Water
- Formula: H2O
- Molecular weight: 18.0153
- IUPAC Standard InChI:
- InChI=1S/H2O/h1H2
- Download the identifier in a file.
- IUPAC Standard InChIKey: XLYOFNOQVPJJNP-UHFFFAOYSA-N
- CAS Registry Number: 7732-18-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Water vapor; Distilled water; Ice; H2O; Dihydrogen oxide; steam; Tritiotope
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Condensed phase thermochemistry data
- Phase change data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300, reactions 301 to 350, reactions 351 to 400, reactions 401 to 450, reactions 451 to 500, reactions 501 to 550, reactions 551 to 600, reactions 601 to 650, reactions 651 to 700, reactions 701 to 750, reactions 751 to 800, reactions 801 to 850, reactions 851 to 900, reactions 901 to 950, reactions 951 to 1000, reactions 1001 to 1050, reactions 1051 to 1100, reactions 1101 to 1150, reactions 1151 to 1200, reactions 1201 to 1250, reactions 1251 to 1300, reactions 1301 to 1350, reactions 1351 to 1360
- Gas phase ion energetics data
- IR Spectrum
- Mass spectrum (electron ionization)
- Vibrational and/or electronic energy levels
- Gas Chromatography
- Fluid Properties
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
- NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
- NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Ag+ + H2O = (Ag+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 139. | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; M |
By formula: (Ag+ H2O) + H2O = (Ag+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 106. | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.3 | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; M |
By formula: (Ag+ 2H2O) + H2O = (Ag+
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; M |
By formula: (Ag+ 3H2O) + H2O = (Ag+
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.3 | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 123. | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; M |
By formula: (Ag+ 4H2O) + H2O = (Ag+
5H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.3 | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 127. | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; M |
By formula: (Ag+ 5H2O) + H2O = (Ag+
6H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.6 | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 135. | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; M |
By formula: Al+ + H2O = (Al+ H2O)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
104. (+15.,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Al+ (3s2); M |
By formula: (Al+ H2O) + H2O = (Al+
2H2O)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.4 (+5.0,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Al+ (3s2); M |
By formula: (Al+ 2H2O) + H2O = (Al+
3H2O)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
63.6 (+7.5,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Al+ (3s2); M |
By formula: (Al+ 3H2O) + H2O = (Al+
4H2O)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
52.3 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Al+ (3s2); M |
By formula: Bi+ + H2O = (Bi+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 95.4 | kJ/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ H2O) + H2O = (Bi+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.1 | kJ/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107. | J/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ 2H2O) + H2O = (Bi+
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.6 | kJ/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ 3H2O) + H2O = (Bi+
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.2 | kJ/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.3 | J/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ 4H2O) + H2O = (Bi+
5H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.9 | kJ/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.0 | J/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ 5H2O) + H2O = (Bi+
6H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: Br- + H2O = (Br- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.14 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 49.0 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 52.72 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
![]() | 53.1 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 61.5 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 77.0 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
![]() | 82.8 | J/mol*K | MS | Burdett and Hayhurst, 1982 | gas phase; FLAME SOURCE, 1600 K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 ± 3.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 29. ± 12. | kJ/mol | TDAs | Burdett and Hayhurst, 1982 | gas phase; B |
![]() | 29. ± 8.4 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
By formula: (Br- H2O) + H2O = (Br-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 51.04 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 51.5 ± 4.2 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 51.5 ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.3 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 95.8 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 23. ± 5.9 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 22.6 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 24. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (Br- 2H2O) + H2O = (Br-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 28.9 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 48.1 ± 4.2 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 48.1 ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 104. | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. ± 4.6 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 17. ± 5.9 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 17.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 18. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (Br- 3H2O) + H2O = (Br-
4H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.02 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 26. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 45.6 ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 112. | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.0 ± 2.9 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 12.1 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 14. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (Br- 4H2O) + H2O = (Br-
5H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 26. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.6 ± 5.0 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 5H2O) + H2O = (Br-
6H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 25. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 8.8 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (Br- 6H2O) + H2O = (Br-
7H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy estimated; B,M |
![]() | 10. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | N/A | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.44 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy estimated; B |
By formula: (Br- 7H2O) + H2O = (Br-
8H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 8H2O) + H2O = (Br-
9H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 9H2O) + H2O = (Br-
10H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 10H2O) + H2O = (Br-
11H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 11H2O) + H2O = (Br-
12H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 12H2O) + H2O = (Br-
