Water

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

Copper ion (1+) + Water = (Copper ion (1+) • Water)

By formula: Cu+ + H2O = (Cu+ • H2O)

Quantity Value Units Method Reference Comment
Δr49.8kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Δr150. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr150. ± 10.kJ/molCIDMagnera, David, et al., 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Δr18.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
157. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Hydronium cation • 5Water) + Water = (Hydronium cation • 6Water)

By formula: (H3O+ • 5H2O) + H2O = (H3O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.8kJ/molPHPMSLau, Ikuta, et al., 1982gas phase; M
Δr49.0kJ/molHPMSKebarle, Searles, et al., 1967gas phase; M
Δr67.32kJ/molMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSLau, Ikuta, et al., 1982gas phase; M
Δr124.J/mol*KHPMSKebarle, Searles, et al., 1967gas phase; M
Δr346.0J/mol*KMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M

(Chlorine anion • 4Water) + Water = (Chlorine anion • 5Water)

By formula: (Cl- • 4H2O) + H2O = (Cl- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr28.0kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr40. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr12. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Fluorine anion • 4Water) + Water = (Fluorine anion • 5Water)

By formula: (F- • 4H2O) + H2O = (F- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr55.2 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr128.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr19. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr29.7kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr19. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Lithium ion (1+) • 3Water) + Water = (Lithium ion (1+) • 4Water)

By formula: (Li+ • 3H2O) + H2O = (Li+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 4Water) + Water = (Lithium ion (1+) • 5Water)

By formula: (Li+ • 4H2O) + H2O = (Li+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Fluorine anion • 3Water) + Water = (Fluorine anion • 4Water)

By formula: (F- • 3H2O) + H2O = (F- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.2 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr56.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr113.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr25. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr23.0kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Copper ion (1+) • Water) + Water = (Copper ion (1+) • 2Water)

By formula: (Cu+ • H2O) + H2O = (Cu+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Δr160. ± 10.kJ/molCIDMagnera, David, et al., 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Δr27.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
170. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(CN- • 2Water) + Water = (CN- • 3Water)

By formula: (CN- • 2H2O) + H2O = (CN- • 3H2O)

Quantity Value Units Method Reference Comment
Δr44.8 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B,M
Δr44.8kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.8J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr82.8J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr33. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B

CH3O- + Water = (CH3O- • Water)

By formula: CH3O- + H2O = (CH3O- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr106. ± 9.2kJ/molCIDTDeTuri and Ervin, 1999gas phase; B
Δr100.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M,B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSMeot-ner and Sieck, 1986gas phase; M
Δr95.8J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr71.1 ± 1.3kJ/molTDAsMeot-ner and Sieck, 1986gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
64.4296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)H2O, DG>; Meot-Ner(Mautner), 1986; M

(NH4+ • 2Water) + Water = (NH4+ • 3Water)

By formula: (H4N+ • 2H2O) + H2O = (H4N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr56.1kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Δr51.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr105.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Δr88.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr27.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • 3Water) + Water = (Iodide • 4Water)

By formula: (I- • 3H2O) + H2O = (I- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr29. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr98.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr8.8 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr9.2 ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(C3H10N+ • 3Water) + Water = (C3H10N+ • 4Water)

By formula: (C3H10N+ • 3H2O) + H2O = (C3H10N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated, attributed to MeNH3+.4H2O by error in footnote; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated, attributed to MeNH3+.4H2O by error in footnote; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.254.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated, attributed to MeNH3+.4H2O by error in footnote; M

(Rubidium ion (1+) • 2Water) + Water = (Rubidium ion (1+) • 3Water)

By formula: (Rb+ • 2H2O) + H2O = (Rb+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(CH6N+ • 2Water) + Water = (CH6N+ • 3Water)

By formula: (CH6N+ • 2H2O) + H2O = (CH6N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr51.9kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Δr51.9kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr22.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Rubidium ion (1+) • Water) + Water = (Rubidium ion (1+) • 2Water)

By formula: (Rb+ • H2O) + H2O = (Rb+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(CH6N+ • Water) + Water = (CH6N+ • 2Water)

By formula: (CH6N+ • H2O) + H2O = (CH6N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr61.1kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Δr61.1kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr112.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Δr112.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr31.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • 4Water) + Water = (Iodide • 5Water)

By formula: (I- • 4H2O) + H2O = (I- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Δr17.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr6.28kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

