Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Silane, tetramethyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-286.60kJ/molReviewChase, 1998Data last reviewed in December, 1960
Quantity Value Units Method Reference Comment
gas,1 bar361.12J/mol*KReviewChase, 1998Data last reviewed in December, 1960

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. - 1500.
A 38.91706
B 397.3951
C -189.3310
D 34.87301
E -0.268466
F -315.1887
G 296.3318
H -286.6044
ReferenceChase, 1998
Comment Data last reviewed in December, 1960

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid272.04J/mol*KN/AHarada, Atake, et al., 1977 
liquid277.27J/mol*KN/AAston, Kennedy, et al., 1941 

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
189.84290.Harada, Atake, et al., 1977T = 3 to 300 K.
164.56177.45Shinoda, Enokida, et al., 1973T = 2 to 26 K and 106 to 277.5 K.
197.90290.Aston, Kennedy, et al., 1941T = 11 to 290 K.

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil299.7KN/APCR Inc., 1990BS
Tboil299.KN/ASommer, Goldberg, et al., 1946Uncertainty assigned by TRC = 3. K; ~; TRC
Quantity Value Units Method Reference Comment
Ttriple172. ± 5.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Tc448.640KN/AMcGlashan and McKinnon, 1977Uncertainty assigned by TRC = 0.03 K; TRC
Quantity Value Units Method Reference Comment
Pc28.21barN/AMcGlashan and McKinnon, 1977Uncertainty assigned by TRC = 0.01 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.362l/molN/AMcGlashan and McKinnon, 1977Uncertainty assigned by TRC = 0.008 l/mol; TRC
Quantity Value Units Method Reference Comment
Deltavap26.0 ± 0.6kJ/molCVoronkov, Baryshok, et al., 1988AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
24.204299.80N/AAston, Kennedy, et al., 1941P = 101.325 kPa; DH
24.2 ± 0.1299.CBergmann and Haskelberg, 1941AC

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
80.73299.80Aston, Kennedy, et al., 1941P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
208.93 - 293.643.977031047.272-36.057Aston, Kennedy, et al., 1941Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
6.74174.Domalski and Hearing, 1996AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.703165.920crystaline, «alpha»liquidHarada, Atake, et al., 1977DH
5.878171.016crystaline, «beta»liquidHarada, Atake, et al., 1977DH
5.840970.983crystaline, IIliquidShinoda, Enokida, et al., 1973Metastable form.; DH
6.7413174.049crystaline, IliquidShinoda, Enokida, et al., 1973Stable form.; DH
5.9697171.04crystaline, IliquidAston, Kennedy, et al., 1941DH
6.895174.12crystaline, IIliquidAston, Kennedy, et al., 1941DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
4.24165.920crystaline, «alpha»liquidHarada, Atake, et al., 1977DH
34.37171.016crystaline, «beta»liquidHarada, Atake, et al., 1977DH
34.1670.983crystaline, IIliquidShinoda, Enokida, et al., 1973Metastable; DH
38.73174.049crystaline, IliquidShinoda, Enokida, et al., 1973Stable; DH
34.90171.04crystaline, IliquidAston, Kennedy, et al., 1941DH
39.60174.12crystaline, IIliquidAston, Kennedy, et al., 1941DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H11Si- + Hydrogen cation = Silane, tetramethyl-

By formula: C4H11Si- + H+ = C4H12Si

Quantity Value Units Method Reference Comment
Deltar1624. ± 13.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Comparable to fluorobenzene; B
Deltar1636. ± 8.4kJ/molD-EAWetzel and Brauman, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar1586. ± 13.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Comparable to fluorobenzene; B
Deltar1597. ± 8.8kJ/molH-TSWetzel and Brauman, 1988gas phase; B
Deltar1635. ± 21.kJ/molIMRBDePuy and Damrauer, 1984gas phase; B

Fluorine anion + Silane, tetramethyl- = (Fluorine anion bullet Silane, tetramethyl-)

By formula: F- + C4H12Si = (F- bullet C4H12Si)

Quantity Value Units Method Reference Comment
Deltar125. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar98.7 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

C3H9Si+ + Silane, tetramethyl- = (C3H9Si+ bullet Silane, tetramethyl-)

By formula: C3H9Si+ + C4H12Si = (C3H9Si+ bullet C4H12Si)

Quantity Value Units Method Reference Comment
Deltar93.3kJ/molPHPMSWojtyniak, Li, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar147.J/mol*KPHPMSWojtyniak, Li, et al., 1987gas phase; M