13H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 13H2O) + H2O = (Br-
14H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 14H2O) + H2O = (Br-
15H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -2. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 15H2O) + H2O = (Br-
16H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.6 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: CF3+ + H2O = (CF3+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19. | kJ/mol | HPMS | Bennet and Field, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.7 | J/mol*K | HPMS | Bennet and Field, 1972 | gas phase; M |
By formula: CF3O- + H2O = CH2F3O2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28. ± 4.2 | kJ/mol | N/A | Amelynck, Van Bavel, et al., 2000 | gas phase; B |
By formula: CF3O3S- + H2O = (CF3O3S- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: (CF3O3S- H2O) + H2O = (CF3O3S-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.9 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: CHO2- + H2O = (CHO2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.9 ± 4.2 | kJ/mol | TDAs | Meot-Ner and Sieck, 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Meot-Ner and Sieck, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 6.7 | kJ/mol | TDAs | Meot-Ner and Sieck, 1986 | gas phase; B |
![]() | 35.1 ± 0.84 | kJ/mol | N/A | Viidanoja, Reiner, et al., 2000 | gas phase; B |
![]() | 38.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (CHO2- H2O) + H2O = (CHO2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.7 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 28.9 ± 0.84 | kJ/mol | N/A | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: (CHO2- 2H2O) + H2O = (CHO2-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.6 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.3 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 21.8 ± 0.84 | kJ/mol | N/A | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: CHO3- + H2O = CH3O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.69 ± 0.84 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 35.6 ± 1.7 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
By formula: (CH2N+ CHN) + H2O = (CH2N+
H2O
CHN)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.1 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.0 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
By formula: CH2N+ + H2O = (CH2N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
![]() | 124. | kJ/mol | ICR | Berman and Beauchamp, 1980 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
![]() | 120. | J/mol*K | N/A | Berman and Beauchamp, 1980 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
87.9 | 300. | ICR | Berman and Beauchamp, 1980 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
By formula: (CH2N+ H2O
CHN) + H2O = (CH2N+
2H2O
CHN)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.7 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99.6 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
By formula: (CH2N+ H2O) + H2O = (CH2N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 89.5 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 106. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
By formula: (CH2N+ 2H2O) + H2O = (CH2N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.0 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
By formula: CH2NO5- + H2O + CH2O2 = CH4NO6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.4 ± 0.84 | kJ/mol | IMRE | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: CH2O2S- + 2H2O = CH4O3S-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.8 ± 8.4 | kJ/mol | N/A | Surber and Sanov, 2002 | gas phase; Stated electron affinity is the Vertical Detachment Energy; B |
By formula: CH2O4- + 2H2O = CH4O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 ± 2.1 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. ± 4.2 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
By formula: CH3O+ + H2O = (CH3O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 119. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; switching reaction(H3O+)H2O; Davidson, Sunner J., et al., 1979, Lias, Liebman, et al., 1984; M |
![]() | 117. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2O)2H+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Yamdagni and Kebarle, 1976, Wolf, Staley, et al., 1977; M |
![]() | 119. | kJ/mol | ICR | Berman and Beauchamp, 1980 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 120. | kJ/mol | FA | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 120. | kJ/mol | FA | Fehsenfeld, Dotan, et al., 1978 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | N/A | Berman and Beauchamp, 1980 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 113. | J/mol*K | N/A | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 112. | J/mol*K | FA | Fehsenfeld, Dotan, et al., 1978 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | kJ/mol | ICR | Berman and Beauchamp, 1980 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 85.8 | kJ/mol | FA | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
By formula: (CH3O+ H2O) + H2O = (CH3O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 90.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 83.3 | kJ/mol | FA | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 82.8 | kJ/mol | FA | Fehsenfeld, Dotan, et al., 1978 | gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 110. | J/mol*K | N/A | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 110. | J/mol*K | FA | Fehsenfeld, Dotan, et al., 1978 | gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 50.6 | kJ/mol | FA | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
By formula: (CH3O+ 2H2O) + H2O = (CH3O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 70.7 | kJ/mol | FA | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 71.1 | kJ/mol | FA | Fehsenfeld, Dotan, et al., 1978 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 109. | J/mol*K | N/A | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
![]() | 109. | J/mol*K | FA | Fehsenfeld, Dotan, et al., 1978 | gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. | kJ/mol | FA | Bohme, Mackay, et al., 1979 | gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M |
By formula: (CH3O+ 3H2O) + H2O = (CH3O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH3O+ 4H2O) + H2O = (CH3O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.6 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH3O+ 5H2O) + H2O = (CH3O+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.0 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH3O+ 6H2O) + H2O = (CH3O+
7H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 108. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH3O- CH4O) + H2O = (CH3O-
H2O
CH4O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.5 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 108. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH3O- 2CH4O) + H2O = (CH3O-
H2O
2CH4O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.7 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: CH3O- + H2O = (CH3O- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 106. ± 9.2 | kJ/mol | CIDT | DeTuri and Ervin, 1999 | gas phase; B |
![]() | 100. | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M,B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Meot-ner and Sieck, 1986 | gas phase; M |
![]() | 95.8 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 ± 1.3 | kJ/mol | TDAs | Meot-ner and Sieck, 1986 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
