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Tetrafluoromethane

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Trifluoromethyl cation + Tetrafluoromethane = (Trifluoromethyl cation bullet Tetrafluoromethane)

By formula: CF3+ + CF4 = (CF3+ bullet CF4)

Quantity Value Units Method Reference Comment
Deltar6.6kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet Tetrafluoromethane) + Tetrafluoromethane = (Trifluoromethyl cation bullet 2Tetrafluoromethane)

By formula: (CF3+ bullet CF4) + CF4 = (CF3+ bullet 2CF4)

Quantity Value Units Method Reference Comment
Deltar4.9kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 2Tetrafluoromethane) + Tetrafluoromethane = (Trifluoromethyl cation bullet 3Tetrafluoromethane)

By formula: (CF3+ bullet 2CF4) + CF4 = (CF3+ bullet 3CF4)

Quantity Value Units Method Reference Comment
Deltar2.9kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 3Tetrafluoromethane) + Tetrafluoromethane = (Trifluoromethyl cation bullet 4Tetrafluoromethane)

By formula: (CF3+ bullet 3CF4) + CF4 = (CF3+ bullet 4CF4)

Quantity Value Units Method Reference Comment
Deltar2.8kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

CF3- + Tetrafluoromethane = (CF3- bullet Tetrafluoromethane)

By formula: CF3- + CF4 = (CF3- bullet CF4)

Quantity Value Units Method Reference Comment
Deltar3.6kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(CF3- bullet Tetrafluoromethane) + Tetrafluoromethane = (CF3- bullet 2Tetrafluoromethane)

By formula: (CF3- bullet CF4) + CF4 = (CF3- bullet 2CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(CF3- bullet 2Tetrafluoromethane) + Tetrafluoromethane = (CF3- bullet 3Tetrafluoromethane)

By formula: (CF3- bullet 2CF4) + CF4 = (CF3- bullet 3CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(CF3- bullet 3Tetrafluoromethane) + Tetrafluoromethane = (CF3- bullet 4Tetrafluoromethane)

By formula: (CF3- bullet 3CF4) + CF4 = (CF3- bullet 4CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated

CHF4+ + Tetrafluoromethane = (CHF4+ bullet Tetrafluoromethane)

By formula: CHF4+ + CF4 = (CHF4+ bullet CF4)

Quantity Value Units Method Reference Comment
Deltar5.1kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(CHF4+ bullet Tetrafluoromethane) + Tetrafluoromethane = (CHF4+ bullet 2Tetrafluoromethane)

By formula: (CHF4+ bullet CF4) + CF4 = (CHF4+ bullet 2CF4)

Quantity Value Units Method Reference Comment
Deltar2.8kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar11.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(CHF4+ bullet 2Tetrafluoromethane) + Tetrafluoromethane = (CHF4+ bullet 3Tetrafluoromethane)

By formula: (CHF4+ bullet 2CF4) + CF4 = (CHF4+ bullet 3CF4)

Quantity Value Units Method Reference Comment
Deltar2.3kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar16.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(CHF4+ bullet 3Tetrafluoromethane) + Tetrafluoromethane = (CHF4+ bullet 4Tetrafluoromethane)

By formula: (CHF4+ bullet 3CF4) + CF4 = (CHF4+ bullet 4CF4)

Quantity Value Units Method Reference Comment
Deltar2.3kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase

C4H9+ + Tetrafluoromethane = (C4H9+ bullet Tetrafluoromethane)

By formula: C4H9+ + CF4 = (C4H9+ bullet CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar10.4cal/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase

Fluorine anion + Tetrafluoromethane = (Fluorine anion bullet Tetrafluoromethane)

By formula: F- + CF4 = (F- bullet CF4)

Quantity Value Units Method Reference Comment
Deltar6.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(Fluorine anion bullet Tetrafluoromethane) + Tetrafluoromethane = (Fluorine anion bullet 2Tetrafluoromethane)

By formula: (F- bullet CF4) + CF4 = (F- bullet 2CF4)

Quantity Value Units Method Reference Comment
Deltar5.9kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(Fluorine anion bullet 2Tetrafluoromethane) + Tetrafluoromethane = (Fluorine anion bullet 3Tetrafluoromethane)

By formula: (F- bullet 2CF4) + CF4 = (F- bullet 3CF4)

Quantity Value Units Method Reference Comment
Deltar4.1kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(Fluorine anion bullet 3Tetrafluoromethane) + Tetrafluoromethane = (Fluorine anion bullet 4Tetrafluoromethane)

By formula: (F- bullet 3CF4) + CF4 = (F- bullet 4CF4)

Quantity Value Units Method Reference Comment
Deltar3.9kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase

(Fluorine anion bullet 4Tetrafluoromethane) + Tetrafluoromethane = (Fluorine anion bullet 5Tetrafluoromethane)

By formula: (F- bullet 4CF4) + CF4 = (F- bullet 5CF4)

Quantity Value Units Method Reference Comment
Deltar2.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KN/AHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Nasu, et al., 1996
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Gas-Phase Stability and Structure of the Cluster Ions CF3+(CO)n, CF3+(N2)n, CF3+((CF4)n, and CF4H+(CF4)n, J. Phys. Chem., 1996, 100, 13, 5245, https://doi.org/10.1021/jp9530010 . [all data]

Hiraoka, Nasu, et al., 1995
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Weak Ion-Molecule Complexes of F-(CF4)n and CF3-(CF4)n, Chem Phys. Let., 1995, 245, 1, 14, https://doi.org/10.1016/0009-2614(95)00980-I . [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757, https://doi.org/10.1021/ja00299a002 . [all data]


Notes

Go To: Top, Ion clustering data, References