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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(FS- bullet 4294967295sulfur) + sulfur = FS-

By formula: (FS- bullet 4294967295S) + S = FS-

Quantity Value Units Method Reference Comment
Deltar56.4 ± 1.5kcal/molN/APolak, Gilles, et al., 1992gas phase

(HS- bullet 4294967295sulfur) + sulfur = HS-

By formula: (HS- bullet 4294967295S) + S = HS-

Quantity Value Units Method Reference Comment
Deltar120.13kcal/molN/AChaibi, Delsart, et al., 2006gas phase; For H(32)S-. Given: 2.3147282(17) eV
Deltar120.18 ± 0.18kcal/molTherBreyer, Frey, et al., 1981gas phase
Deltar120.4 ± 2.2kcal/molTherBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale
Deltar85.57kcal/molTherShiell, Hu, et al., 1900gas phase; 0K:350.125±0.009 kcal/mol, corr to 298K from Gurvich, Veyts, et al., With EA( Breyer, Frey, et al., 1981)BDE(0K)=89.97±0.05

(S2- bullet 4294967295sulfur) + sulfur = S2-

By formula: (S2- bullet 4294967295S) + S = S2-

Quantity Value Units Method Reference Comment
Deltar92.7 ± 5.2kcal/molN/AMoran and Ellison, 1988gas phase

(S3- bullet 4294967295sulfur) + sulfur = S3-

By formula: (S3- bullet 4294967295S) + S = S3-

Quantity Value Units Method Reference Comment
Deltar72.2 ± 5.3kcal/molN/ANimlos and Ellison, 1986gas phase


Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Polak, Gilles, et al., 1992
Polak, M.L.; Gilles, M.K.; Lineberger, W.C., Photoelectron Spectroscopy of SF-, J. Chem. Phys., 1992, 96, 9, 7191, https://doi.org/10.1063/1.462526 . [all data]

Chaibi, Delsart, et al., 2006
Chaibi, W.; Delsart, C.; Drag, C.; Blondel, C., High precision measurement of the (SH)-S-32 electron affinity by laser detachment microscopy, J. Molec. Spectros., 2006, 239, 1, 11-15, https://doi.org/10.1016/j.jms.2006.05.012 . [all data]

Breyer, Frey, et al., 1981
Breyer, F.; Frey, P.; Hotop, H., High Resolution Photoelectron Spectrometry of Negative Ions: Rotational Transitions in Laser-Photodetachment of OH-, SH-, and SD-, Z. Phys. A, 1981, 300, 1, 7, https://doi.org/10.1007/BF01412609 . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Shiell, Hu, et al., 1900
Shiell, R.C.; Hu, X.K.; Hu, Q.J.; Hepburn, J.W., A determination of the bond dissociation energy (D-0(H-SH)): Threshold ion-pair production spectroscopy (TIPPS) of a triatomic molecule, J. Phys. Chem. A, 1900, 104, 19, 4339-4342, https://doi.org/10.1021/jp000025k . [all data]

Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]

Moran and Ellison, 1988
Moran, S.; Ellison, G.B., Photoelectron Spectroscopy of Sulfur Ions, J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021 . [all data]

Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B., Photoelectron spectroscopy of SO2-, S3-, and S2O-, J. Phys. Chem., 1986, 90, 2574. [all data]


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