64.4 | 296. | FA | MacKay and Bohme, 1978 | gas phase; From thermochemical cycle,switching reaction(OH-)H2O, DG>; Meot-Ner(Mautner), 1986; M |
By formula: (CH3O- H2O
CH4O) + H2O = (CH3O-
2H2O
CH4O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63.6 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 116. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH3O- H2O) + H2O = (CH3O-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 80.3 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 106. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
34. | 296. | FA | MacKay and Bohme, 1978 | gas phase; From thermochemical cycle,switching reaction(OH-)2H2O; Meot-Ner(Mautner), 1986; M |
By formula: (CH3O- 2H2O) + H2O = (CH3O-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.9 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
33. | 296. | FA | MacKay and Bohme, 1978 | gas phase; From thermochemical cycle,switching reaction(OH-)3H2O; Meot-Ner(Mautner), 1986; M |
By formula: (CH3O- 3H2O) + H2O = (CH3O-
4H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.7 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: CH3O3S- + H2O = (CH3O3S- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.9 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: (CH3O3S- H2O) + H2O = (CH3O3S-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.6 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: (CH3O3S- 2H2O) + H2O = (CH3O3S-
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.4 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: CH3O4- + 2H2O = CH5O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.34 ± 0.84 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
By formula: CH3S- + H2O = (CH3S- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.76 ± 0.84 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88.7 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 36.4 ± 2.9 | kJ/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
By formula: (CH3S- H2O) + H2O = (CH3S-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.5 | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.3 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
By formula: (CH3S- 2H2O) + H2O = (CH3S-
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.4 | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.8 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
By formula: (CH3S- 3H2O) + H2O = (CH3S-
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.3 | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
By formula: CH4NO+ + H2O = (CH4NO+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 88.7 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 89.1 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 114. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 114. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; M |
By formula: (CH4NO+ H2O) + H2O = (CH4NO+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 58.6 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.4 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 95.0 | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; M |
By formula: (CH4NO+ 2H2O) + H2O = (CH4NO+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 49.4 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.9 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 87.9 | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; M |
By formula: (CH4NO+ 3H2O) + H2O = (CH4NO+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 41. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 84.5 | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; M |
By formula: (CH4NO+ 4H2O) + H2O = (CH4NO+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 41. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 107. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; M |
By formula: CH4O5- + 3H2O = CH6O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 ± 3.3 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14. ± 4.2 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
By formula: (CH5O+ CH4O) + H2O = (CH5O+
H2O
CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.0 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 108. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ 3CH4O) + H2O = (CH5O+
H2O
3CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.6 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ 4CH4O) + H2O = (CH5O+
H2O
4CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.8 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99.6 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: CH5O+ + H2O = (CH5O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 100. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 123. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 96. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH5O+ H2O
2CH4O) + H2O = (CH5O+
2H2O
2CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.4 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107. | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ H2O
3CH4O) + H2O = (CH5O+
2H2O
3CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.5 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ 2H2O
CH4O) + H2O = (CH5O+
3H2O
CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ 2H2O
2CH4O) + H2O = (CH5O+
3H2O
2CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.5 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ 2H2O
3CH4O) + H2O = (CH5O+
3H2O
3CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 272. | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
By formula: (CH5O+ 3H2O
CH4O) + H2O = (CH5O+
4H2O
CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.3 | J/mol*K | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n; M |
By formula: (CH5O+ 3H2O
2CH4O) + H2O = (CH5O+
4H2O
2CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 272. | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
By formula: (CH5O+ 4H2O
CH4O) + H2O = (CH5O+
5H2O
CH4O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. | kJ/mol | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 269. | PHPMS | Meot-Ner(Mautner), 1986 | gas phase; n, Entropy change calculated or estimated; M |
By formula: (CH5O+ H2O) + H2O = (CH5O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.8 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 87.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 114. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 121. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH5O+ 2H2O) + H2O = (CH5O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.0 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 61.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 108. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH5O+ 3H2O) + H2O = (CH5O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 48.5 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 92.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH5O+ 4H2O) + H2O = (CH5O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 38. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 86.6 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 77.4 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH5O+ 5H2O) + H2O = (CH5O+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 39. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.5 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 92.9 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH5O+ 6H2O) + H2O = (CH5O+
