Water

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 551 to 600

(O2S- • 6Sulfur dioxide • 2Water) + Sulfur dioxide = (O2S- • 7Sulfur dioxide • 2Water)

By formula: (O2S- • 6O2S • 2H2O) + O2S = (O2S- • 7O2S • 2H2O)

Quantity Value Units Method Reference Comment
Δr3.70 ± 0.70kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr0.60 ± 0.20kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B

(CH2OH+ • 3Water) + Water = (CH2OH+ • 4Water)

By formula: (CH3O+ • 3H2O) + H2O = (CH3O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.9kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr23.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ • 4Water) + Water = (CH2OH+ • 5Water)

By formula: (CH3O+ • 4H2O) + H2O = (CH3O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr11.1kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr22.6cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ • 6Water) + Water = (CH2OH+ • 7Water)

By formula: (CH3O+ • 6H2O) + H2O = (CH3O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.0kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr25.7cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

2,2-Dimethoxy-4,4-dimethylpentane + Water = 2-Pentanone, 4,4-dimethyl- + 2Methyl Alcohol

By formula: C9H20O2 + H2O = C7H14O + 2CH4O

Quantity Value Units Method Reference Comment
Δr1.642 ± 0.021kcal/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis; ALS
Δr1.64 ± 0.02kcal/molCmWiberg and Squires, 1979liquid phase; Heat of hydrolysis; ALS

(O2S- • Water • 3Sulfur dioxide) + Water = (O2S- • 2Water • 3Sulfur dioxide)

By formula: (O2S- • H2O • 3O2S) + H2O = (O2S- • 2H2O • 3O2S)

Quantity Value Units Method Reference Comment
Δr7.10 ± 0.40kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr3.80 ± 0.20kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • Water • 4Sulfur dioxide) + Water = (O2S- • 2Water • 4Sulfur dioxide)

By formula: (O2S- • H2O • 4O2S) + H2O = (O2S- • 2H2O • 4O2S)

Quantity Value Units Method Reference Comment
Δr7.10 ± 0.70kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr3.00 ± 0.20kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B

(Hydronium cation • 4Water) + Sulfur dioxide = (Hydronium cation • Sulfur dioxide • 4Water)

By formula: (H3O+ • 4H2O) + O2S = (H3O+ • O2S • 4H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.6300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
2.6300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH2OH+ • 5Water) + Water = (CH2OH+ • 6Water)

By formula: (CH3O+ • 5H2O) + H2O = (CH3O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.5kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr20.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 2Water) + Water = (C2H4N+ • 3Water)

By formula: (C2H4N+ • 2H2O) + H2O = (C2H4N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr15.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr24.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 3Water) + Water = (C2H4N+ • 4Water)

By formula: (C2H4N+ • 3H2O) + H2O = (C2H4N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr11.2kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr21.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 4Water) + Water = (C2H4N+ • 5Water)

By formula: (C2H4N+ • 4H2O) + H2O = (C2H4N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.4kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr23.4cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 5Water) + Water = (C2H4N+ • 6Water)

By formula: (C2H4N+ • 5H2O) + H2O = (C2H4N+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.1kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr25.5cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 2Water) + Water = (C2H5O+ • 3Water)

By formula: (C2H5O+ • 2H2O) + H2O = (C2H5O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr17.0kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr27.9cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 3Water) + Water = (C2H5O+ • 4Water)

By formula: (C2H5O+ • 3H2O) + H2O = (C2H5O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr11.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 2Water) + Water = (C2H5O+ • 3Water)

By formula: (C2H5O+ • 2H2O) + H2O = (C2H5O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.9kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr23.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 3Water) + Water = (C2H5O+ • 4Water)

By formula: (C2H5O+ • 3H2O) + H2O = (C2H5O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr20.4cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ • 2Water) + Water = (C2H5O2+ • 3Water)

By formula: (C2H5O2+ • 2H2O) + H2O = (C2H5O2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr13.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H8N+ • 3Water) + Water = (C2H8N+ • 4Water)

