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Tin(IV) chloride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)11.7 ± 0.2eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
2.500 ± 0.050LPESWang, Chi, et al., 2010Reverse Coulombic barrier estimated as 1.4±0.1 eV; B
2.40 ± 0.10LPESIoffe, Avdoshenko, et al., 2005Vertical Detachment Energy: 2.6±0.1 eV; B
2.20 ± 0.20NBIELacmann, Maneira, et al., 1983B
2.49 ± 0.15NBIEMathur, Rothe, et al., 1979B
2.91329N/ACheck, Faust, et al., 2001NiF3-; ; «DELTA»S(EA)=2.6; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.5PEBancroft, Pellach, et al., 1982LBLHLM
11.88 ± 0.05PEBassett and Lloyd, 1971LLK
11.5 ± 0.4EIBuchanan, Knowles, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
SnCl+12.5 ± 1.0?EIBuchanan, Knowles, et al., 1969RDSH
SnCl2+13.6 ± 1.0?EIBuchanan, Knowles, et al., 1969RDSH
SnCl3+12.2 ± 0.4ClEIBuchanan, Knowles, et al., 1969RDSH
Sn+22.2 ± 1.0?EIBuchanan, Knowles, et al., 1969RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Chi, et al., 2010
Wang, X.B.; Chi, C.X.; Zhou, M.F.; Kuvychko, I.V.; Seppelt, K.; Popov, A.A.; Strauss, S.H.; Boltalina, O.V.; Wang, L.S., Photoelectron Spectroscopy of C60Fn- and C60Fm2- (n=17, 33, 35, 43, 45, 47; m=34, 46) in the Gas Phase and the Generation and Characterization of C-1-C60F47- and D-2-C60F44 in Solution, J. Phys. Chem. A, 2010, 114, 4, 1756-1765, https://doi.org/10.1021/jp9097364 . [all data]

Ioffe, Avdoshenko, et al., 2005
Ioffe, I.N.; Avdoshenko, S.M.; Boltalina, O.V.; Sidorov, L.N.; Berndt, K.; Weber, J.M., Mass spectrometry, photoelectron spectroscopy, and quantum chemical studies of fluorofullerene dianions, Int. J. Mass Spectrom., 2005, 243, 3, 223-230, https://doi.org/10.1016/j.ijms.2005.03.005 . [all data]

Lacmann, Maneira, et al., 1983
Lacmann, K.; Maneira, M.J.P.; Moutinho, A.M.C.; Weigman, U., Total and Double Differential Cross Sections of Ion- Pair Formations in Collisions of K Atoms with SnCl4 and CCl4, J. Chem. Phys., 1983, 78, 1767. [all data]

Mathur, Rothe, et al., 1979
Mathur, E.P.; Rothe, E.W.; Reck, G.P., Negative ions from the reactions of alkalis with SnCl4, GeCl4, and TiCl4, Int. J. Mass Spectrom. Ion Phys., 1979, 31, 77. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Bancroft, Pellach, et al., 1982
Bancroft, G.M.; Pellach, E.; Tse, J.S., High resolution HeI and HeII photoelectron spectra of TiCl4, SnCl4, and (CH3)4Sn, Inorg. Chem., 1982, 21, 2950. [all data]

Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R., Photoelectron spectra of halides. Part I. Tetrafluorides and tetrachlorides of group IVB, J. Chem. Soc., 1971, (A), 641. [all data]

Buchanan, Knowles, et al., 1969
Buchanan, A.S.; Knowles, D.J.; Swingler, D.L., Electron impact studies of stannous chloride and stannic chloride, J. Phys. Chem., 1969, 73, 4394. [all data]


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