7H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 269. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: CH5O2- + 2H2O = CH7O3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 80.3 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 49.0 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
By formula: CH5O5- + 3H2O = CH7O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 ± 1.3 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19. ± 4.2 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
By formula: CH5S+ + H2O = (CH5S+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.9 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated; M |
![]() | 56.5 | kJ/mol | ICR | Berman and Beauchamp, 1986 | gas phase; bracketing; Lias, Liebman, et al., 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
22. | 476. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated; M |
By formula: CH6N+ + H2O = (CH6N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 78.7 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
![]() | 78.7 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.8 | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (CH6N+ H2O) + H2O = (CH6N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 61.1 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
![]() | 61.1 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 112. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
![]() | 112. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (CH6N+ 2H2O) + H2O = (CH6N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.5 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 51.9 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
![]() | 51.9 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (CH6N+ 3H2O) + H2O = (CH6N+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (CH6N+ 4H2O) + H2O = (CH6N+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 269. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: (CH6N+ 5H2O) + H2O = (CH6N+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.4 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 259. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: CH7O3- + 3H2O = CH9O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.9 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.4 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
By formula: CH7O6- + 4H2O = CH9O7-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 ± 3.8 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14. ± 4.2 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
By formula: CH9O4- + 4H2O = CH11O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.3 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
By formula: (CN- CHN) + H2O = (CN-
H2O
CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.4 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B |
By formula: (CN- 2CHN) + H2O = (CN-
H2O
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32. ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 52.3 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B |
By formula: (CN- 3CHN) + H2O = (CN-
H2O
3CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
18. | 262. | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
By formula: CN- + H2O = (CN- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 ± 3.3 | kJ/mol | TDAs | Larson, Szulejko, et al., 1988 | gas phase; B,M |
![]() | 61.1 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,B,M,M |
![]() | 57.74 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B,M |
![]() | 61.1 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.0 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
![]() | 75. | J/mol*K | PHPMS | Larson, Szulejko, et al., 1988 | gas phase; M |
![]() | 82.0 | J/mol*K | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
![]() | 82.0 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
![]() | 82.8 | J/mol*K | HPMS | Payzant, Yamdagni, et al., 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 ± 0.84 | kJ/mol | TDAs | Larson, Szulejko, et al., 1988 | gas phase; B |
![]() | 36. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988, 2 | gas phase; B |
![]() | 36. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
![]() | 33.1 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
By formula: (CN- H2O
CHN) + H2O = (CN-
2H2O
CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 73.2 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B |
By formula: (CN- H2O
2CHN) + H2O = (CN-
2H2O
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 12. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 262. | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
By formula: (CN- 2H2O
CHN) + H2O = (CN-
3H2O
CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B |
By formula: (CN- H2O) + H2O = (CN-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B,M |
![]() | 49.0 | kJ/mol | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.7 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
![]() | 75.7 | J/mol*K | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; B |
By formula: (CN- 2H2O) + H2O = (CN-
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.8 ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B,M |
![]() | 44.8 | kJ/mol | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.8 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n; M |
![]() | 82.8 | J/mol*K | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 33. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B |
By formula: (CN- 3H2O) + H2O = (CN-
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. ± 4.2 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16. ± 5.9 | kJ/mol | TDAs | Meot-Ner (Mautner) M. and Speller, 1989 | gas phase; Entropy estimated; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 262. | PHPMS | Meot-Ner (Mautner) and Speller, 1989 | gas phase; n, Entropy change calculated or estimated; M |
By formula: CO3- + H2O = CH2O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.99 ± 0.84 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
![]() | 48.1 ± 4.2 | kJ/mol | IMRE | Fehsenfeld and Ferguson, 1974 | gas phase; B |
![]() | <161.1 | kJ/mol | PDis | Smith, Lee, et al., 1978 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.6 ± 1.7 | kJ/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase; B |
![]() | 28.0 ± 1.7 | kJ/mol | IMRE | Fehsenfeld and Ferguson, 1974 | gas phase; B |
By formula: CO3- + H2O = (CO3- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.0 | kJ/mol | HPMS | Keesee, Lee, et al., 1979 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | HPMS | Keesee, Lee, et al., 1979 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
By formula: (CO3- H2O) + H2O = (CO3-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | HPMS | Keesee, Lee, et al., 1979 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 124. | J/mol*K | HPMS | Keesee, Lee, et al., 1979 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
18. | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
By formula: (CO3- 2H2O) + H2O = (CO3-
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 | kJ/mol | HPMS | Keesee, Lee, et al., 1979 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 136. | J/mol*K | HPMS | Keesee, Lee, et al., 1979 | gas phase; M |
By formula: C2Cl3O2- + H2O = (C2Cl3O2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1995 | gas phase; M |
By formula: C2F3O2- + H2O = (C2F3O2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.7 ± 6.3 | kJ/mol | N/A | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