CF3CO2 anion + Water = (CF3CO2 anion • Water)

By formula: C2F3O2- + H2O = (C2F3O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.7 ± 6.3kJ/molN/ABlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr57.3 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr27. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B

(Sodium ion (1+) • 4Water) + Water = (Sodium ion (1+) • 5Water)

By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr44.8kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Δr48.5kJ/molHPMSTang and Castleman, 1972gas phase; M
Δr51.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
Δr111.J/mol*KHPMSTang and Castleman, 1972gas phase; M
Δr118.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • Carbon dioxide) + Water = (Sodium ion (1+) • Water • Carbon dioxide)

By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)

Quantity Value Units Method Reference Comment
Δr86.6kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Δr95.8kJ/molFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Δr107.J/mol*KFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M

(Chlorine anion • 5Water) + Water = (Chlorine anion • 6Water)

By formula: (Cl- • 5H2O) + H2O = (Cl- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr35.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr37. ± 2.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

C3H10N+ + Water = (C3H10N+ • Water)

By formula: C3H10N+ + H2O = (C3H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr60.7kJ/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Δr60.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr60.7kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Δr101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr101.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

CH6N+ + Water = (CH6N+ • Water)

By formula: CH6N+ + H2O = (CH6N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr78.7kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Δr78.7kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr44.8kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Potassium ion (1+) • 3Water) + Water = (Potassium ion (1+) • 4Water)

By formula: (K+ • 3H2O) + H2O = (K+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr49.4kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr103.J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Potassium ion (1+) • Water) + Water = (Potassium ion (1+) • 2Water)

By formula: (K+ • H2O) + H2O = (K+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr67.4kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr101.J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

C7H10N+ + Water = (C7H10N+ • Water)

By formula: C7H10N+ + H2O = (C7H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.5kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; ring to N proton shift on hydration; M

C7H10NO+ + Water = (C7H10NO+ • Water)

By formula: C7H10NO+ + H2O = (C7H10NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

C7H10NS + Water = (C7H10NS • Water)

By formula: C7H10NS + H2O = (C7H10NS • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.6433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

C8H12N+ + Water = (C8H12N+ • Water)

By formula: C8H12N+ + H2O = (C8H12N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.434.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

Nitric oxide anion + Water = (Nitric oxide anion • Water)

By formula: NO- + H2O = (NO- • H2O)

Quantity Value Units Method Reference Comment
Δr77.4kJ/molPHPMSFrench, Hills, et al., 1973gas phase; M
Δr69.5kJ/molPESEaton, Arnold, et al., 1990gas phase; M
Δr95.0kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSFrench, Hills, et al., 1973gas phase; M
Δr100.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
53.1296.SAMSPuckett and Teague, 1971gas phase; switching reaction(NO+)NO; M

HCO2 anion + Water = (HCO2 anion • Water)

By formula: CHO2- + H2O = (CHO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr66.9 ± 4.2kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr38. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B
Δr35.1 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B
Δr38.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

ClO2- + Water = (ClO2- • Water)

By formula: ClO2- + H2O = (ClO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.6 ± 2.1kJ/molTherTschurl and Boesl, 2007gas phase; affinity is difference from ClO2- EA, corrected for calculated neutral BE of 0.09 eV; B
Δr66.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr37.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(Hydroxyl anion • 3Water) + Water = (Hydroxyl anion • 4Water)

By formula: (HO- • 3H2O) + H2O = (HO- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr50.2kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr59.4kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr88.3J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr123.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr23.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

(Oxygen anion • Water) + Water = (Oxygen anion • 2Water)

By formula: (O2- • H2O) + H2O = (O2- • 2H2O)

Quantity Value Units Method Reference Comment
Δr72.0 ± 4.2kJ/molTDAsArshadi and Kebarle, 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr40.6kJ/molTDAsArshadi and Kebarle, 1970gas phase; B
Δr36. ± 4.2kJ/molIMREPayzant J.D. and Kebarle, 1972gas phase; B
Δr41. ± 4.2kJ/molIMREPack and Phelps, 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.300.PHPMSPayzant J.D. and Kebarle, 1972gas phase; M

(Cesium ion (1+) • 2Water) + Water = (Cesium ion (1+) • 3Water)

By formula: (Cs+ • 2H2O) + H2O = (Cs+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr41.kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr46.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr69.5J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr99.2J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr20.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

(Hydronium cation • 6Water) + Water = (Hydronium cation • 7Water)

