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Trichloroacetic Acid

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C14H10Cl6O4Ti (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = Titanocene dichloride (cr) + 2Trichloroacetic Acid (cr)

By formula: C14H10Cl6O4Ti (cr) + 2(HCl bullet 4.40H2O) (solution) = C10H10Cl2Ti (cr) + 2C2HCl3O2 (cr)

Quantity Value Units Method Reference Comment
Deltar13.4 ± 2.6kJ/molRSCDias, Salema, et al., 1984Please also see Calhorda, Carrondo, et al., 1986.; MS

Trichloroacetyl chloride + Water = Trichloroacetic Acid + Hydrogen chloride

By formula: C2Cl4O + H2O = C2HCl3O2 + HCl

Quantity Value Units Method Reference Comment
Deltar-117.7kJ/molCmPritchard and Skinner, 1950liquid phase; Heat of hydrolysis at 298 K; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dias, Salema, et al., 1984
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., Rev. Port. Quím., 1984, 26, 227. [all data]

Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C., Organometallics, 1986, 5, 660. [all data]

Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A., The heats of hydrolysis of the chloro-substituted acetyl chlorides, J. Chem. Soc., 1950, 272-276. [all data]


Notes

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