Triphenylmethyl chloride

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid43.7kcal/molCcbSchmidlin, 1906ALS
Quantity Value Units Method Reference Comment
Δcsolid-2348.5kcal/molCcbSchmidlin, 1906ALS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
87.780298.15Naoki, Seki, et al., 1991T = 232 to 411 K. Cp value calculated from equation. Cp(c) = -3980 + 55.15T - 0.2726T2 + 6.07x10-4T3 - 5.0x10-7T4 J/mol*K (232.8 to 359.0 K).; DH
74.50298.5Smith and Andrews, 1931T = 102 to 346 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schmidlin, 1906
Schmidlin, M.J., Recherches chimiques et thermochimiques sur la constitution des rosanilines, Ann. Chim. Phys., 1906, 1, 195-256. [all data]

Naoki, Seki, et al., 1991
Naoki, M.; Seki, M.; Kugo, H.; Saito, F.; Taioka, T., Dielectric relaxation in supercooled triphenylchloromethane and intrinsic factor determining mobility in molecular liquids, J. Phys. Chem., 1991, 95(14), 5628-5633. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. I. Phenyl derivatives of methane, ethane and some related compounds. J. Am. Chem. Soc., 1931, 53, 3644-3660. [all data]


Notes

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