3-Hexene, (Z)-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeSqualaneSqualaneSqualaneOV-101
Column length (m) 150.93.   
Carrier gas HeHe   
Substrate      
Column diameter (mm) 0.2500.250   
Phase thickness (μm)      
Temperature (C) 30.30.100.25.40.
I 602.2592.1593.593.602.
ReferenceSoják, Addová, et al., 2002Soják, Addová, et al., 2002Heinzen, Soares, et al., 1999Hilal, Carreira, et al., 1994Laub and Purnell, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101Squalane
Column length (m)   100.100.100.
Carrier gas   N2N2N2
Substrate      
Column diameter (mm)   0.270.270.25
Phase thickness (μm)   0.90.9 
Temperature (C) 60.80.50.70.50.
I 603.603.602.4602.7592.8
ReferenceLaub and Purnell, 1988Laub and Purnell, 1988Boneva and Dimov, 1986Boneva and Dimov, 1986Boneva and Dimov, 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneDB-1HP-PONAOV-101OV-101
Column length (m) 100.60.50.  
Carrier gas N2H2H2  
Substrate      
Column diameter (mm) 0.250.2640.21  
Phase thickness (μm)  0.250.5  
Temperature (C) 70.40.40.30.40.
I 593.1603.603.602.602.
ReferenceBoneva and Dimov, 1986Lubeck and Sutton, 1984Lubeck and Sutton, 1984Chien, Furio, et al., 1983Chien, Furio, et al., 1983
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101OV-3
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 50.60.70.80.30.
I 602.603.603.603.607.9
ReferenceChien, Furio, et al., 1983Chien, Furio, et al., 1983Chien, Furio, et al., 1983Chien, Furio, et al., 1983Chien, Furio, et al., 1983, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-3OV-3OV-3OV-3OV-3
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 40.50.60.70.80.
I 607.9607.9607.9607.9607.9
ReferenceChien, Furio, et al., 1983, 2Chien, Furio, et al., 1983, 2Chien, Furio, et al., 1983, 2Chien, Furio, et al., 1983, 2Chien, Furio, et al., 1983, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-1OV-1OV-1OV-1
Column length (m)      
Carrier gas H2H2H2H2H2
Substrate      
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 30.40.50.60.70.
I 602.3602.9603.5604.2604.9
ReferenceChien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1SE-30SE-30SE-30SE-30
Column length (m)      
Carrier gas H2H2H2H2H2
Substrate      
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 80.30.40.50.60.
I 605.6604.8604.5603.6602.9
ReferenceChien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedCapillaryCapillary
Active phase SE-30SE-30SqualaneSqualaneSqualane
Column length (m)     120.
Carrier gas H2H2  He
Substrate      
Column diameter (mm)     0.25
Phase thickness (μm)      
Temperature (C) 70.80.80.50.100.
I 602.2601.4593.593.592.2
ReferenceChien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chrétien and Dubois, 1977Chretien and Dubois, 1976Lulova, Leont'eva, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 100.100.100.  
Carrier gas N2N2   
Substrate      
Column diameter (mm) 0.250.250.25  
Phase thickness (μm)      
Temperature (C) 50.70.27.100.115.
I 593.593.591.50593.594.
ReferenceRijks and Cramers, 1974Rijks and Cramers, 1974Schomburg and Dielmann, 1973Sojak, Hrivnak, et al., 1973Sojak, Hrivnak, et al., 1973
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneApiezon LSqualaneSqualaneSqualane
Column length (m)  45.80.80.200.
Carrier gas     N2
Substrate      
Column diameter (mm)  0.250.250.250.2
Phase thickness (μm)      
Temperature (C) 86.100.50.60.115.
I 593.595.8592.7593.593.7
ReferenceSojak, Hrivnak, et al., 1973Eisen, Orav, et al., 1972Eisen, Orav, et al., 1972Orav and Eisen, 1972Soják and Bucinská, 1970
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedPackedPacked
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 200.91.415.15.15.
Carrier gas N2N2HeHeHe
Substrate   Chromosorb PChromosorb PChromosorb P
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm)      
Temperature (C) 86.40.27.49.67.
I 593.0593.592.593.594.
ReferenceSoják and Bucinská, 1970Matukuma, 1969Hively and Hinton, 1968Hively and Hinton, 1968Hively and Hinton, 1968
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedCapillaryPacked
Active phase SqualaneSqualaneSqualane
Column length (m) 15.100.10.
Carrier gas HeAr 
Substrate Chromosorb P  
Column diameter (mm) 0.25  
Phase thickness (μm)    
Temperature (C) 86.70.26.
I 594.593.593.
ReferenceHively and Hinton, 1968Schomburg, 1967Zulaïca and Guiochon, 1966
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Soják, Addová, et al., 2002
Soják, L.; Addová, G.; Kubinec, R.; Kraus, A.; Hu, G., Gas chromatographic-mass spectrometric characterization of all acyclic C5-C7 alkenes from fluid catalytic cracked gasoline using polydimethylsiloxane and squalane stationary phases, J. Chromatogr. A, 2002, 947, 1, 103-117, https://doi.org/10.1016/S0021-9673(01)01564-3 . [all data]

Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A., Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes, J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0 . [all data]

Hilal, Carreira, et al., 1994
Hilal, S.H.; Carreira, L.A.; Karickhoff, S.W.; Melton, C.M., Estimation of Gas-Liquid Chromatographic Retention Times from Molecular Structure, J. Chromatogr. A, 1994, 662, 2, 269-280, https://doi.org/10.1016/0021-9673(94)80515-6 . [all data]

Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H., Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1988, 11, 9, 649-660, https://doi.org/10.1002/jhrc.1240110908 . [all data]

Boneva and Dimov, 1986
Boneva, S.; Dimov, N., Gas Chromatographic Retention Indices for Alkenes on OV-101 and Squalane Capillary Columns, Chromatographia, 1986, 21, 3, 149-151, https://doi.org/10.1007/BF02311743 . [all data]

Lubeck and Sutton, 1984
Lubeck, A.J.; Sutton, D.L., Kovats Retention Indices of Selected Olefins on Bonded Phase Fused Silica Capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1984, 7, 9, 542-544, https://doi.org/10.1002/jhrc.1240070913 . [all data]

Chien, Furio, et al., 1983
Chien, C.-F.; Furio, D.L.; Kopecni, M.M.; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-101 and SP-2100 Polydimethylsiloxane Solvents, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 10, 577-580, https://doi.org/10.1002/jhrc.1240061013 . [all data]

Chien, Furio, et al., 1983, 2
Chien, C.-F.; Furio, D.L.; Kopecni, M.M.; Laub, R.J., Specific retention volumes and retention indices of selected hydrocarbon solutes with OV-3, OV-7, OV-11, OV-17, OV-22, and OV-25 polymethylphenylsiloxane solvents, J. Hi. Res. Chromatogr., 1983, 6, 12, 669-679, https://doi.org/10.1002/jhrc.1240061207 . [all data]

Chien, Kopecni, et al., 1981
Chien, C.-F.; Kopecni, M.M.; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-1 and SE-30 Polydimethylsiloxane Solvents, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1981, 4, 10, 539-543, https://doi.org/10.1002/jhrc.1240041017 . [all data]

Chrétien and Dubois, 1977
Chrétien, J.R.; Dubois, J.E., Topological analysis of gas-liquid chromatographic behavior of alkenes, Anal. Chem., 1977, 49, 6, 747-756, https://doi.org/10.1021/ac50014a021 . [all data]

Chretien and Dubois, 1976
Chretien, J.R.; Dubois, J.-E., New Perspectives in the Prediction of Kovats Indices, J. Chromatogr., 1976, 126, 171-189, https://doi.org/10.1016/S0021-9673(01)84071-1 . [all data]

Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N., Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]

Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819 . [all data]

Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G., Identification by means of retention parameters, J. Chromatogr. Sci., 1973, 11, 3, 151-159, https://doi.org/10.1093/chromsci/11.3.151 . [all data]

Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J., Capillary Gas Chromatography of Linear Alkenes on Squalane, Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039 . [all data]

Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S., Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire, Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600 . [all data]

Orav and Eisen, 1972
Orav, A.; Eisen, O., The retention indexes for alkenes, alkynes and cyclenes on capillary columns, Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]

Soják and Bucinská, 1970
Soják, L.; Bucinská, A., Open tubular column gas chromatography of dehydrogenation products of C6-C10 n-alkanes. Separation and identification of mixtures of C6-C10 straight-chain alkanes, alkenes and aromatics, J. Chromatogr., 1970, 51, 75-82, https://doi.org/10.1016/S0021-9673(01)96841-4 . [all data]

Matukuma, 1969
Matukuma, A., Retention indices of alkanes through C10 and alkenes through C8 and relation between boiling points and retention data, Gas Chromatogr., Int. Symp. Anal. Instrum. Div Instrum Soc. Amer., 1969, 7, 55-75. [all data]

Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E., Variation of the retention index with temperature on squalane substrates, J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203 . [all data]

Schomburg, 1967
Schomburg, G., Struktur und Retentionsverhalten von Offenkettigen und Cyclischen Kohlenwasserstoffen und Deren Einfacher Substitutionsprodukte, Anal. Chim. Acta., 1967, 38, 45-64, https://doi.org/10.1016/S0003-2670(01)80560-2 . [all data]

Zulaïca and Guiochon, 1966
Zulaïca, J.; Guiochon, G., Analyse des hauts polymères par chromatographie en phase gazeuse de leurs produits de pyrolyse. II. Application à quelques hydrocarbures macromoléculaires purs, Bull. Soc. Chim. Fr., 1966, 4, 1351-1363. [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References