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Trifluoroacetic acid

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-243.2 ± 1.1kcal/molEqkGuthrie, 1976 
Deltafgas-246.52 ± 0.41kcal/molCcrKolesov, Slavutskaya, et al., 1972Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -244.2 ± 0.4 kcal/mol; see Kolesov and Zenkov, 1966

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-255.72 ± 0.36kcal/molCcrKolesov, Slavutskaya, et al., 1972Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -253.4 ± 0.4 kcal/mol; see Kolesov and Zenkov, 1966
Quantity Value Units Method Reference Comment
Deltacliquid-94.93 ± 0.35kcal/molCcrKolesov, Slavutskaya, et al., 1972see Kolesov and Zenkov, 1966

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil347.KN/AFarchan Laboratories, 1990BS
Tboil347.KN/APCR Inc., 1990BS
Tboil345.6KN/AWeast and Grasselli, 1989BS
Tboil345.1KN/AMalijevska, Sysova, et al., 1986Uncertainty assigned by TRC = 0.2 K; TRC
Tboil345.7KN/AParnes, Khotimskaya, et al., 1969Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tfus531.17KN/AKohler, Atrops, et al., 1981Uncertainty assigned by TRC = 0.2 K; TRC
Tfus288.43KN/AParnes, Khotimskaya, et al., 1969Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap9.8 ± 0.7kcal/molEGuthrie, 1976ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
8.58300.AStephenson and Malanowski, 1987Based on data from 285. - 345. K. See also Kreglewski, 1962, Dykyj, 1970, and Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
285. - 344.803.339631267.252-52.958Kreglewski, 1962, 2Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H2F3O2+ + Trifluoroacetic acid = (C2H2F3O2+ bullet Trifluoroacetic acid)

By formula: C2H2F3O2+ + C2HF3O2 = (C2H2F3O2+ bullet C2HF3O2)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar29.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar28.5cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar20.8kcal/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

CF3CO2 anion + Hydrogen cation = Trifluoroacetic acid

By formula: C2F3O2- + H+ = C2HF3O2

Quantity Value Units Method Reference Comment
Deltar323.8 ± 2.9kcal/molG+TSCaldwell, Renneboog, et al., 1989gas phase; B
Deltar322.8 ± 2.9kcal/molG+TSJinfeng, Topsom, et al., 1988gas phase; value altered from reference due to change in acidity scale; B
Deltar322.8 ± 4.1kcal/molG+TSCumming and Kebarle, 1978gas phase; B
Quantity Value Units Method Reference Comment
Deltar317.4 ± 2.0kcal/molIMRECaldwell, Renneboog, et al., 1989gas phase; B
Deltar316.4 ± 2.0kcal/molIMREJinfeng, Topsom, et al., 1988gas phase; value altered from reference due to change in acidity scale; B
Deltar316.3 ± 2.0kcal/molIMRECumming and Kebarle, 1978gas phase; B

Acetic acid, trifluoro-, anhydride + Cyclopentanol = Trifluoroacetic acid, cyclopentyl ester + Trifluoroacetic acid

By formula: C4F6O3 + C5H10O = C7H9F3O2 + C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-22.219 ± 0.056kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; solvent: Trifluoroactic acid; Trifluoroacetolysis; ALS

2-Norbornene + Trifluoroacetic acid = exo-Norborneol, trifluoroacetate

By formula: C7H10 + C2HF3O2 = C9H11F3O2

Quantity Value Units Method Reference Comment
Deltar-15.333 ± 0.055kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; solvent: Trifluoroacetic acid; Trifluoroacetolysis; ALS

Cyclohexane, methylene- + Trifluoroacetic acid = Acetic acid, trifluoro-, 1-methyl cyclohexyl ester

By formula: C7H12 + C2HF3O2 = C9H13F3O3

Quantity Value Units Method Reference Comment
Deltar-10.710 ± 0.024kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; solvent: Trifluoroacetic acid; Trifluoroacetolysis; ALS

Cyclohexene + Trifluoroacetic acid = Acetic acid, trifluoro-, cyclohexyl ester

By formula: C6H10 + C2HF3O2 = C8H11F3O2

Quantity Value Units Method Reference Comment
Deltar-10.36 ± 0.03kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; solvent: Trifluoroacetic acid; Triflouroacetolysis; ALS

Cyclopentene + Trifluoroacetic acid = Trifluoroacetic acid, cyclopentyl ester

By formula: C5H8 + C2HF3O2 = C7H9F3O2

Quantity Value Units Method Reference Comment
Deltar-9.167 ± 0.044kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; solvent: Trifluoroacetic acid; Trifluoroacetolysis; ALS

Cyclohexene, 1-methyl- + Trifluoroacetic acid = Acetic acid, trifluoro-, 1-methyl cyclohexyl ester

