2-Octene, (Z)-
- Formula: C8H16
- Molecular weight: 112.2126
- IUPAC Standard InChIKey: ILPBINAXDRFYPL-HYXAFXHYSA-N
- CAS Registry Number: 7642-04-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (Z)-2-Octene; cis-2-Octene; 2-Octene, cis-; (Z)-2-C8H16; cis-Octene-2; (2Z)-2-Octene; (Z)-Oct-2-ene
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Petrocol DH | Squalane | Squalane | BP-1 | OV-101 |
Column length (m) | 150. | 93. | 15. | ||
Carrier gas | H2 | He | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.53 | ||
Phase thickness (μm) | 1. | 1.0 | |||
Temperature (C) | 30. | 30. | 100. | 0. | 40. |
I | 811.2 | 800.4 | 803. | 804. | 812. |
Reference | Soják, Addová, et al., 2004 | Soják, Addová, et al., 2004 | Heinzen, Soares, et al., 1999 | Skrbic and Cvejanov, 1992 | Laub and Purnell, 1988 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | OV-101 | DB-1 | HP-PONA |
Column length (m) | 50. | 60. | 50. | ||
Carrier gas | He | H2 | H2 | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.264 | 0.21 | ||
Phase thickness (μm) | 0.25 | 0.5 | |||
Temperature (C) | 60. | 80. | 110. | 40. | 40. |
I | 812. | 812. | 813. | 811. | 811. |
Reference | Laub and Purnell, 1988 | Laub and Purnell, 1988 | Rang, Kuningas, et al., 1987 | Lubeck and Sutton, 1984 | Lubeck and Sutton, 1984 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-1 | Squalane | Squalane | Squalane | Squalane |
Column length (m) | 150. | 120. | 120. | 100. | |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.50 | 0.25 | 0.25 | 0.25 | |
Phase thickness (μm) | |||||
Temperature (C) | 60. | 80. | 100. | 55. | 80. |
I | 811. | 802. | 800.8 | 800.8 | 803.3 |
Reference | Nijs and Jacobs, 1981 | Chrétien and Dubois, 1977 | Lulova, Leont'eva, et al., 1976 | Lulova, Leont'eva, et al., 1975 | Schomburg and Dielmann, 1973 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Apiezon L | Squalane |
Column length (m) | 45. | 80. | |||
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | |||
Phase thickness (μm) | |||||
Temperature (C) | 100. | 115. | 86. | 100. | 80. |
I | 803. | 804. | 803. | 811.4 | 802.4 |
Reference | Sojak, Hrivnak, et al., 1973 | Sojak, Hrivnak, et al., 1973 | Sojak, Hrivnak, et al., 1973 | Eisen, Orav, et al., 1972 | Eisen, Orav, et al., 1972 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Squalane |
Column length (m) | 80. | 200. | 200. | 91.4 |
Carrier gas | N2 | N2 | N2 | |
Substrate | ||||
Column diameter (mm) | 0.25 | 0.2 | 0.2 | 0.25 |
Phase thickness (μm) | ||||
Temperature (C) | 80. | 115. | 86. | 40. |
I | 802. | 803.6 | 802.8 | 802. |
Reference | Orav and Eisen, 1972 | Soják and Bucinská, 1970 | Soják and Bucinská, 1970 | Matukuma, 1969 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Soják, Addová, et al., 2004
Soják, L.; Addová, G.; Kubinec, R.; Kraus, A.; Bohác, A.,
Capillary gas chromatography-mass spectrometry of all 93 acyclic octenes and their identification in fluid catalytic cracked gasoline,
J. Chromatogr. A, 2004, 1025, 2, 237-253, https://doi.org/10.1016/j.chroma.2003.10.112
. [all data]
Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A.,
Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes,
J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0
. [all data]
Skrbic and Cvejanov, 1992
Skrbic, B.D.; Cvejanov, J.Dj.,
Unified retention indices of hydrocarbons on BP-1 dimethylsiloxane stationary phase,
Chromatographia, 1992, 34, 1/2, 83-84, https://doi.org/10.1007/BF02290465
. [all data]
Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H.,
Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1988, 11, 9, 649-660, https://doi.org/10.1002/jhrc.1240110908
. [all data]
Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O.,
Retention and Thermodynamics of Solution of n-Alkenes in OV-101,
J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4
. [all data]
Lubeck and Sutton, 1984
Lubeck, A.J.; Sutton, D.L.,
Kovats Retention Indices of Selected Olefins on Bonded Phase Fused Silica Capillaries,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1984, 7, 9, 542-544, https://doi.org/10.1002/jhrc.1240070913
. [all data]
Nijs and Jacobs, 1981
Nijs, H.H.; Jacobs, P.A.,
On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor,
J. Chromatogr. Sci., 1981, 19, 1, 40-45, https://doi.org/10.1093/chromsci/19.1.40
. [all data]
Chrétien and Dubois, 1977
Chrétien, J.R.; Dubois, J.E.,
Topological analysis of gas-liquid chromatographic behavior of alkenes,
Anal. Chem., 1977, 49, 6, 747-756, https://doi.org/10.1021/ac50014a021
. [all data]
Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N.,
Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines
in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]
Lulova, Leont'eva, et al., 1975
Lulova, N.I.; Leont'eva, S.A.; Fedosova, A.K.; Kvasova, V.A.,
Individual composition of hydrocarbons in naphthas from secondary processes,
Chem. Technol. Fuels Oils (Engl. Transl.), 1975, 11, 1/2, 59-64, https://doi.org/10.1007/BF00717315
. [all data]
Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G.,
Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats indices,
Anal. Chem., 1973, 45, 9, 1647-1658, https://doi.org/10.1021/ac60331a021
. [all data]
Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J.,
Capillary Gas Chromatography of Linear Alkenes on Squalane,
Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039
. [all data]
Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S.,
Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire,
Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600
. [all data]
Orav and Eisen, 1972
Orav, A.; Eisen, O.,
The retention indexes for alkenes, alkynes and cyclenes on capillary columns,
Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]
Soják and Bucinská, 1970
Soják, L.; Bucinská, A.,
Open tubular column gas chromatography of dehydrogenation products of C6-C10 n-alkanes. Separation and identification of mixtures of C6-C10 straight-chain alkanes, alkenes and aromatics,
J. Chromatogr., 1970, 51, 75-82, https://doi.org/10.1016/S0021-9673(01)96841-4
. [all data]
Matukuma, 1969
Matukuma, A.,
Retention indices of alkanes through C10 and alkenes through C8 and relation between boiling points and retention data,
Gas Chromatogr., Int. Symp. Anal. Instrum. Div Instrum Soc. Amer., 1969, 7, 55-75. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
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