S(CN)2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 67600 ± 1000 gas Rosmus, Stafast, et al., 1975

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 41800 ± 1000 gas Rosmus, Stafast, et al., 1975

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 29850 ± 320 gas Rosmus, Stafast, et al., 1975
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 CS stretch 560 ± 40 gas PE Rosmus, Stafast, et al., 1975

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 23400 ± 320 gas Rosmus, Stafast, et al., 1975
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 CS stretch 840 ± 40 gas PE Rosmus, Stafast, et al., 1975

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 21780 ± 320 gas Rosmus, Stafast, et al., 1975

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 18320 ± 320 gas Rosmus, Stafast, et al., 1975
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CN stretch 1980 ± 40 gas PE Rosmus, Stafast, et al., 1975

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 15730 ± 320 gas Rosmus, Stafast, et al., 1975
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CN stretch 1840 ± 40 gas PE Rosmus, Stafast, et al., 1975

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 15200 ± 1000 gas Rosmus, Stafast, et al., 1975

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CN stretch 2040 ± 40 gas PE Rosmus, Stafast, et al., 1975
2 SC2 stretch 640 ± 40 gas PE Rosmus, Stafast, et al., 1975

Additional references: Jacox, 1994, page 280

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rosmus, Stafast, et al., 1975
Rosmus, P.; Stafast, H.; Bock, H., Sulphur dicyanide: Ionisation potentials Hartree-Fock calculations, Chem. Phys. Lett., 1975, 34, 275. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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