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Phosphorus pentafluoride


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   D3h     Symmetry Number sigma = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1' 1 PF3 s-str 816  B 816 p gas
a1' 2 PF2 s-str 648  C 648 p gas
a2 3 PF2 a-str 947  B 946.6 VS gas
a2 4 PF3 op-deform 575  B 575.1 M gas
e' 5 PF3 d-str 1024  B 1024 VS gas 1029 gas
e' 6 PF3 d-deform 533  B 532.5 M gas 535 dp gas
e' 7 PF bend 174  C 174 dp gas
e 8 PF bend 520  C 520 dp gas

Source: Shimanouchi, 1972

Notes

VSVery strong
MMedium
pPolarized
dpDepolarized
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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