![]() | 57.3 ± 4.2 | kJ/mol | N/A | Meot-Ner and Sieck, 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | PHPMS | Meot-Ner and Sieck, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 27. ± 6.7 | kJ/mol | TDAs | Meot-Ner and Sieck, 1986 | gas phase; B |
By formula: (C2F3O2- H2O) + H2O = (C2F3O2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.7 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C2H- + H2O = (C2H- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67.8 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.8 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: C2HCl2O2- + H2O = (C2HCl2O2- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.7 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
(C2HCl2O2-
) +
= (C2HCl2O2-
2
)
By formula: (C2HCl2O2- H2O) + H2O = (C2HCl2O2-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.8 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: C2HF2O2- + H2O = (C2HF2O2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.7 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.4 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2HF2O2- H2O) + H2O = (C2HF2O2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C2HO4- + H2O = (C2HO4- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1995 | gas phase; M |
By formula: C2H2ClO2- + H2O = (C2H2ClO2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C2H2FO2- + H2O = (C2H2FO2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.0 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34.7 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2H2FO2- H2O) + H2O = (C2H2FO2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.7 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2H2FO2- 2H2O) + H2O = (C2H2FO2-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C2H2F3O2+ + H2O = (C2H2F3O2+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 118. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.5 | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
89.5 | 309. | ICR | Larson and McMahon, 1982 | gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M |
By formula: C2H2IO2- + H2O = (C2H2IO2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.1 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2H2IO2- H2O) + H2O = (C2H2IO2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2H2IO2- 2H2O) + H2O = (C2H2IO2-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.3 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.0 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C2H2N- + H2O = (C2H2N- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 73.6 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 33. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: C2H2O+ + H2O = (C2H2O+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 | kJ/mol | EI | Postma, Ruttink, et al., 1986 | gas phase; based on AE(CH2CO+)H2O from (HOCH2)2CO+; M |
By formula: C2H3O+ + H2O = (C2H3O+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 103. | kJ/mol | HPMS | Davidson, Lau, et al., 1978 | gas phase; forms CH3COOH2+; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 138. | J/mol*K | HPMS | Davidson, Lau, et al., 1978 | gas phase; forms CH3COOH2+; M |
By formula: C2H3O- + H2O = (C2H3O- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.4 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.6 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 40. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: (C2H3O2- C6H11NO3) + H2O = (C2H3O2-
H2O
C6H11NO3)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 106. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: C2H3O2- + H2O = (C2H3O2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.6 ± 3.3 | kJ/mol | TDAs | Wincel, 2008 | gas phase; B |
![]() | 66.5 ± 4.2 | kJ/mol | N/A | Meot-ner, Elmore, et al., 1999 | gas phase; B |
![]() | 66.9 ± 4.2 | kJ/mol | N/A | Meot-Ner and Sieck, 1986 | gas phase; B,M |
![]() | 68.6 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
![]() | 66.1 | kJ/mol | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.9 | J/mol*K | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
![]() | 94.1 | J/mol*K | PHPMS | Meot-Ner and Sieck, 1986 | gas phase; ion given as C2H3COO- in paper by error; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 5.9 | kJ/mol | N/A | Wincel, 2008 | gas phase; B |
![]() | 39.8 | kJ/mol | TDAs | Meot-ner, Elmore, et al., 1999 | gas phase; B |
![]() | 39. ± 6.7 | kJ/mol | TDAs | Meot-Ner and Sieck, 1986 | gas phase; B |
![]() | 39.3 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2H3O2- H2O) + H2O = (C2H3O2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 ± 4.2 | kJ/mol | N/A | Meot-ner, Elmore, et al., 1999 | gas phase; B |
![]() | 57.7 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
![]() | 53.6 | kJ/mol | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
![]() | 54.0 | kJ/mol | PHPMS | Meot-Ner and Sieck, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.9 | J/mol*K | PHPMS | Meot-ner, 1988, 2 | gas phase; M |
![]() | 85.8 | J/mol*K | PHPMS | Meot-Ner and Sieck, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.3 | kJ/mol | TDAs | Meot-ner, Elmore, et al., 1999 | gas phase; B |
![]() | 28.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C2H3O2- 2H2O) + H2O = (C2H3O2-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.4 ± 4.2 | kJ/mol | N/A | Meot-ner, Elmore, et al., 1999 | gas phase; B |
![]() | 51.0 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
![]() | 49.4 | kJ/mol | PHPMS | Meot-ner, 1988, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Meot-ner, 1988, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.4 | kJ/mol | TDAs | Meot-ner, Elmore, et al., 1999 | gas phase; B |
![]() | 21.8 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 25. | kJ/mol | PHPMS | Meot-ner, 1988, 2 | gas phase; Entropy change calculated or estimated; M |
By formula: C2H4F3O+ + H2O = (C2H4F3O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 128. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99.6 | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
97.9 | 309. | ICR | Larson and McMahon, 1982 | gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M |
By formula: (C2H4N+ C2H3N) + H2O = (C2H4N+
H2O
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.5 | kJ/mol | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n; M |
By formula: C2H4N+ + H2O = (C2H4N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92.5 ± 5.9 | kJ/mol | CID | Honma, Sunderlin, et al., 1993 | gas phase; guided ion beam CID; M |
![]() | 95.4 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; M |
![]() | 104. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; M |
![]() | 119. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H4N+ H2O
C2H3N) + H2O = (C2H4N+
2H2O
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.0 | kJ/mol | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n; M |
By formula: (C2H4N+ H2O
2C2H3N) + H2O = (C2H4N+
2H2O
2C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n, Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
12. | 316. | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n, Entropy change calculated or estimated; M |
By formula: (C2H4N+ 2H2O
C2H3N) + H2O = (C2H4N+
3H2O
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 | kJ/mol | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.3 | J/mol*K | PHPMS | Deakyne, Meot-Ner (Mautner), et al., 1986 | gas phase; n; M |
