Silane, tetramethyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedPackedPackedPackedPacked
Active phase C78, Branched paraffinC78, Branched paraffinApolaneApolaneApolane
Column length (m) 3.33.32.42.42.4
Carrier gas He HeHeHe
Substrate  Chromosorb G HPChromosorbChromosorbChromosorb
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 130.130.110.130.150.
I 428.1428.0428.4427.6426.8
ReferenceDallos, Sisak, et al., 2000Reddy, Dutoit, et al., 1992Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase ApolaneApolaneApolaneApolaneApolane
Column length (m) 2.42.42.42.42.4
Carrier gas HeHeHeHeHe
Substrate ChromosorbChromosorbChromosorbChromosorbChromosorb
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 170.190.210.230.30.
I 425.9424.8423.6422.4430.
ReferenceRiedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedCapillary
Active phase ApolaneApolaneApolaneApolaneApiezon L
Column length (m) 2.42.42.42.4 
Carrier gas HeHeHeHe 
Substrate ChromosorbChromosorbChromosorbChromosorb 
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 50.70.90.70.160.
I 429.8429.4429.429.4420.
ReferenceRiedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Riedo, Fritz, et al., 1976Peetre and Smith, 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Peetre and Smith, 1974
Peetre, I.-B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. IV. determination, calculation and correlation of Kováts retention indices for tetraalkylsilanes, J. Chromatogr., 1974, 90, 1, 41-55, https://doi.org/10.1016/S0021-9673(01)94772-7 . [all data]


Notes

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