By formula: C7H12 + C2HF3O2 = C9H13F3O3

Quantity Value Units Method Reference Comment
Deltar-8.74 ± 0.21kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; solvent: Trifluoroacetic acid; Trifluoroacetolysis; ALS

C14H10F6MoO4 (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = C10H10Cl2Mo (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6MoO4 (cr) + 2(HCl bullet 4.40H2O) (solution) = C10H10Cl2Mo (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Deltar13.9 ± 0.60kcal/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.; MS

C14H10F6O4Ti (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = Titanocene dichloride (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6O4Ti (cr) + 2(HCl bullet 4.40H2O) (solution) = C10H10Cl2Ti (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Deltar9.03 ± 0.55kcal/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.; MS

C14H10F6O4W (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = C10H10Cl2W (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6O4W (cr) + 2(HCl bullet 4.40H2O) (solution) = C10H10Cl2W (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Deltar7.62 ± 0.45kcal/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.; MS

Acetic acid, trifluoro-, anhydride + exo-Norbornyl alcohol = exo-Norborneol, trifluoroacetate + Trifluoroacetic acid

By formula: C4F6O3 + C7H12O = C9H11F3O2 + C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-21.771 ± 0.034kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; Trifluoroacetolysis; ALS

Cyclohexanol + Acetic acid, trifluoro-, anhydride = Acetic acid, trifluoro-, cyclohexyl ester + Trifluoroacetic acid

By formula: C6H12O + C4F6O3 = C8H11F3O2 + C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-21.524 ± 0.037kcal/molCacWiberg, Wasserman, et al., 1985liquid phase; Trifluoroacetolysis; ALS

Acetic acid, trifluoro-, anhydride + Amylene hydrate = Acetic acid, trifluoro-, 2,2-dimethylpropyl ester + Trifluoroacetic acid

By formula: C4F6O3 + C5H12O = C7H11F3O2 + C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-21.16 ± 0.02kcal/molCmWiberg and Hao, 1991liquid phase; Trifuoroacetolysis; ALS

Trifluoroacetic acid + 3-Hexene, (Z)- = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C2HF3O2 + C6H12 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-10.704 ± 0.032kcal/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis; ALS

Trifluoroacetic acid + 2-Hexene, (Z)- = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C2HF3O2 + C6H12 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-10.220 ± 0.030kcal/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis; ALS

3-Hexene, (E)- + Trifluoroacetic acid = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-9.775 ± 0.031kcal/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis; ALS

2-Hexene, (E)- + Trifluoroacetic acid = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-9.492 ± 0.032kcal/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis; ALS

2-Pentene, 3-methyl-, (E)- + Trifluoroacetic acid = Acetic acid, trifluoro-, 1,2-dimethylbutyl ester, (R*,S*)-(+/-)-

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-8.79 ± 0.06kcal/molCmWiberg and Hao, 1991liquid phase; Trifluoroacetolysis; ALS

1-Hexene + Trifluoroacetic acid = Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C6H12 + C2HF3O2 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-12.07 ± 0.03kcal/molEqkWiberg and Wasserman, 1981liquid phase; Trifluoroacetolysis; ALS

2-Methyl-1-butene + Trifluoroacetic acid = Acetic acid, trifluoro-, 2,2-dimethylpropyl ester

By formula: C5H10 + C2HF3O2 = C7H11F3O2

Quantity Value Units Method Reference Comment
Deltar-10.93 ± 0.04kcal/molCmWiberg and Hao, 1991liquid phase; Trifuoroacetolysis; ALS

2-Butene, 2-methyl- + Trifluoroacetic acid = Acetic acid, trifluoro-, 2,2-dimethylpropyl ester

By formula: C5H10 + C2HF3O2 = C7H11F3O2

Quantity Value Units Method Reference Comment
Deltar-9.11 ± 0.04kcal/molCmWiberg and Hao, 1991liquid phase; Trifluoroacetolysis; ALS

Trifluoroacetic acid + 2-Pentene, 3-methyl-, (Z)- = Acetic acid, trifluoro-, 1,2-dimethylbutyl ester, (R*,S*)-(+/-)-

By formula: C2HF3O2 + C6H12 = C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-9.01 ± 0.02kcal/molCmWiberg and Hao, 1991liquid phase; Trifuoroacetolysis; ALS

C5H11BrMg (solution) + Trifluoroacetic acid (solution) = C2BrF3MgO2 (solution) + Pentane (solution)

By formula: C5H11BrMg (solution) + C2HF3O2 (solution) = C2BrF3MgO2 (solution) + C5H12 (solution)

Quantity Value Units Method Reference Comment
Deltar-65.39kcal/molRSCHolm, 1983solvent: Diethyl ether; MS

Acetic acid, trifluoro-, anhydride + 2-Hexanol = Trifluoroacetic acid + Acetic acid, 2,2,2-trifluoro-, 1-methylpentyl ester

