr-23.4kJ/molEqkRubtsov, 1986liquid phase; ALS

Water + Acetaldehyde, phenylhydrazone = Hydrazine, phenyl- + Acetaldehyde

By formula: H2O + C8H10N2 = C6H8N2 + C2H4O

Quantity Value Units Method Reference Comment
Δr-61.1kJ/molCmLandrieu, 1905solid phase; ALS

Benzoic acid, 2-[(phenylamino)carbonyl]- = 1H-Isoindole-1,3(2H)-dione, 2-phenyl- + Water

By formula: C14H11NO3 = C14H9NO2 + H2O

Quantity Value Units Method Reference Comment
Δr-15.kJ/molEqkKaryakin, Bazhan, et al., 1977solid phase; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Viidanoja, Reiner, et al., 2000
Viidanoja, J.; Reiner, T.; Kiendler, A.; Grimm, F.; Arnold, F., Laboratory investigations of negative ion molecule reactions of propionic, butyric, glyoxylic, pyruvic, and pinonic acids, Int. J. Mass Spectrom., 2000, 194, 1, 53-68, https://doi.org/10.1016/S1387-3806(99)00172-4 . [all data]

Möhler, Reiner, et al., 1992
Möhler, O.; Reiner, T.; Arnold, F., The Formation of SO5(-) by Gas Phase Ion-Molecule Reactions, J. Chem. Phys., 1992, 97, 11, 8233, https://doi.org/10.1063/1.463394 . [all data]

Kochanski and Constantin, 1987
Kochanski, E.; Constantin, E., Theoretical and Experimental Studies of the System Ca+(H2O)n for n=1 to 10, J. Chem. Phys., 1987, 87, 3, 1661, https://doi.org/10.1063/1.453229 . [all data]

Swientoslawski, 1910
Swientoslawski, W., Thermochemische Untersuchungen der organischen Verbindungen. Dritte Mitteilung. Stickstoffhaltige Verbindungen., Z. Phys. Chem., 1910, 72, 49-83. [all data]

Leal, Pires de Matos, et al., 1991
Leal, J.P.; Pires de Matos, A.; Martinho Simões, J.A., J. Organometal. Chem., 1991, 403, 1. [all data]

Kokubo, Ando, et al., 2004
Kokubo, S.; Ando, N.; Koyasu, K.; Mitsui, M.; Nakajima, A., Negative ion photoelectron spectroscopy of acridine molecular anion and its monohydrate, J. Chem. Phys., 2004, 121, 22, 11112-11117, https://doi.org/10.1063/1.1818132 . [all data]

Amelynck, Van Bavel, et al., 2000
Amelynck, C.; Van Bavel, A.M.; Schoon, N.; Arijs, E., Gas phase reactions of CF3O- and CF3O-center dot H2O and their relevance to the detection of stratospheric HCl, Int. J. Mass Spectrom., 2000, 202, 1-3, 207-216, https://doi.org/10.1016/S1387-3806(00)00244-X . [all data]

Landrieu, 1905
Landrieu, M.Ph., Thermochimie. - Thermochimie des hydrazones, Compt. Rend., 1905, 141, 358-361. [all data]

Rubtsov, 1986
Rubtsov, Yu.I., Thermodynamic calculation of equilibrium in nitration of alcohols, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 19-22. [all data]

Karyakin, Bazhan, et al., 1977
Karyakin, N.V.; Bazhan, N.G.; Sapozhnikov, V.N.; Shvetsova, K.G.; Berestneva, G.L.; Lomteva, A.N.; Zimin, Yu.B.; Korshak, V.V., Thermodynamics of synthesis of poly-(p,p'-diphenyleneoxide)pyromellitimide, Polym. Sci. USSR, 1977, 19, 1766-1775. [all data]


Notes

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