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Silane, chlorotrimethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)10.83 ± 0.02eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
10.65 ± 0.02PIPECOSzepes and Baer, 1984T = 298K; LBLHLM
10.83 ± 0.02PIPECOSzepes and Baer, 1984T = 0K; LBLHLM
10.83 ± 0.02PIPECOSzepes and Baer, 1984, 2T = 0K; LBLHLM
9.9 ± 0.1EIBand, Davidson, et al., 1968RDSH
10.58 ± 0.04EIHess, Lampe, et al., 1965RDSH
10.71PEZykov, Khvostenko, et al., 1981Vertical value; LLK
10.84PEBlock, Biernbaum, et al., 1977Vertical value; LLK
10.76PEGreen, Lappert, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H6SiCl+10.6 ± 0.1CH3EIBand, Davidson, et al., 1968RDSH
C2H6SiCl+11.00 ± 0.16CH3EIHess, Lampe, et al., 1965RDSH
C3H9Si+11.6 ± 0.1ClEIPotzinger, Ritter, et al., 1975LLK
C3H9Si+10.9 ± 0.1ClEIBand, Davidson, et al., Commun. 1967RDSH
C3H9Si+11.5 ± 0.2ClEIConnor, Finney, et al., 1966RDSH
C3H9Si+12.40 ± 0.06ClEIHess, Lampe, et al., 1965RDSH
C3H9Si+12.42 ± 0.03ClEIHess, Lampe, et al., 1964RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Szepes and Baer, 1984
Szepes, L.; Baer, T., Dissociation dynamics of energy selected hexamethyldisilane ions and the heats of formation of (CH3)3Si+ and (CH3)3Si, J. Am. Chem. Soc., 1984, 106, 273. [all data]

Szepes and Baer, 1984, 2
Szepes, L.; Baer, T., (CH3)3SiX tipusu vegyuletek vizsgalata fotoelectron-fotoion koincidenciaval,I. Meghatarozott belso energiaju hexametil-diszilan-ionok disszociaciojanak dinamikaja, Magy. Kem. Foly., 1984, 90, 104. [all data]

Band, Davidson, et al., 1968
Band, S.J.; Davidson, I.M.T.; Lambert, C.A., Bond dissociation energies: electron impact studies on some trimethylsilyl compounds, J. Chem. Soc. A, 1968, 2068. [all data]

Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H., An electron impact study of ionization and dissociation of trimethylsilanes, J. Am. Chem. Soc., 1965, 87, 5327. [all data]

Zykov, Khvostenko, et al., 1981
Zykov, B.G.; Khvostenko, V.I.; Voronkov, M.G.; Yur'ev, V.P.; Lomakin, G.S.; Suslova, E.N., Photoelectron spectra of Si-substituted chloromethylsilanes, Dokl. Akad. Nauk SSSR, 1981, 258, 135. [all data]

Block, Biernbaum, et al., 1977
Block, T.F.; Biernbaum, M.; West, R., Cyclic polysilanes XII. Photoelectron spectra and bonding in 1,2,3,4-tetra-t-butyltetramethylcyclotetrasilane and related t-butylsilicon compounds, J. Organomet. Chem., 1977, 131, 199. [all data]

Green, Lappert, et al., 1971
Green, M.C.; Lappert, M.F.; Pedley, J.B.; Schmidt, W.; Wilkins, B.T., Photoelectron spectra energy level trends in MenSiCl4-n and related series, J. Organomet. Chem., 1971, 31, 55. [all data]

Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J., Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen, Z. Naturforsch. A:, 1975, 30, 347. [all data]

Band, Davidson, et al., Commun. 1967
Band, S.J.; Davidson, I.M.T.; Lambert, C.A.; Stephenson, I.L., Bond dissociation energies and heats of formation of trimethylsilyl compounds, Chem., Commun. 1967, 723. [all data]

Connor, Finney, et al., 1966
Connor, J.A.; Finney, G.; Leigh, G.J.; Haszeldine, R.N.; Robinson, P.J.; Sedgwick, R.D.; Simmons, R.F., Bond dissociation energies in organosilicon compounds, Chem. Commun., 1966, 178. [all data]

Hess, Lampe, et al., 1964
Hess, G.G.; Lampe, F.W.; Sommer, L.H., Bond dissociation energies and ion energetics in organosilicon compounds by electron impact, J. Am. Chem. Soc., 1964, 86, 3174. [all data]


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