Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Silane, tetramethyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Kovats' RI, non-polar column, isothermal

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedPackedPackedPackedPacked
Active phase C78, Branched paraffinC78, Branched paraffinApolaneApolaneApolane
Column length (m) 3.33.32.42.42.4
Carrier gas He HeHeHe
Substrate  Chromosorb G HPChromosorbChromosorbChromosorb
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 130.130.110.130.150.
I 428.1428.0428.4427.6426.8
ReferenceDallos, Sisak, et al., 2000Reddy, Dutoit, et al., 1992Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase ApolaneApolaneApolaneApolaneApolane
Column length (m) 2.42.42.42.42.4
Carrier gas HeHeHeHeHe
Substrate ChromosorbChromosorbChromosorbChromosorbChromosorb
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 170.190.210.230.30.
I 425.9424.8423.6422.4430.
ReferenceRiedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedCapillary
Active phase ApolaneApolaneApolaneApolaneApiezon L
Column length (m) 2.42.42.42.4 
Carrier gas HeHeHeHe 
Substrate ChromosorbChromosorbChromosorbChromosorb 
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 50.70.90.70.160.
I 429.8429.4429.429.4420.
ReferenceRiedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Peetre and Smith, 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Peetre and Smith, 1974
Peetre, I.-B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. IV. determination, calculation and correlation of Kováts retention indices for tetraalkylsilanes, J. Chromatogr., 1974, 90, 1, 41-55, https://doi.org/10.1016/S0021-9673(01)94772-7 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References