By formula: (C2H4N+ H2O) + H2O = (C2H4N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 ± 7.1 | kJ/mol | CID | Honma, Sunderlin, et al., 1993 | gas phase; guided ion beam CID; M |
![]() | 73.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H4N+ 2H2O) + H2O = (C2H4N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H4N+ 3H2O) + H2O = (C2H4N+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H4N+ 4H2O) + H2O = (C2H4N+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.9 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H4N+ 5H2O) + H2O = (C2H4N+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: C2H4NO2- + H2O = C2H6NO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.5 ± 2.1 | kJ/mol | TDAs | Nieckarz, Atkins, et al., 2008 | gas phase; B |
![]() | 66.9 ± 1.3 | kJ/mol | N/A | Wincel, 2008 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 39. ± 4.2 | kJ/mol | TDAs | Nieckarz, Atkins, et al., 2008 | gas phase; B |
![]() | 34.3 ± 1.7 | kJ/mol | TDAs | Wincel, 2008 | gas phase; B |
By formula: C2H4NO5- + H2O + C2H4O2 = C2H6NO6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19.2 ± 0.84 | kJ/mol | IMRE | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: C2H5F2O+ + H2O = (C2H5F2O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | ICR | Berman and Beauchamp, 1986 | gas phase; bracketing; Lias, Liebman, et al., 1984; M |
By formula: C2H5F3N+ + H2O = (C2H5F3N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 88.3 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 126. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
By formula: (C2H5F3N+ H2O) + H2O = (C2H5F3N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.4 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 125. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
By formula: (C2H5F3N+ 2H2O) + H2O = (C2H5F3N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 122. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
By formula: C2H5O+ + H2O = (C2H5O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 105. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 115. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ H2O) + H2O = (C2H5O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 2H2O) + H2O = (C2H5O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 3H2O) + H2O = (C2H5O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 89.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 4H2O) + H2O = (C2H5O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.7 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 5H2O) + H2O = (C2H5O+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.8 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 6H2O) + H2O = (C2H5O+
7H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 108. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: C2H5O+ + H2O = (C2H5O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 91.6 | kJ/mol | HPMS | Davidson, Sunner J., et al., 1979 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.9 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ H2O) + H2O = (C2H5O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.5 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 2H2O) + H2O = (C2H5O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O+ 3H2O) + H2O = (C2H5O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: C2H5O2+ + H2O = (C2H5O2+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 90.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O2+ H2O) + H2O = (C2H5O2+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 111. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O2+ 2H2O) + H2O = (C2H5O2+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 89.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H5O2+ 3H2O) + H2O = (C2H5O2+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
16. | 334. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: (C2H5O2+ 4H2O) + H2O = (C2H5O2+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88.7 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17. | 280. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: C2H5O4- + 2H2O = C2H7O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: C2H6NO2+ + H2O = (C2H6NO2+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
By formula: (C2H6NO2+ H2O) + H2O = (C2H6NO2+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
30. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
By formula: (C2H6NO2+ 2H2O) + H2O = (C2H6NO2+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
23. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
By formula: (C2H7O+ C2H6O) + H2O = (C2H7O+
H2O
C2H6O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.2 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n, Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 162. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n, Entropy change is questionable; M |
By formula: C2H7O+ + H2O = (C2H7O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 | kJ/mol | PHPMS | Tholman, Tonner, et al., 1994 | gas phase; M |
![]() | 100. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 94.6 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 114. | J/mol*K | PHPMS | Tholman, Tonner, et al., 1994 | gas phase; M |
![]() | 121. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 111. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; M |
By formula: (C2H7O+ H2O
C2H6O) + H2O = (C2H7O+
2H2O
C2H6O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: (C2H7O+ H2O
2C2H6O) + H2O = (C2H7O+
2H2O
2C2H6O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 127. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: (C2H7O+ H2O
3C2H6O) + H2O = (C2H7O+
2H2O
3C2H6O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 127. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: (C2H7O+ 2H2O
C2H6O) + H2O = (C2H7O+
3H2O
C2H6O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 112. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: (C2H7O+ H2O) + H2O = (C2H7O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.0 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: (C2H7O+ 2H2O) + H2O = (C2H7O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Tholman, Tonner, et al., 1994 | gas phase; M |
![]() | 57.7 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.0 | J/mol*K | PHPMS | Tholman, Tonner, et al., 1994 | gas phase; M |
![]() | 106. | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: (C2H7O+ 3H2O) + H2O = (C2H7O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42.7 | kJ/mol | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.5 | J/mol*K | PHPMS | Hiraoka, Grimsrud, et al., 1974 | gas phase; n; M |
By formula: C2H7O+ + H2O = (C2H7O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 111. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 100. | kJ/mol | PHPMS | Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 128. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
By formula: (C2H7O+ H2O) + H2O = (C2H7O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 78.2 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 80.3 | kJ/mol | PHPMS | Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 120. | J/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
By formula: (C2H7O+ 2H2O) + H2O = (C2H7O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 59.4 | kJ/mol | PHPMS | Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
By formula: (C2H7O+ 3H2O) + H2O = (C2H7O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.3 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 52.3 | kJ/mol | PHPMS | Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.4 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 110. | J/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
