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Nitrogen

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 151 to 156

(Iron ion (1+) bullet Nitrogen) + Nitrogen = (Iron ion (1+) bullet 2Nitrogen)

By formula: (Fe+ bullet N2) + N2 = (Fe+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar19.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

3Ethane, hexafluoro- + 2Nitrogen trifluoride = 6Tetrafluoromethane + Nitrogen

By formula: 3C2F6 + 2F3N = 6CF4 + N2

Quantity Value Units Method Reference Comment
Deltar-311.7 ± 3.0kcal/molCcbSinke, 1966gas phase; ALS

Calcium ion (1+) + Nitrogen = (Calcium ion (1+) bullet Nitrogen)

By formula: Ca+ + N2 = (Ca+ bullet N2)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.0296.FASpears and Fehsenfeld, 1972gas phase; M

Methyl cation + Nitrogen = (Methyl cation bullet Nitrogen)

By formula: CH3+ + N2 = (CH3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar48.4kcal/molPDissFoster, Williamson, et al., 1974gas phase; M

3-Methyl-3-chlorodiazirine = Ethene, chloro- + Nitrogen

By formula: C2H3ClN2 = C2H3Cl + N2

Quantity Value Units Method Reference Comment
Deltar-46.9 ± 3.4kcal/molCmArcher and Tyler, 1976gas phase; ALS

Iron ion (1+) + Nitrogen = (Iron ion (1+) bullet Nitrogen)

By formula: Fe+ + N2 = (Fe+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar12.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Sinke, 1966
Sinke, G.C., The heat of reaction of nitrogen trifluoride and hexafluoroethane, J. Phys. Chem., 1966, 70, 1326-1327. [all data]

Spears and Fehsenfeld, 1972
Spears, K.G.; Fehsenfeld, F.C., Termolecular Association Reactions of Mg, Ca, and Ba Ions, J. Chem. Phys., 1972, 56, 11, 5698, https://doi.org/10.1063/1.1677091 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Archer and Tyler, 1976
Archer, W.H.; Tyler, B.J., Self-heating in the decomposition of 3-methyl-3-chlorodiazirine: Determination of reaction exothermicity and correction of Arrhenius parameters, J. Chem. Soc. Faraday Trans. 1, 1976, 72, 1448-1455. [all data]


Notes

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