By formula: (H3O+ • 6H2O) + H2O = (H3O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Δr43.1kJ/molHPMSKebarle, Searles, et al., 1967gas phase; M
Δr50.33kJ/molMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KHPMSKebarle, Searles, et al., 1967gas phase; M
Δr218.9J/mol*KMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M

(Nitric oxide anion • Water) + Water = (Nitric oxide anion • 2Water)

By formula: (NO- • H2O) + H2O = (NO- • 2H2O)

Quantity Value Units Method Reference Comment
Δr65.69kJ/molN/AEaton, Arnold, et al., 1990gas phase; Vertical Detachment Energy: 1.860±0.020 eV; B,M
Δr67.4kJ/molPHPMSFrench, Hills, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSFrench, Hills, et al., 1973gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.293.HPMSMcAdams and Bone, 1972gas phase; M
36.296.FAHoward, Rundle, et al., 1971gas phase; M
36.296.SAMSPuckett and Teague, 1971gas phase; M

(Bromine anion • 4Water) + Water = (Bromine anion • 5Water)

By formula: (Br- • 4H2O) + H2O = (Br- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.2 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr119.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion • 5Water) + Water = (Bromine anion • 6Water)

By formula: (Br- • 5H2O) + H2O = (Br- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr25. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.5 ± 8.8kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Mg+2 • 10Water) + Water = (Mg+2 • 11Water)

By formula: (Mg+2 • 10H2O) + H2O = (Mg+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M
31.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mg+2 • 11Water) + Water = (Mg+2 • 12Water)

By formula: (Mg+2 • 11H2O) + H2O = (Mg+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Oxygen anion • 2Water) + Water = (Oxygen anion • 3Water)

By formula: (O2- • 2H2O) + H2O = (O2- • 3H2O)

Quantity Value Units Method Reference Comment
Δr64.4 ± 4.2kJ/molTDAsArshadi and Kebarle, 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr29.3kJ/molTDAsArshadi and Kebarle, 1970gas phase; B
Δr26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.296.FAFehsenfeld and Ferguson, 1974gas phase; M
30.300.PHPMSPayzant J.D. and Kebarle, 1972gas phase; M

(Hydroxyl anion • 2Water) + Water = (Hydroxyl anion • 3Water)

By formula: (HO- • 2H2O) + H2O = (HO- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr67.8kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr63.2kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Δr75.kJ/molCIDDePaz, Giardini, et al., 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr104.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

(NO3 anion • 2Water) + Water = (NO3 anion • 3Water)

By formula: (NO3- • 2H2O) + H2O = (NO3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr57.7kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr139.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr16.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

HO- + Hydrogen cation = Water

By formula: HO- + H+ = H2O

Quantity Value Units Method Reference Comment
Δr1633.141 ± 0.042kJ/molD-EASmith, Kim, et al., 1997gas phase; Given: 14741.02(3) cm-1. dHacid(0K) = 389.11±0.014; B
Δr1622.1kJ/molN/ACheck, Faust, et al., 2001gas phase; MnBr3-; ; ΔS(EA)=1.7; B
Quantity Value Units Method Reference Comment
Δr1605.57 ± 0.25kJ/molH-TSSmith, Kim, et al., 1997gas phase; Given: 14741.02(3) cm-1. dHacid(0K) = 389.11±0.014; B
Δr1594.5kJ/molN/ACheck, Faust, et al., 2001gas phase; MnBr3-; ; ΔS(EA)=1.7; B

(Lithium ion (1+) • 2Water) + Water = (Lithium ion (1+) • 3Water)

By formula: (Li+ • 2H2O) + H2O = (Li+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Δr86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Δr104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

NH4+ + Water = (NH4+ • Water)

By formula: H4N+ + H2O = (H4N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr86.2kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr83.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr72.4kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr96.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr82.4J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

Water + Propane, 2,2-dimethoxy- = 2Methyl Alcohol + Acetone

By formula: H2O + C5H12O2 = 2CH4O + C3H6O

Quantity Value Units Method Reference Comment
Δr20.3 ± 0.04kJ/molCmWiberg, Morgan, et al., 1994liquid phase; ALS
Δr20.43 ± 0.04kJ/molCmWiberg and Squires, 1979liquid phase; Heat of hydrolysis; ALS
Δr20.433 ± 0.028kJ/molCmWiberg and Squires, 1979, 2liquid phase; solvent: Water; Hydrolysis; ALS
Δr-16.5 ± 0.2kJ/molCmStern and Dorer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 15.4 ± 0.2 kJ/mol; Heat of hydrolysis; ALS