By formula: (C2H8N+ • 3H2O) + H2O = (C2H8N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.5kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr25.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H4N2+ • 2Water) + Water = (C3H4N2+ • 3Water)

By formula: (C3H4N2+ • 2H2O) + H2O = (C3H4N2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.2kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr29.8cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H7O+ • 2Water) + Water = (C3H7O+ • 3Water)

By formula: (C3H7O+ • 2H2O) + H2O = (C3H7O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.7kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr21.9cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ • 3Water) + Water = (C3H7O+ • 4Water)

By formula: (C3H7O+ • 3H2O) + H2O = (C3H7O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ • 4Water) + Water = (C3H7O+ • 5Water)

By formula: (C3H7O+ • 4H2O) + H2O = (C3H7O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C5H9O+ • 2Water) + Water = (C5H9O+ • 3Water)

By formula: (C5H9O+ • 2H2O) + H2O = (C5H9O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.2kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr19.3cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH6N+ • 3Water) + Water = (CH6N+ • 4Water)

By formula: (CH6N+ • 3H2O) + H2O = (CH6N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr22.0cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(O2S- • 6Sulfur dioxide • Water) + Sulfur dioxide = (O2S- • 7Sulfur dioxide • Water)

By formula: (O2S- • 6O2S • H2O) + O2S = (O2S- • 7O2S • H2O)

Quantity Value Units Method Reference Comment
Δr3.20 ± 0.60kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr0.70 ± 0.20kcal/molTDAsVacher, Leduc, et al., 1994gas phase; B

(NO3 anion • Sulfur dioxide) + Water = (NO3 anion • Water • Sulfur dioxide)

By formula: (NO3- • O2S) + H2O = (NO3- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr4.30 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.3299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • Water) + Sulfur dioxide = (Iodide • Sulfur dioxide • Water)

By formula: (I- • H2O) + O2S = (I- • O2S • H2O)

Quantity Value Units Method Reference Comment
Δr9.00 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.1300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H5O+ • 4Water) + Water = (C2H5O+ • 5Water)

By formula: (C2H5O+ • 4H2O) + H2O = (C2H5O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.4kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr18.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 5Water) + Water = (C2H5O+ • 6Water)

By formula: (C2H5O+ • 5H2O) + H2O = (C2H5O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr21.7cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 6Water) + Water = (C2H5O+ • 7Water)

By formula: (C2H5O+ • 6H2O) + H2O = (C2H5O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr25.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • Water) + Water = (C2H5O+ • 2Water)

By formula: (C2H5O+ • H2O) + H2O = (C2H5O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr16.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr25.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • Water) + Water = (C2H5O+ • 2Water)

By formula: (C2H5O+ • H2O) + H2O = (C2H5O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr17.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr26.4cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ • Water) + Water = (C2H5O2+ • 2Water)

By formula: (C2H5O2+ • H2O) + H2O = (C2H5O2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr16.2kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr26.5cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H8N+ • 4Water) + Water = (C2H8N+ • 5Water)

By formula: (C2H8N+ • 4H2O) + H2O = (C2H8N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.4kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr24.4cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H10N+ • 3Water) + Water = (C3H10N+ • 4Water)

By formula: (C3H10N+ • 3H2O) + H2O = (C3H10N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.9kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr24.9cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H4N2+ • Water) + Water = (C3H4N2+ • 2Water)

By formula: (C3H4N2+ • H2O) + H2O = (C3H4N2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.6kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr23.3cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H7O+ • Water) + Water = (C3H7O+ • 2Water)

By formula: (C3H7O+ • H2O) + H2O = (C3H7O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr13.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr23.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C5H9O+ • Water) + Water = (C5H9O+ • 2Water)

By formula: (C5H9O+ • H2O) + H2O = (C5H9O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr11.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr20.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C7H11O+ • 2Water) + Water = (C7H11O+ • 3Water)

By formula: (C7H11O+ • 2H2O) + H2O = (C7H11O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr8.9kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr17.1cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C7H11O+ • Water) + Water = (C7H11O+ • 2Water)