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Quantity Value Units Method Reference Comment
IE (evaluated)9.80 ± 0.04eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.80 ± 0.03PIMurphy and Beauchamp, 1977LLK
9.6PEPotzinger, Ritter, et al., 1975LLK
9.99 ± 0.03EIMacLean and Sacher, 1974LLK
9.79 ± 0.04PEJonas, Schweitzer, et al., 1973LLK
9.4 ± 0.1PEEvans, Green, et al., 1972LLK
9.85 ± 0.16EILappert, Pedley, et al., 1971LLK
9.74 ± 0.05EIPotzinger and Lampe, 1970RDSH
9.86 ± 0.02PIDistefano, 1970RDSH
9.85 ± 0.16EILappert, Simpson, et al., 1969RDSH
9.9 ± 0.1EIBand, Davidson, et al., 1968RDSH
9.98 ± 0.03EIHess, Lampe, et al., 1965RDSH
10.29PEKhvostenko, Zykov, et al., 1981Vertical value; LLK
10.4PERoberge, Sandorfy, et al., 1978Vertical value; LLK
10.57PEStarzewski, Richter, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3Si+17.3?EIdeRidder and Dijkstra, 1967RDSH
CH3Si+17.1 ± 0.4?EIHobrock and Kiser, 1961RDSH
CH4Si+16.3?EIdeRidder and Dijkstra, 1967RDSH
CH5Si+13.81 ± 0.02C2H4+CH3PIDistefano, 1970RDSH
CH5Si+14.4C2H4+CH3EIdeRidder and Dijkstra, 1967RDSH
C2H6Si+13.4?EIdeRidder and Dijkstra, 1967RDSH
C2H6Si+13.9 ± 0.3?EIHobrock and Kiser, 1961RDSH
C2H7Si+13.3?EIdeRidder and Dijkstra, 1967RDSH
C3H9Si+10.09 ± 0.01CH3PIPECOSzepes and Baer, 1984T = 298K; LBLHLM
C3H9Si+10.28 ± 0.01CH3PIPECOSzepes and Baer, 1984T = 0K; LBLHLM
C3H9Si+10.28 ± 0.01CH3PIPECOSzepes and Baer, 1984, 2T = 0K; LBLHLM
C3H9Si+10.03 ± 0.04CH3PIMurphy and Beauchamp, 1977LLK
C3H9Si+10.3 ± 0.1CH3EIPotzinger, Ritter, et al., 1975LLK
C3H9Si+10.63 ± 0.05CH3EIMacLean and Sacher, 1974LLK
C3H9Si+10.53 ± 0.20CH3EILappert, Pedley, et al., 1971LLK
C3H9Si+10.25 ± 0.05CH3EIPotzinger and Lampe, 1970RDSH
C3H9Si+10.09 ± 0.02CH3PIDistefano, 1970RDSH
C3H9Si+10.53 ± 0.20CH3EILappert, Simpson, et al., 1969RDSH
C3H9Si+10.4 ± 0.1CH3EIBand, Davidson, et al., Commun. 1967RDSH
C3H9Si+10.5 ± 0.1CH3EIConnor, Finney, et al., 1966RDSH
C3H9Si+10.63 ± 0.13CH3EIHess, Lampe, et al., 1964RDSH
SiH+18.2?EIdeRidder and Dijkstra, 1967RDSH
SiH3+16.5?EIdeRidder and Dijkstra, 1967RDSH
Si+17.9?EIdeRidder and Dijkstra, 1967RDSH

De-protonation reactions

C4H11Si- + Hydrogen cation = Silane, tetramethyl-

By formula: C4H11Si- + H+ = C4H12Si

Quantity Value Units Method Reference Comment
Deltar1624. ± 13.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Comparable to fluorobenzene; B
Deltar1636. ± 8.4kJ/molD-EAWetzel and Brauman, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar1586. ± 13.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Comparable to fluorobenzene; B
Deltar1597. ± 8.8kJ/molH-TSWetzel and Brauman, 1988gas phase; B
Deltar1635. ± 21.kJ/molIMRBDePuy and Damrauer, 1984gas phase; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H9Si+ + Silane, tetramethyl- = (C3H9Si+ bullet Silane, tetramethyl-)

By formula: C3H9Si+ + C4H12Si = (C3H9Si+ bullet C4H12Si)

Quantity Value Units Method Reference Comment
Deltar93.3kJ/molPHPMSWojtyniak, Li, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar147.J/mol*KPHPMSWojtyniak, Li, et al., 1987gas phase; M

Fluorine anion + Silane, tetramethyl- = (Fluorine anion bullet Silane, tetramethyl-)

By formula: F- + C4H12Si = (F- bullet C4H12Si)

Quantity Value Units Method Reference Comment
Deltar125. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar98.7 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin R.W.CRAWFORD UNIV. OF CALIFORNIA, LIVERMORE, CALIFORNIA, USA
NIST MS number 19500

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

UVVis spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Source Bastian, et al., 1980
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 18490
Instrument unknown