By formula: (C2H7O+ 4H2O) + H2O = (C2H7O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.4 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C2H7O+ 5H2O) + H2O = (C2H7O+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 | kJ/mol | PHPMS | Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
By formula: C2H7O2- + H2O + CH4O = C2H9O3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.5 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 42.3 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
By formula: C2H7O5- + 3H2O = C2H9O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: C2H7O5S- + 2H2O = C2H9O6S-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: C2H7S+ + H2O = (C2H7S+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50. | kJ/mol | ICR | Berman and Beauchamp, 1986 | gas phase; bracketing; Lias, Liebman, et al., 1984; M |
![]() | 54.8 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.6 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: (C2H7S+ H2O) + H2O = (C2H7S+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: C2H7S+ + H2O = (C2H7S+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.5 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.4 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: C2H8N+ + H2O = (C2H8N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (C2H8N+ H2O) + H2O = (C2H8N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.5 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (C2H8N+ 2H2O) + H2O = (C2H8N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (C2H8N+ 3H2O) + H2O = (C2H8N+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H8N+ 4H2O) + H2O = (C2H8N+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C2H8N+ 5H2O) + H2O = (C2H8N+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88.7 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 255. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: C2H8N+ + H2O = (C2H8N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.2 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 108. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
By formula: (C2H8N+ H2O) + H2O = (C2H8N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.5 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 124. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
By formula: (C2H8N+ 2H2O) + H2O = (C2H8N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 129. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase; M |
C2H8O8S2-2 + 3 = C2H10O9S2-2
By formula: C2H8O8S2-2 + 3H2O = C2H10O9S2-2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31.4 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; B |
By formula: C2H9N+ + H2O = (C2H9N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
33. | 293. | ES/HPMS | Blades, Klassen, et al., 1995 | gas phase; M |
By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63.6 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.9 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase; B |
C2H10O9S2-2 + 4 = C2H12O10S2-2
By formula: C2H10O9S2-2 + 4H2O = C2H12O10S2-2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27.6 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; B |
C2H12O10S2-2 + 5 = C2H14O11S2-2
By formula: C2H12O10S2-2 + 5H2O = C2H14O11S2-2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24.7 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; B |
C2H14O11S2-2 + 6 = C2H16O12S2-2
By formula: C2H14O11S2-2 + 6H2O = C2H16O12S2-2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; B |
By formula: C3H2F3O- + H2O = (C3H2F3O- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: C3H2F3O- + H2O = (C3H2F3O- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 72.4 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: C3H2N+ + H2O = (C3H2N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.5 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99.6 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; M |
By formula: C3H2NO2- + H2O = (C3H2NO2- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.83 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.7 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: (C3H2NO2- H2O) + H2O = (C3H2NO2-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.8 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
By formula: C3H3N2- + H2O = (C3H3N2- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.6 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: (C3H3N2- H2O) + H2O = (C3H3N2-
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 76.1 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: (C3H3N2- 2H2O) + H2O = (C3H3N2-
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 122. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: C3H3O4- + H2O = (C3H3O4- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1995 | gas phase; M |
By formula: (C3H3O4- H2O) + H2O = (C3H3O4-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1995 | gas phase; M |
By formula: C3H4N2+ + H2O = (C3H4N2+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99.6 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: (C3H4N2+ H2O) + H2O = (C3H4N2+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.7 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: (C3H4N2+ 2H2O) + H2O = (C3H4N2+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 125. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1988 | gas phase; M |
By formula: C3H4O5- + H2O + C2H4O2 = C3H6O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19.2 ± 0.84 | kJ/mol | IMRE | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: C3H5O+ + H2O = (C3H5O+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.1 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.9 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: (C3H5O+ H2O) + H2O = (C3H5O+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.4 | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: (C3H5O+ 2H2O) + H2O = (C3H5O+
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.4 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 115. | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: (C3H5O+ 3H2O) + H2O = (C3H5O+
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 | kJ/mol | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
By formula: C3H5O+ + H2O = (C3H5O+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 99.2 | kJ/mol | PHPMS | Davidson, Meza-Hojer, et al., 1979 | gas phase; forms protonated propanoic acid; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 147. | J/mol*K | PHPMS | Davidson, Meza-Hojer, et al., 1979 | gas phase; forms protonated propanoic acid; M |
By formula: (C3H5O+ 2H2O) + H2O = (C3H5O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.6 | kJ/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
By formula: (C3H5O+ 3H2O) + H2O = (C3H5O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 | kJ/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
By formula: C3H5O- + H2O = (C3H5O- H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.1 ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 4.2 | kJ/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: C3H5O2- + H2O = (C3H5O2- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.2 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38.9 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 35.1 ± 0.84 | kJ/mol | N/A | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: (C3H5O2- H2O) + H2O = (C3H5O2-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.6 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 28.9 ± 0.84 | kJ/mol | N/A | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: (C3H5O2- 2H2O) + H2O = (C3H5O2-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.6 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.3 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