By formula: (C7H11O+ • H2O) + H2O = (C7H11O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr11.2kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr22.3cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C8H9O • Water) + Water = (C8H9O • 2Water)

By formula: (C8H9O • H2O) + H2O = (C8H9O • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.7kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr21.1cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

HO4S- + Water = (HO4S- • Water)

By formula: HO4S- + H2O = (HO4S- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr5.90 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(C4H10NO+ • 2Water) + Water = (C4H10NO+ • 3Water)

By formula: (C4H10NO+ • 2H2O) + H2O = (C4H10NO+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr9.3kcal/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr19.2cal/mol*KPHPMSMeot-Ner, 1984gas phase; M

HCaO+ + Water = (HCaO+ • Water)

By formula: HCaO+ + H2O = (HCaO+ • H2O)

Quantity Value Units Method Reference Comment
Δr34.4kcal/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr21.5cal/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

HOSr+ + Water = (HOSr+ • Water)

By formula: HOSr+ + H2O = (HOSr+ • H2O)

Quantity Value Units Method Reference Comment
Δr29.9kcal/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr21.5cal/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

(C2H7O+ • 5Water) + Water = (C2H7O+ • 6Water)

By formula: (C2H7O+ • 5H2O) + H2O = (C2H7O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr13.1kcal/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KPHPMSKebarle, 1977gas phase; M

C11H18N+ + Water = (C11H18N+ • Water)

By formula: C11H18N+ + H2O = (C11H18N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.8kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr32.1cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C12H28N+ + Water = (C12H28N+ • Water)

By formula: C12H28N+ + H2O = (C12H28N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr13.6kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr36.4cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C3H2N+ + Water = (C3H2N+ • Water)

By formula: C3H2N+ + H2O = (C3H2N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.3kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.8cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vacher, Leduc, et al., 1994
Vacher, J.R.; Leduc, E.; Fitaire, M., Stabilities of Anionic Mixed Clusters of Sulfur Dioxide and Water, Int. J. Mass Spectrom. Ion Proc., 1994, 135, 2-3, 139, https://doi.org/10.1016/0168-1176(94)03985-2 . [all data]

Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration, J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016 . [all data]

Wiberg, 1980
Wiberg, K.B., Energies of organic compounds, Rept. DOE-E(11-1)4060 Prepared for US Dept. of Energy by Yale Univ., New Haven, CT. Avail. NTIS, 1980, 1-24. [all data]

Wiberg and Squires, 1979
Wiberg, K.B.; Squires, R.R., Thermodynamics of hydrolysis aliphatic ketals. An entropy component of steric effects, J. Am. Chem. Soc., 1979, 101, 5512-5515. [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Meot-Ner (Mautner), 1988
Meot-Ner (Mautner), M., Models for Strong Interactions in Proteins and Enzymes. 2. Interactions of Ions with the Peptide Link and Imidazole, J. Am. Chem. Soc., 1988, 110, 10, 3075, https://doi.org/10.1021/ja00218a014 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner), The Ionic Hydrogen Bond. 4. Intramolecular and Multiple Bonds. Proton Affinities, Hydration and Complexes of Amides and Amino Acid Derivatives, J. Am. Chem. Soc., 1984, 106, 2, 278, https://doi.org/10.1021/ja00314a003 . [all data]

Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N., Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer., J. Chem. Soc. Faraday Trans. 1, 1982, 78, 2997. [all data]

Kebarle, 1977
Kebarle, P., Ion Thermochemistry and Solvation from Gas Phase Ion Equilibria, Ann. Rev. Phys. Chem., 1977, 28, 1, 445, https://doi.org/10.1146/annurev.pc.28.100177.002305 . [all data]

Meot-Ner M. and Sieck, 1983
Meot-Ner M.; Sieck, L.W., The Ionic Hydrogen Bond. 1. Sterically Hindered Bonds. Solvation and Clustering of Sterically Hindered Amines and Pyridines, J. Am. Chem. Soc., 1983, 105, 10, 2956, https://doi.org/10.1021/ja00348a005 . [all data]

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]


Notes

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