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4-Octene, (Z)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil395.7KN/AWeast and Grasselli, 1989BS
Tboil395.82KN/AKuus, Kudryavtseva, et al., 1980Uncertainty assigned by TRC = 0.2 K; from Int. Dtra Ser., 1980 (2), 123; TRC
Tboil395.67KN/AHoff, Greenlee, et al., 1951Uncertainty assigned by TRC = 0.5 K; TRC
Tboil395.69KN/AHoff, Greenlee, et al., 1951Uncertainty assigned by TRC = 0.3 K; TRC
Tboil393.4KN/AYoung, Jasaitis, et al., 1937Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Tfus153.83KN/AHoff, Greenlee, et al., 1951Uncertainty assigned by TRC = 1. K; TRC
Tfus154.13KN/AHoff, Greenlee, et al., 1951Uncertainty assigned by TRC = 0.5 K; TRC
Tfus154.45KN/AHoff, Greenlee, et al., 1951Uncertainty assigned by TRC = 0.2 K; TRC
Tfus155.KN/ACampbell and Eby, 1941Uncertainty assigned by TRC = 2. K; TRC
Tfus155.15KN/ACampbell and Eby, 1941, 2Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap39.7kJ/molN/AReid, 1972AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
37.2368.AStephenson and Malanowski, 1987Based on data from 353. - 395. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + 4-Octene, (Z)- = Octane

By formula: H2 + C8H16 = C8H18

Quantity Value Units Method Reference Comment
Deltar-118.2 ± 0.4kJ/molChydRogers, Dejroongruang, et al., 1992liquid phase; solvent: Cyclohexane
Deltar-119.7 ± 2.2kJ/molChydRogers and Siddiqui, 1975liquid phase; solvent: n-Hexane
Deltar-114.6 ± 0.59kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid

Octane = Hydrogen + 4-Octene, (Z)-

By formula: C8H18 = H2 + C8H16

Quantity Value Units Method Reference Comment
Deltar118.24kJ/molEqkEliseev, 1986liquid phase

IR Spectrum

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-3496
NIST MS number 227615

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References

Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kuus, Kudryavtseva, et al., 1980
Kuus, M.; Kudryavtseva, L.S.; Eisen, O.G., Eesti NSV Tead. Akad. Toim., Keem., 1980, 29, 25. [all data]

Hoff, Greenlee, et al., 1951
Hoff, M.C.; Greenlee, K.W.; Boord, C.E., The Quantitavitve Inversion of cis- and trans-Alkene Isomers: A New Synthesis of Normal cis-Alkenes, J. Am. Chem. Soc., 1951, 73, 3329-36. [all data]

Young, Jasaitis, et al., 1937
Young, W.G.; Jasaitis, Z.; Levanas, L., J. Am. Chem. Soc., 1937, 59, 403. [all data]

Campbell and Eby, 1941
Campbell, K.N.; Eby, L.T., The preparation of higher cis and trans olefins, J. Am. Chem. Soc., 1941, 63, 216. [all data]

Campbell and Eby, 1941, 2
Campbell, K.N.; Eby, L.T., The Reduction of Multiple Carbon-Carbon Bonds III. Further Studies on the Preparation of Olefins from Acetylenes, J. Am. Chem. Soc., 1941, 63, 2683. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Rogers, Dejroongruang, et al., 1992
Rogers, D.W.; Dejroongruang, K.; Samuel, S.D.; Fang, W.; Zhao, Y., Enthalpies of hydrogenation of the octenes and the methylheptenes, J. Chem. Thermodyn., 1992, 24, 561-565. [all data]

Rogers and Siddiqui, 1975
Rogers, D.W.; Siddiqui, N.A., Heats of hydrogenation of large molecules. I. Esters of unsaturated fatty acids, J. Phys. Chem., 1975, 79, 574-577. [all data]

Turner, Jarrett, et al., 1973
Turner, R.B.; Jarrett, A.D.; Goebel, P.; Mallon, B.J., Heats of hydrogenation. 9. Cyclic acetylenes and some miscellaneous olefins, J. Am. Chem. Soc., 1973, 95, 790-792. [all data]

Eliseev, 1986
Eliseev, N.A., Thermodynamic calculation of the equilibrium composition of isomeric octenes in dehydrogenation of n-octane, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1986, 29, 26-29. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References