By formula: C4F6O3 + C6H14O = C2HF3O2 + C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-21.35 ± 0.01kcal/molCmWiberg and Wasserman, 1981liquid phase; ALS

Acetic acid, trifluoro-, anhydride + 3-Hexanol = Trifluoroacetic acid + Hexan-3-yl trifluoroacetate

By formula: C4F6O3 + C6H14O = C2HF3O2 + C8H13F3O2

Quantity Value Units Method Reference Comment
Deltar-22.15 ± 0.01kcal/molCmWiberg and Wasserman, 1981liquid phase; ALS

Acetic acid, trifluoro-, anhydride + Water = 2Trifluoroacetic acid

By formula: C4F6O3 + H2O = 2C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-18.01 ± 0.01kcal/molCmWiberg and Wasserman, 1981liquid phase; ALS

Acetic acid, trifluoro-, anhydride + Nitric acid = C2F3NO4 + Trifluoroacetic acid

By formula: C4F6O3 + HNO3 = C2F3NO4 + C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-6.60kcal/molCmTsvetkov, Shmakov, et al., 1989liquid phase; ALS

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference
8900.9300.MN/A

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
IE (evaluated)11.5eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)170.1kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity162.7kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
11.6PEAsbrink, Svensson, et al., 1981LLK
11.46PESweigart and Turner, 1972LLK
12.0PEAsbrink, Svensson, et al., 1981Vertical value; LLK
12.06PECarnovale, Gan, et al., 1980Vertical value; LLK
12.08 ± 0.05PEColeman, Green, et al., 1979Vertical value; LLK
12.00PEWatanabe, Yokoyama, et al., 1973Vertical value; LLK
12.00 ± 0.03PEThomas, 1972Vertical value; LLK

De-protonation reactions

CF3CO2 anion + Hydrogen cation = Trifluoroacetic acid

By formula: C2F3O2- + H+ = C2HF3O2

Quantity Value Units Method Reference Comment
Deltar323.8 ± 2.9kcal/molG+TSCaldwell, Renneboog, et al., 1989gas phase; B
Deltar322.8 ± 2.9kcal/molG+TSJinfeng, Topsom, et al., 1988gas phase; value altered from reference due to change in acidity scale; B
Deltar322.8 ± 4.1kcal/molG+TSCumming and Kebarle, 1978gas phase; B
Quantity Value Units Method Reference Comment
Deltar317.4 ± 2.0kcal/molIMRECaldwell, Renneboog, et al., 1989gas phase; B
Deltar316.4 ± 2.0kcal/molIMREJinfeng, Topsom, et al., 1988gas phase; value altered from reference due to change in acidity scale; B
Deltar316.3 ± 2.0kcal/molIMRECumming and Kebarle, 1978gas phase; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H2F3O2+ + Trifluoroacetic acid = (C2H2F3O2+ bullet Trifluoroacetic acid)

By formula: C2H2F3O2+ + C2HF3O2 = (C2H2F3O2+ bullet C2HF3O2)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar29.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986
Quantity Value Units Method Reference Comment
Deltar28.5cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986
Quantity Value Units Method Reference Comment
Deltar20.8kcal/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
Source reference No.222236 (NIST/EPA/NIH MS Database)
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 1851

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guthrie, 1976
Guthrie, J.P., Thermodynamics of ester and orthoester formation from trifluoroacetic acid, Can. J. Chem., 1976, 54, 202-209. [all data]

Kolesov, Slavutskaya, et al., 1972
Kolesov, V.P.; Slavutskaya, G.M.; Papina, T.S., Standard enthalpies of formation of perfluorodi-n-butyl ether and trifluoroacetic acid, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 474. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Kolesov and Zenkov, 1966
Kolesov, V.P.; Zenkov, I.D., Standard of enthalpy of formation of trifluoroacetic acid, Russ. J. Phys. Chem. (Engl. Transl.), 1966, 40, 743-744. [all data]

Farchan Laboratories, 1990
Farchan Laboratories, Research Chemicals Catalog, Farchan Laboratories, Gainesville, FL, 1990, 91. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Malijevska, Sysova, et al., 1986
Malijevska, I.; Sysova, M.; Vlckova, D., Vapour-Liquid Equilibrium in Strongly Associated Systems. The Systems Acetic Acid-Propionic Acid and Acetic Acid-Trifluoroacetic Acid, Collect. Czech. Chem. Commun., 1986, 51, 194. [all data]

Parnes, Khotimskaya, et al., 1969
Parnes, Z.N.; Khotimskaya, G.A.; Kudryavtsev, R.V.; Lukina, M.Y.; Kursanov, D.N., The Behavior of Cyclopropane Hydrocarbons in Ionic Hydrogenation Reactions, Dokl. Akad. Nauk SSSR, Ser. Khim., 1969, 184, 615-8. [all data]

Kohler, Atrops, et al., 1981
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Notes

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