Fluorine anion + Water = (Fluorine anion • Water)

By formula: F- + H2O = (F- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr114.6 ± 2.1kJ/molTDAsWeis, Kemper, et al., 1999gas phase; B
Δr97.49kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr91.6 ± 2.1kJ/molTDAsWeis, Kemper, et al., 1999gas phase; B
Δr75.7 ± 8.4kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

El-Shall, Schriver, et al., 1989
El-Shall, M.S.; Schriver, K.E.; Whetten, R.L.; Meot-Ner (Mautner), M., Ion/Molecule Clustering Thermochemistry by Laser Ionization High - Pressure Mass Spectrometry, J. Phys. Chem., 1989, 93, 24, 7969, https://doi.org/10.1021/j100361a002 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Magnera, David, et al., 1989, 2
Magnera, T.F.; David, D.E.; Stulik, D.; Orth, R.G.; Jorikman, H.T.; Michl, J., Production of Hydrated Metal Ions by Fast Ion or Atom Beam Sputtering. Collision - Induced Dissociation and Successive Hydration Energies of Gaseous Cu+ with 1 - 4 Water Molecules, J. Am. Chem. Soc., 1989, 111, 14, 5036, https://doi.org/10.1021/ja00196a003 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Lau, Ikuta, et al., 1982
Lau, Y.K.; Ikuta, S.; Kebarle, P., Thermodynamics and Kinetics of the Gas - Phase Reactions: H3O+(H2O)n - 1 + H2O = H3O+(H2O)n, J. Am. Chem. Soc., 1982, 104, 6, 1462, https://doi.org/10.1021/ja00370a002 . [all data]

Kebarle, Searles, et al., 1967
Kebarle, P.; Searles, S.K.; Zolla, A.; Scarborough, J.; Arshadi, M., The Solvation of the Hydrogen Ion by Water Molecules in the Gas Phase. Heats and Entropies of Solvation of the Individual Reactions: H+(H2O)n-1 + H2O = H+(H2O)n, J. Am. Chem. Soc., 1967, 89, 25, 6393, https://doi.org/10.1021/ja01001a001 . [all data]

Shi, Ford, et al., 1993
Shi, Z.; Ford, V.; Wei, S.; Castleman, A.W., Water Clusters - Contributions of Binding Energy and Entropy to Stability, J. Chem. Phys., 1993, 99, 10, 8009, https://doi.org/10.1063/1.465678 . [all data]

Magnera, David, et al., 1991
Magnera, T.F.; David, D.E.; Michl, J., The First Twenty - Eight Proton Hydration Energies, Chem. Phys. Lett., 1991, 182, 3-4, 363, https://doi.org/10.1016/0009-2614(91)80230-U . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Blades, Jayaweera, et al., 1990
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Meot-Ner (Mautner) M. and Speller, 1989
Meot-Ner (Mautner) M.; Speller, C.V., Multicomponent Cluster Ions. 2. Comparative Stabilities of Cationic and Anionic Hydrogen Bonded Networks. Mixed Clusters of Water and Hydrogen Cyanide, J. Phys. Chem., 1989, 93, 9, 3663, https://doi.org/10.1021/j100346a058 . [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Meot-Ner (Mautner) and Speller, 1989
Meot-Ner (Mautner), M.; Speller, C.V., Multicomponent Cluster Ions.3. Comparative Stabilities of Cationic and Anionic Hydrogen Bonded Networks. Mixed Clusters of Water and Hydrogen Cyanide, J. Phys. Chem., 1989, 93, 6580. [all data]

DeTuri and Ervin, 1999
DeTuri, V.F.; Ervin, K.M., Competitive threshold collision-induced dissociation: Gas-phase acidities and bond dissociation energies for a series of alcohols, J. Phys. Chem. A, 1999, 103, 35, 6911-6920, https://doi.org/10.1021/jp991459m . [all data]

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]

Meot-ner and Sieck, 1986
Meot-ner, M.; Sieck, L.W., Relative acidities of water and methanol, and the stabilities of the dimer adducts, J. Phys. Chem., 1986, 90, 6687. [all data]

MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K., Proton-Transfer Reactions in Nitromethane at 297K, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7 . [all data]

Meot-Ner (Mautner) and Speller, 1986
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Notes

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