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Chlorotrifluoromethane

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Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Deltafgas (kcal/mol) Method Reference Comment
-169.20ReviewChase, 1998Data last reviewed in June, 1969
-169.4 ± 1.0EqkCoomber and Whittle, 1967ALS
-168.50 ± 0.81EqkLord, Goy, et al., 1967Reanalyzed by Cox and Pilcher, 1970, Original value = -167.5 kcal/mol; ALS
-176.7 ± 1.2CmKolesov, Zenkov, et al., 1963Reanalyzed by Cox and Pilcher, 1970, Original value = -171.8 ± 0.9 kcal/mol; Reaction with Na; ALS
-166.2 ± 2.2CmBaibuz, 1961Explosion method; ALS
-167.CcbWartenberg and Schiefer, 1955ALS
-171. ± 1.CmKirkbride and Davidson, 1954Von Wartenberg method; ALS

References

Go To: Top, Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Coomber and Whittle, 1967
Coomber, J.W.; Whittle, E., Bond dissociation energies from equilibrium studies. Part 3.-D(CF3-Cl), D(C2F5-Cl) and the enthalpy of formation of CF3Cl, Trans. Faraday Soc., 1967, 63, 2656-2667. [all data]

Lord, Goy, et al., 1967
Lord, A.; Goy, C.A.; Pritchard, H.O., The heats of formation of trifluoromethyl chloride and bromide, J. Phys. Chem., 1967, 71, 2705-2707. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M., Standard enthalpies of formation of chlorotrifluoromethane and dichlorodifluoromethane, Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 378-379. [all data]

Baibuz, 1961
Baibuz, V.F., Explosion method and heat of formation of CF4, CFCl, CFCl3, and CCl4, Dokl. Phys. Chem. (Engl. Transl.), 1961, 140, 786-788, In original 1358. [all data]

Wartenberg and Schiefer, 1955
Wartenberg, H.V.; Schiefer, J., Bildungswarmen von fluor-chlor-kohlenstoff-verbindungen, Z. Anorg. Chem., 1955, 278, 326-332. [all data]

Kirkbride and Davidson, 1954
Kirkbride, F.W.; Davidson, F.G., Heats of formation of gaseous fluoro- and fluorochloro-carbons, Nature (London), 1954, 174, 79-80. [all data]


Notes

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