![]() | 21.3 ± 0.84 | kJ/mol | N/A | Viidanoja, Reiner, et al., 2000 | gas phase; B |
By formula: C3H5O3- + H2O = (C3H5O3- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C3H5O3- H2O) + H2O = (C3H5O3-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.5 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.2 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C3H5O3- + H2O = (C3H5O3- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.3 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 36.0 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C3H5O3- H2O) + H2O = (C3H5O3-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.5 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: (C3H5O3- 2H2O) + H2O = (C3H5O3-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.4 ± 6.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.1 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M |
By formula: C3H5O5- + 2H2O = C3H7O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.7 ± 1.3 | kJ/mol | TDAs | Blades, Klassen, et al., 1995 | gas phase; B |
By formula: C3H6+ + H2O = (C3H6+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 | kJ/mol | CID | Holmes, Mommers, et al., 1984 | gas phase; structure confirmed as ion-dipole complex in Shao, Baer, et al., 1987; M |
By formula: C3H6NO2- + H2O = C3H8NO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.0 ± 1.7 | kJ/mol | N/A | Wincel, 2008 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32.6 ± 3.3 | kJ/mol | TDAs | Wincel, 2008 | gas phase; B |
By formula: C3H7+ + H2O = (C3H7+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.6 | kJ/mol | HPMS | Beggs and Field, 1971 | gas phase; «DELTA»rH inconsistent with (CH3)2CHOH2+ product; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 116. | J/mol*K | HPMS | Beggs and Field, 1971 | gas phase; «DELTA»rH inconsistent with (CH3)2CHOH2+ product; M |
By formula: C3H7O+ + H2O = (C3H7O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 85.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 109. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C3H7O+ H2O) + H2O = (C3H7O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C3H7O+ 2H2O) + H2O = (C3H7O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.6 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C3H7O+ 3H2O) + H2O = (C3H7O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: (C3H7O+ 4H2O) + H2O = (C3H7O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.3 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
By formula: C3H7O+ + H2O = (C3H7O+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), Ross, et al., 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.7 | J/mol*K | PHPMS | Meot-Ner (Mautner), Ross, et al., 1985 | gas phase; M |
By formula: C3H9O+ + H2O = (C3H9O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ H2O) + H2O = (C3H9O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.9 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 2H2O) + H2O = (C3H9O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.4 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 3H2O) + H2O = (C3H9O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 4H2O) + H2O = (C3H9O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 86.6 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 5H2O) + H2O = (C3H9O+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.0 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: C3H9O+ + H2O = (C3H9O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.2 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; unusually small «DELTA»rH and «DELTA»rS; M |
![]() | 56.5 | kJ/mol | HPMS | Beggs and Field, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 57.3 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; unusually small «DELTA»rH and «DELTA»rS; M |
![]() | 53.1 | J/mol*K | HPMS | Beggs and Field, 1971 | gas phase; M |
By formula: (C3H9O+ H2O) + H2O = (C3H9O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.6 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 62.3 | kJ/mol | HPMS | Beggs and Field, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 90.0 | J/mol*K | HPMS | Beggs and Field, 1971 | gas phase; M |
By formula: (C3H9O+ 2H2O) + H2O = (C3H9O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.3 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 3H2O) + H2O = (C3H9O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.9 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.0 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 4H2O) + H2O = (C3H9O+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.6 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 5H2O) + H2O = (C3H9O+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 89.1 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
By formula: (C3H9O+ 6H2O) + H2O = (C3H9O+
7H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Hiraoka, Takimoto, et al., 1986 | gas phase; Entropy change calculated or estimated; M |
By formula: C3H9S+ + H2O = (C3H9S+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.7 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 347. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: C3H9S+ + H2O = (C3H9S+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.2 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17. | 446. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: C3H9S+ + H2O = (C3H9S+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
18. | 418. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: C3H9Si+ + H2O = (C3H9Si+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 126. ± 7.9 | kJ/mol | PHPMS | Stone and Wojtyniak, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Stone and Wojtyniak, 1986 | gas phase; M |
By formula: (C3H9Si+ H2O) + H2O = (C3H9Si+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 83.3 | kJ/mol | PHPMS | Stone and Wytenberg, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. | J/mol*K | PHPMS | Stone and Wytenberg, 1987 | gas phase; M |
By formula: C3H9Sn+ + H2O = (C3H9Sn+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 108. | kJ/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 115. | J/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
46.9 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M |
By formula: (C3H10N+ 2C3H9N) + H2O = (C3H10N+
H2O
2C3H9N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. | kJ/mol | PHPMS | El-Shall, Daly, et al., 1992 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | El-Shall, Daly, et al., 1992 | gas phase; M |
By formula: C3H10N+ + H2O = (C3H10N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.7 | kJ/mol | PHPMS | El-Shall, Daly, et al., 1992 | gas phase; M |
![]() | 60.7 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 60.7 | kJ/mol | PHPMS | Meot-Ner M. and Sieck, 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | El-Shall, Daly, et al., 1992 | gas phase; M |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; M |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner M. and Sieck, 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |