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sodium chloride

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

4sodium + Ethene, chlorotrifluoro- = 2carbon + sodium chloride + 3sodium fluoride

By formula: 4Na + C2ClF3 = 2C + ClNa + 3FNa

Quantity Value Units Method Reference Comment
Deltar-1576.1 ± 5.4kJ/molCmKolesov, Zenkov, et al., 1963gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -1543. ± 5.4 kJ/mol; ALS

Sodium ion (1+) + sodium chloride = (Sodium ion (1+) bullet sodium chloride)

By formula: Na+ + ClNa = (Na+ bullet ClNa)

Quantity Value Units Method Reference Comment
Deltar177.kJ/molMSChupka, 1959gas phase; Knudsen cell; M
Quantity Value Units Method Reference Comment
Deltar73.6J/mol*KMSChupka, 1959gas phase; Knudsen cell; M

3Sodium hydroxide + Carbonochloridic acid, ethyl ester = CNa2O3 + Ethanol + sodium chloride + Water

By formula: 3HNaO + C3H5ClO2 = CNa2O3 + C2H6O + ClNa + H2O

Quantity Value Units Method Reference Comment
Deltar-323.3 ± 1.7kJ/molCmDavies, Finch, et al., 1980liquid phase; Heat of hydrolysis; ALS

2Sodium hydroxide + Cyanogen chloride = sodium chloride + Water + CNO.Na

By formula: 2HNaO + CClN = ClNa + H2O + CNO.Na

Quantity Value Units Method Reference Comment
Deltar-277.5 ± 0.4kJ/molCmLord and Woolf, 1954solid phase; Heat of Hydrolysis; ALS

C6H5NaO (cr) + (Hydrogen chloride bullet 552Water) (solution) = Phenol (cr) + sodium chloride (cr)

By formula: C6H5NaO (cr) + (HCl bullet 552H2O) (solution) = C6H6O (cr) + ClNa (cr)

Quantity Value Units Method Reference Comment
Deltar-78.0 ± 5.7kJ/molRSCLeal, Pires de Matos, et al., 1991MS

sodium methanolate (cr) + (Hydrogen chloride bullet 552Water) (solution) = Methyl Alcohol (l) + sodium chloride (cr)

By formula: CH3NaO (cr) + (HCl bullet 552H2O) (solution) = CH4O (l) + ClNa (cr)

Quantity Value Units Method Reference Comment
Deltar-108.0 ± 3.1kJ/molRSCLeal, Pires de Matos, et al., 1991MS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M., Standard enthalpy of formation of chlorotrifluoroethylene, Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 115-116. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Chupka, 1959
Chupka, W.A., Dissociation Energies of Some Gaseous Halide Complex Ions and the Hydrated Ion K(H2O)+, J. Chem. Phys., 1959, 40, 2, 458, https://doi.org/10.1063/1.1729974 . [all data]

Davies, Finch, et al., 1980
Davies, R.H.; Finch, A.; Gardner, P.J., The standard enthalpy of formation of liquid and gaseous ethylchloroformate (C3H5O2Cl), J. Chem. Thermodyn., 1980, 12, 291-296. [all data]

Lord and Woolf, 1954
Lord, G.; Woolf, A.A., The cyanogen halides. Part III. Their heats of formation and free energies, J. Chem. Soc., 1954, 2546-2551. [all data]

Leal, Pires de Matos, et al., 1991
Leal, J.P.; Pires de Matos, A.; Martinho Simões, J.A., J. Organometal. Chem., 1991, 403, 1. [all data]


Notes

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