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedC78, Branched paraffin130.428.1Dallos, Sisak, et al., 2000He; Column length: 3.3 m
PackedC78, Branched paraffin130.428.0Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
PackedApolane110.428.4Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane130.427.6Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane150.426.8Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane170.425.9Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane190.424.8Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane210.423.6Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane230.422.4Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane30.430.Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane50.429.8Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane70.429.4Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane90.429.Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
PackedApolane70.429.4Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
CapillaryApiezon L160.420.Peetre and Smith, 1974 

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedApieson M160.420.Ellren, Peetre, et al., 1974Chromosorb G AW DMCS (80-100 mesh)

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillarySqualane419.Szekely, Nefedov, et al., 1967Nitrogen, 5. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 60. C; Tend: 250. C

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Harada, Atake, et al., 1977
Harada, M.; Atake, T.; Chihara, H., Thermodynamic properties of polymorphic phases of tetramethylsilane, J. Chem. Thermodynam., 1977, 9, 523-534. [all data]

Aston, Kennedy, et al., 1941
Aston, J.G.; Kennedy, R.M.; Messerly, G.H., The heat capacity and entropy, heats of fusion and vaporization and the vapor pressure of silicon tetramethyl, J. Am. Chem. Soc., 1941, 63, 2343-2348. [all data]

Shinoda, Enokida, et al., 1973
Shinoda, T.; Enokida, H.; Maeda, Y.; Tomita, H.; Mashiko, Y., Heat capacity of tetramethylsilane in the range from 2 to 26 K and premelting range, Bull. Chem. Soc. Japan, 1973, 46, 48-52. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Sommer, Goldberg, et al., 1946
Sommer, L.H.; Goldberg, G.M.; Derfman, E.; Whitmore, F.C., Organisilicaon Compounds V. «beta»-Elimination Involving Silicon, J. Am. Chem. Soc., 1946, 68, 1083. [all data]

McGlashan and McKinnon, 1977
McGlashan, M.L.; McKinnon, I.R., The vapor pressure, orthobaric volumes, and critical constants of tetramethylsilane, J. Chem. Thermodyn., 1977, 9, 1205-12. [all data]

Voronkov, Baryshok, et al., 1988
Voronkov, M.G.; Baryshok, V.P.; Klyuchnikov, V.A.; Danilova, T.F.; Pepekin, V.I.; Korchagina, A.N.; Khudobin, Yu.I., Thermochemistry of organosilicon compounds, Journal of Organometallic Chemistry, 1988, 345, 1-2, 27-38, https://doi.org/10.1016/0022-328X(88)80231-6 . [all data]

Bergmann and Haskelberg, 1941
Bergmann, F.; Haskelberg, L., Synthesis of Lipophilic Chemotherapeuticals. V. N 4 -Acyl-sulfanilamides 1a, J. Am. Chem. Soc., 1941, 63, 8, 2243-2245, https://doi.org/10.1021/ja01853a062 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637, https://doi.org/10.1021/om00093a011 . [all data]

Wetzel and Brauman, 1988
Wetzel, D.M.; Brauman, J.I., Quantitative Measure of alpha-Silyl Carbanion Stabilization. The Electron Affinity of (Trimethylsilyl)methyl Radical, J. Am. Chem. Soc., 1988, 110, 25, 8333, https://doi.org/10.1021/ja00233a008 . [all data]

DePuy and Damrauer, 1984
DePuy, C.H.; Damrauer, R., Reactions of organosilane anionic species with nitrous oxide, Organometallics, 1984, 3, 362. [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Wojtyniak, Li, et al., 1987
Wojtyniak, A.C.M.; Li, K.; Stone, J.A., The Formation of (CH3)7Si2+ in (CH3)4Si/CH4 Mixtures and CH3- Exchange Reactions Between (CH3)4Si, (CH3)4Ge and (CH3)4Sn Studied by High Pressure Mass Spectrometry, Can. J. Chem., 1987, 65, 12, 2849, https://doi.org/10.1139/v87-473 . [all data]

Murphy and Beauchamp, 1977
Murphy, M.K.; Beauchamp, J.L., Photoionization mass spectrometry of the fluoromethylsilanes (CH3)n F4-nSi (n = 1-4), J. Am. Chem. Soc., 1977, 99, 2085. [all data]

Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J., Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen, Z. Naturforsch. A:, 1975, 30, 347. [all data]

MacLean and Sacher, 1974
MacLean, D.I.; Sacher, R.E., A study of some spectroscopic properties of Group IVA acetylides, J. Organomet. Chem., 1974, 74, 197. [all data]

Jonas, Schweitzer, et al., 1973
Jonas, A.E.; Schweitzer, G.K.; Grimm, F.A.; Carlson, T.A., The photoelectron spectra of the tetrafluoro and tetramethyl compounds of the group IV elements, J. Electron Spectrosc. Relat. Phenom., 1973, 1, 29. [all data]

