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Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Trifluoroacetic acid + 3-Hexene, (Z)- = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C2HF3O2 + C6H12 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-44.79 ± 0.13kJ/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis

Trifluoroacetic acid + 2-Hexene, (Z)- = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C2HF3O2 + C6H12 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-42.76 ± 0.13kJ/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis

3-Hexene, (E)- + Trifluoroacetic acid = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-40.90 ± 0.13kJ/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis

2-Hexene, (E)- + Trifluoroacetic acid = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-39.71 ± 0.13kJ/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis

1-Hexene + Trifluoroacetic acid = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-50.5 ± 0.1kJ/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis

Hexan-3-yl trifluoroacetate = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C8H13F3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar0.720 ± 0.088kJ/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis

Acetic acid, trifluoro-, anhydride + 2-Hexanol = Trifluoroacetic acid + Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C4F6O3 + C6H14O = C2HF3O2 + C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-89.33 ± 0.04kJ/molCmWiberg and Wasserman, 1981liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Wasserman, 1981
Wiberg, K.B.; Wasserman, D.J., Enthalpies of hydration of alkenes. 1. The n-hexenes, J. Am. Chem. Soc., 1981, 103, 6563-6566. [all data]


Notes

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