Evans, Green, et al., 1972
Evans, S.; Green, J.C.; Joachim, P.J.; Orchard, A.F.; Turner, D.W.; Maier, J.P., Electronic structures of the Group IVB tetramethyls by helium-(I) photoelectron spectroscopy, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 905. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Potzinger and Lampe, 1970
Potzinger, P.; Lampe, F.W., Thermochemistry of simple alkylsilanes, J. Phys. Chem., 1970, 74, 719. [all data]

Distefano, 1970
Distefano, G., Photoionization study of tetramethylsilicon, Inorg. Chem., 1970, 9, 1919. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]

Band, Davidson, et al., 1968
Band, S.J.; Davidson, I.M.T.; Lambert, C.A., Bond dissociation energies: electron impact studies on some trimethylsilyl compounds, J. Chem. Soc. A, 1968, 2068. [all data]

Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H., An electron impact study of ionization and dissociation of trimethylsilanes, J. Am. Chem. Soc., 1965, 87, 5327. [all data]

Khvostenko, Zykov, et al., 1981
Khvostenko, V.I.; Zykov, B.G.; Yuriev, V.P.; Mironov, V.F.; Kovel'zon, G.I.; Panasenko, A.A.; Sheludyakov, V.D.; Gailyunas, I.A., Study of d(«pi»)-p(«pi») interaction in vinyl- and alkylsilicon-containing compounds by photoelectron spectroscopy, J. Organomet. Chem., 1981, 218, 155. [all data]

Roberge, Sandorfy, et al., 1978
Roberge, R.; Sandorfy, C.; Matthews, J.I.; Strausz, O.P., The far ultraviolet HeI photoelectron spectra of alkyl and fluorine substituted silane derivatives, J. Chem. Phys., 1978, 69, 5105. [all data]

Starzewski, Richter, et al., 1976
Starzewski, K.-H.A.O.; Richter, W.; Schmidbaur, H., Photoelektronenspektren und Struktur von Arsenyliden. P versus As: Ein Beitrag zur Problematik der ylidischen Bindung, Chem. Ber., 1976, 109, 473. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]

Hobrock and Kiser, 1961
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of tetramethylsilicon, -tin and -lead, J. Phys. Chem., 1961, 65, 2186. [all data]

Szepes and Baer, 1984
Szepes, L.; Baer, T., Dissociation dynamics of energy selected hexamethyldisilane ions and the heats of formation of (CH3)3Si+ and (CH3)3Si, J. Am. Chem. Soc., 1984, 106, 273. [all data]

Szepes and Baer, 1984, 2
Szepes, L.; Baer, T., (CH3)3SiX tipusu vegyuletek vizsgalata fotoelectron-fotoion koincidenciaval,I. Meghatarozott belso energiaju hexametil-diszilan-ionok disszociaciojanak dinamikaja, Magy. Kem. Foly., 1984, 90, 104. [all data]

Band, Davidson, et al., Commun. 1967
Band, S.J.; Davidson, I.M.T.; Lambert, C.A.; Stephenson, I.L., Bond dissociation energies and heats of formation of trimethylsilyl compounds, Chem., Commun. 1967, 723. [all data]

Connor, Finney, et al., 1966
Connor, J.A.; Finney, G.; Leigh, G.J.; Haszeldine, R.N.; Robinson, P.J.; Sedgwick, R.D.; Simmons, R.F., Bond dissociation energies in organosilicon compounds, Chem. Commun., 1966, 178. [all data]

Hess, Lampe, et al., 1964
Hess, G.G.; Lampe, F.W.; Sommer, L.H., Bond dissociation energies and ion energetics in organosilicon compounds by electron impact, J. Am. Chem. Soc., 1964, 86, 3174. [all data]

Bastian, et al., 1980
Bastian, E., et al., Ber. Bunsen Gesell. Phys. Chem., 1980, 84, 56. [all data]

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Peetre and Smith, 1974
Peetre, I.-B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. IV. determination, calculation and correlation of Kováts retention indices for tetraalkylsilanes, J. Chromatogr., 1974, 90, 1, 41-55, https://doi.org/10.1016/S0021-9673(01)94772-7 . [all data]

Ellren, Peetre, et al., 1974
Ellren, O.; Peetre, I.B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. V. Use of refractive index in conjunction with Kovats retention index for the identification of organosilicon compounds, J. Chromatogr., 1974, 93, 2, 383-392, https://doi.org/10.1016/S0021-9673(01)85402-9 . [all data]

Szekely, Nefedov, et al., 1967
Szekely, T.; Nefedov, O.M.; Garzo, G.; Shiryayav, V.I.; Fritz, D., Gas chromatographic investigation of the thermal decomposition of polydimethylsilylene, Acta Chim. Acad. Sci. Hung., 1967, 54, 3-4, 241-254. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References